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Determination of chemical elements and natural radionuclides in shopping plastic bags using k0-neutron activation analysis

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Abstract

The neutron activation analysis technique was applied to determine several chemical elements in shopping plastic bags in order to evaluate their environmental impact. 40K (from K), 232Th and 238U were also determined to predict their radiological impact. In total, 38 elements were determined including Th, and U. These results revealed that ~ 20% of samples under investigation had Cr exceeded the regulated level for packing and packing waste. On the other hand, 50% of samples have Zn and/or Cr violate the regulated levels in plastic products intended to come into contact with foodstuffs. Models for radiological hazard indices showed that the investigated samples possessed insignificant radiation hazards for human. The obtained data is expected to support the decision-maker in adapting measures to control and manage plastic products, starting from the production stage to the final disposal of the waste.

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References

  1. Our world in data. Plastic pollution. https://ourworldindata.org/plastic-pollution. Accessed 15 May 2022

  2. Chen Y, Awasthi AK, Wei F, Tan Q, Li J (2021) Single-use plastics: production, usage, disposal, and adverse impacts. Sci Total Environ 752:141772

    Article  CAS  PubMed  Google Scholar 

  3. Hahladakis JN, Velis CA, Weber R, Iacovidou E, Purnell P (2018) An overview of chemical additives present in plastics: migration, release, fate and environmental impact during their use, disposal and recycling. J Hazard Mater 344:179–199

    Article  CAS  PubMed  Google Scholar 

  4. Kankanige D, Babel S (2020) Smaller-sized micro-plastics (MPs) contamination in single-use PET bottled water in Thailand. Sci Total Environ 717:137232

    Article  CAS  PubMed  Google Scholar 

  5. Wagner TP (2017) Reducing single-use plastic shopping bags in the USA. Waste Manag 70:3–12

    Article  PubMed  Google Scholar 

  6. Depledge MH, Galgani F, Panti C, Caliani I, Casini S, Fossi MC (2013) Plastic litter in the sea. Mar Environ Res 92:279–281

    Article  CAS  PubMed  Google Scholar 

  7. Brouwer R, Hadzhiyska D, Ioakeimidis C, Ouderdorp H( 2017) The social costs of marine litter along European coasts, Ocean Coast Manage 138: 38 - 49.

  8. Schöpel B, Stamminger R (2019) A comprehensive literature study on microfibres from washing machines. Tenside Surf Det 56(2):94–104

    Article  Google Scholar 

  9. Shen M, Zhang Y, Zhu Y, Song B, Zeng G, Hu D, Wen X, Ren X (2019) Recent advances in toxicological research of nanoplastics in the environment: a review. Environ Pollut 252:511–521

    Article  CAS  PubMed  Google Scholar 

  10. Ford HV, Jones NH, Davies AJ, Godley BJ, Jambeck JR, Napper I, Suckling CC, Williams GJ, Woodall LC, Koldewey HJ (2022) The fundamental links between climate change and marine plastic pollution. Sci Total Environ 806:150392

    Article  CAS  PubMed  Google Scholar 

  11. Hansen E, Nilsson N (2014) Hazardous substances in plastics: survey of chemical substances in consumer products no. 132. The Danish Environmental Protection Agency Strandgade, Copenhagen Denmark, p 1401

    Google Scholar 

  12. Shawaphun S, Manangan T, Wacharawichanant S (2010) Thermo- and photo-degradation of LDPE and PP films using metal oxides as catalysts. Adv Mater Res 93:505–508

    Article  Google Scholar 

  13. European Parliament (2011) Directive 2011/65/EC of the European parliament and of the council of 8 June 2011 on the restriction of the use of certain hazardous substances in electrical and electronic equipment. https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32011L0065&from=en. Accessed 15 May 2022

  14. Bi X, Simoneit BRT, Wang ZZ, Wang X, Sheng G, Fu J (2010) The major components of particles emitted during recycling of waste printed circuit boards in a typical e-waste workshop of South China. Atmos Environ 44:4440–4445

