Abstract
Amorphous precursor powders have proven to be highly advantageous for the sol–gel processing of TiO2 thin films. Oxide yield, density, solubility, and thermal degradation of powders prepared under various conditions were determined; the thermoanalytical data could be assigned to the oxidative decomposition of different organic constituents. Certain powders are suitable for the preparation of alcohol-based sols, whereas also aqueous coating solutions can be prepared from others. Thin films prepared from both systems show excellent adhesion and optical properties when deposited on borosilicate glass substrates.
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References
C. Brinker and G. Scherer, Sol–Gel Science: The Physics and Chemistry of Sol–Gel Processing (Academic Press, Boston, 1990).
J. Mackenzie and E. Bescher, J. Sol–Gel Sci. Tec. 19, 23 (2000).
G. Schottner, Chem. Mat. 13, 3422 (2001).
M. Sedlar and M. Sayer, J. Sol–Gel Sci. Tec. 5, 27 (1995).
J. Blanchard, F. Ribot, C. Sanchez, P. Bellot, and A. Trokiner, J. Non Cryst. Solids 265, 83 (2000).
W. Rupp, N. Hüsing, and U. Schubert, J. Mat. Chem. 12, 2594 (2002).
P. Löbmann and P. Röhlen, Glass Sci.Tec. 76, 1 (2003).
PCT/EP 99/06374; WO 2000020337 A1 20000413; U.S. Appl. 09/555,256.
T. Ohya, A. Nakayama, Y. Shibata, T. Ban, Y. Ohya, and Y. Takahashi, J. Sol–Gel Sci. Tec. 26, 799 (2003).
R. Krüger, W. Glaubitt, and P. Löbmann, J. Am. Ceram. Soc. 85, 2827 (2002).
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Löbmann, P. Soluble Powders as Precursors for TiO2 Thin Films. J Sol-Gel Sci Technol 33, 275–282 (2005). https://doi.org/10.1007/s10971-005-6377-8
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DOI: https://doi.org/10.1007/s10971-005-6377-8