Kinetics of the amorphous—anatase phase transformation in copper doped titanium oxide

Abstract

Samples of TiO₂ doped with 2 and 5 mol% of Cu²⁺ were prepared by the sol-gel process. Titanium(IV) isopropoxide and copper(II) nitrate were used as precursors. The samples were prepared as monolithic shapes, dried at 80°C for 72 h and heat treated at various temperatures in the range 200–900°C for 2 h. The structural transformation and texture of the samples were investigated by X-ray powder diffraction (XRD) and nitrogen adsorption. Significant changes were observed during the crystallization process; on the one hand, the crystallization profiles show that crystallization occurs uniformly and is practically insensitive to the dopant concentration, but when the transformation at a given temperature is followed as a function of time, the rate of the amorphous-anatase transformation is larger for the sample containing 2 mol% Cu²⁺. Electron spin resonance (ESR) results show that in this sample there is no segregation of Cu²⁺ ions. The sample containing 2 mol% of Cu²⁺ was selected for the kinetic studies and the temperatures selected were 300, 325, 350, 375 and 400°C, which were taken from the amorphous to anatase crystallization profile. An activation energy of 137 ± 4 kJ/mol for the crystallization process was estimated from the kinetic data. These results showed that the effect of the open structure present in the TiO₂ amorphous phase provides the atomic mobility required for the crystallization. On the other hand, the differences in the crystallization rate due to the amount of Cu²⁺ were explained by the segregation of copper ions to the surface of the samples.