    Article  CAS  Google Scholar 

  15. Asante KA, Agusa T, Biney CA et al (2012) Multi-trace element levels and arsenic speciation in urine of e-waste recycling workers from Agbogbloshie, Accra in Ghana. Sci Total Environ 424:63–73

    Article  CAS  PubMed  Google Scholar 

  16. Tue NM, Katsura K, Suzuki G et al (2014) Dioxin-related compounds in breast milk of women from Vietnamese e-waste recycling sites: levels, toxic equivalents and relevance of non-dietary exposure. Ecotoxicol Environ Saf 106:220–225

    Article  CAS  PubMed  Google Scholar 

  17. Tang Z, Zhang L, Huang Q et al (2015) Contamination and risk of heavy metals in soils and sediments from a typical plastic waste recycling area in North China. Ecotoxicol Environ Saf 122:343–351

    Article  PubMed  Google Scholar 

  18. Song Q, Li J (2014) Environmental effects of heavy metals derived from the e-waste recycling activities in China: a systematic review. Waste Manag 34:2587–2594

    Article  CAS  PubMed  Google Scholar 

  19. Bridson JH, Gaugler EC, Smith DA, Northcott GL, Gaw S (2021) Leaching and extraction of additives from plastic pollution to inform environmental risk: a multidisciplinary review of analytical approaches. J Hazard Mater 414:125571

    Article  CAS  PubMed  Google Scholar 

  20. Ong HT, Samsudin H, Soto-Valdez H (2020) Migration of endocrine-disrupting chemicals into food from plastic packaging materials: an overview of chemical risk assessment, techniques to monitor migration, and international regulations. Crit Rev Food Sci Nutr 62:1–23

    Google Scholar 

  21. Warzecha E, Herman SM, Arnold E et al (2023) Determination of distribution coefficients of 41 elements in nitric and hydrochloric acids for actinide resin. J Radioanal Nucl Chem 332:2785–2791

    Article  CAS  Google Scholar 

  22. Wu F, Huang H, Sun X et al (2023) Persimmon tannin-modified graphene oxide/chitosan microsphere for removing U(VI) in rare earth wastewater. J Radioanal Nucl Chem 332:3617–3633

    Article  CAS  Google Scholar 

  23. Fletcher N, Manard BT, Metzger SC, Ticknor BW, Bostick DA, Hexel CR (2020) Determining P, S, Br, and I content in uranium by triple quadrupole inductively coupled plasma mass spectrometry. J Radioanal Nucl Chem 324:395–402

    Article  CAS  Google Scholar 

  24. Bootharajan M, Hemalatha V, Vithya J et al (2023) Pyrohydrolytic separation of fluoride and chloride in U–Zr and U–Pu–Zr metallic fuel alloys through oxidation accompanied by estimation using ion chromatography. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-023-09156-0

    Article  Google Scholar 

  25. Silachyov I, Akymbek Y (2023) Element content of the samples of medieval ceramics from Southern Kazakhstan: searching the way of preliminary differentiation. J Radioanal Nucl Chem 332:3799–3811

    Article  CAS  Google Scholar 

  26. Soliman MA, Abdou FS, Mohamed NM (2020) Novel neutron activation analysis scheme for determination of trace elements in medicinal plants infusion. J Radioanal Nucl Chem 325(841):846

    Google Scholar 

  27. Mohamed GY, Soliman M, Issa SAM, Mohamed NMA, Al-Abyad M (2021) Trace elements assessment and natural radioactivity levels of infant formulas consumed in Egypt. J Radioanal Nucl Chem 330:1127–1136

    Article  CAS  Google Scholar 

  28. Soliman M, Mohamed NMA, Gaheen MA, Saad EA, Yousef SK, Sohsah MA (2011) Implementation of k0-standardization method of the INAA at ETRR-2 research reactor. J Radioanal Nucl Chem 287:629–634

