Abstract
Sol–gel-derived nanocrystalline ZnO thin films on silica glass substrates were prepared by using a zinc naphthenate precursor. As-deposited films were heat treated at 500, 600 and 700°C for 30 min in air. The ZnO films were analyzed by X-ray diffraction, field emission—scanning electron microscope, scanning probe microscope, and ultra violet—visible—near infrared spectrophotometer. With an increase in heat treatment temperature, the peak intensity of (002) plane increases. No evidently aggregated particles are present. All the films exhibit a high transmittance (>80%) in visible region and show a sharp fundamental absorption edge at about 0.38–0.40 μm. The estimated energy band gap for all the films are within the range reported for films and single crystal.
Similar content being viewed by others
References
K. Matsubara, P. Fons, A. Yamada, M. Watanabe, and S. Niki, Thin Solids Films 347, 238 (1999).
S. Zhu, C. Su, S. Lehoczky, M. George, and D. Lowndes, J. Mater. Res. 15(5), 1125 (2000).
M. Chen, Z. Pei, X. Wang, C. Sun, and L. Wen, J. Mater. Res. 16(7), 2118 (2001).
K. Ellmer, F. Kudella, R. Mientus, R. Schieck, and S. Fiechter, Thin Solids Film 247, 15 (1994).
Y. Chen, S. Hong, H. Ko, M. Nakajima, T. Yao, and Y. Segawa, Appl. Phys. Lett. 76(2), 245 (2000).
A. Ohtomo, K. Tamura, K. Saikusa, K. Takahashi, T. Makino, Y. Segawa, H. Koinuma, and M. Kawasaki, Appl. Phys. Lett. 75(17), 2635 (1999).
P. Nunes, B. Fernandes, E. Fortunato, P. Vilarinho, and R. Martins, Thin Solids Film 337, 176 (1999).
K. Hwang and Y. Park, J. Mater. Res. 16(9), 2519 (2001).
K. Hwang, Y. Yun, Y. Kim, H. Ryu, and B. Kang, Jpn. J. Appl. Phys. 41, 795 (2002).
K. Hwang, Y. Yun, B. Kang, S. Kim, S. Jang, C. Kim, and J. Oh, J. Mater. Sci.: Mater. in Med. 14, 761 (2003).
K. Hwang, T. Manabe, I. Yamaguchi, T. Kumagai, and S. Mizuta, Jpn. J. Appl. Phys. 36, 5221 (1997).
A. Jiménez-González, J. Soto Urueta, and R. Suárez-Parra, J. Crys. Growth 192, 430 (1998).
D. Shimono, S. Tanaka, T. Torikai, T. Watari, and M. Murano, J. Ceram. Proc. Res. 2(4), 184 (2001).
M. Ohyama, H. Kozuka, and T. Yoko, Thin Solids Film 306, 78 (1997).
Y. Ohya, H. Saiki, and Y. Takahashi, J. Mater. Sci. 29, 4099 (1994).
B. Wessler, F.F. Lange, and W. Mader, J. Mater. Res. 17(7), 1644 (2002).
J. Fukushima, K. Kodaira, A. Tsunashima, and T. Matsushita, Yogyo-Kyokai-Shi 83(11), 535 (1975).
R. Cebulla, R. Wendt, and K. Ellmer, J. Appl. Phys. 83, 1087 (1998).
K. Park, D. Ma, and K. Kim, Thin Solid Films 305, 201 (1997).
E. Ziegler, A. Heinrich, H. Oppermann, and G. Stover, Phys. Status Solidi A66, 635 (1981).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hwang, KS., Jeon, YS., An, JH. et al. Naphthenic Acid-Derived Nanocrystalline ZnO Films on Silica Substrate. J Sol-Gel Sci Technol 33, 215–219 (2005). https://doi.org/10.1007/s10971-005-5616-3
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10971-005-5616-3