    Article  CAS  Google Scholar 

  29. Soliman MA, Abdou FS, Ho VD, Sekimoto S, Takamiya K, Mohamed NMA, Ohtsuki T (2022) Measurement of neutron flux parameters for implementation of k0-INAA at Kyoto university research reactor. J Radioanal Nucl Chem 331:3949–3956

    Article  CAS  Google Scholar 

  30. Mohamed NMA (2017) Accurate corrections of HPGe detector efficiency for NAA samples. J Radiat Nucl Appl 2:37–43

    Article  Google Scholar 

  31. De Corte F (1987) The k0-standardization method; A move to the optimization of neutron activation analysis. Faculteit van de Wetenschappen, Instituutvoor Nucleaire Wetenschappen, Gent

    Google Scholar 

  32. Kotelnikova AD, Rogova OB, Stolbova VV (2021) Lanthanides in the soil: routes of entry, content, effect on plants, and genotoxicity, a review. Eurasian Soil Sci 54:117–134

    Article  CAS  Google Scholar 

  33. Alam O, Yang L, Yanchun X (2019) Determination of the selected heavy metal and metalloid contents in various types of plastic bags. J Environ Health Sci Eng 17:161–170

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  34. Turner A, Filella M (2023) The role of titanium dioxide on the behaviour and fate of plastics in the aquatic environment. Sci Total Environ 869:161727

    Article  CAS  PubMed  Google Scholar 

  35. Vertes A, Nagy S, Klencsar Z, Lovas RG, Rosch F (eds) (2011) Handbook of nuclear chemistry, 2nd edn. Springer, London, New York

    Google Scholar 

  36. The University of Missouri (2015) Tables for analytical methods at MURR: NAA, XRF and ICP-MS 2015

  37. Buranurak S, Pangza K (2018) Assessment of natural radioactivity levels and radiation hazards of Thai Portland cement brands using gamma spectrometry technique. Mater Today 5:13979–13988

    CAS  Google Scholar 

  38. UNSCEAR (2008) Report to the general assembly. Annex B Exposures of the public and workers from various sources of radiation

  39. Attallah MF, Metwally SS, Moussa SI, Soliman MA (2019) Environmental impact assessment of phosphate fertilizers and phosphogypsum waste: elemental and radiological effects. Microchem J 146:789–797

    Article  CAS  Google Scholar 

  40. European Parliament and Council of the EU (1994) Directive 94/62/EC of 20 December 1994 on packaging and packaging waste. Off J Eur Union L365

  41. Commission Directive (2002) EC directive 2002/72/EC of 6 August 2002 relating to plastic materials and articles intended to come into contact with foodstuffs. Off J Eur Communities L220/18

  42. Alam O, Billah M, Yajie D (2018) Characteristics of plastic bags and their potential environmental hazards. Resour Conserv Recycl 132:121–129

    Article  Google Scholar 

  43. Markowicz F, Pulikowska AS (2019) Analysis of the possibility of environmental pollution by composted biodegradable and oxo-biodegradable plastics. Geosciences 9:460

    Article  CAS  Google Scholar 

  44. Alam O, Wang S, Lu W (2018) Heavy metals dispersion during thermal treatment of plastic bags and its recovery. J Environ Manag 212:367–374

    Article  CAS  Google Scholar 

  45. Bode P, De Bruin M, Aalbers TG, Meyer PJ (1989) Plastics from household waste as a source of heavy metal pollution: an inventory study using INAA as the analytical technique. Biol Trace Elem Res 26:377–383

    Google Scholar 

  46. Boscaro ME, De Nadai Fernandes EA, Bacchi MA et al (2015) Neutron activation analysis for chemical characterization of Brazilian oxo-biodegradable plastics. J Radioanal Nucl Chem 303:421–426

    Article  CAS  Google Scholar 

  47. ABNT NBR 15448–2 (2008) Degradable and/or renewable plastic packaging–part 2: biodegradation and composting requirements and test methods

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Acknowledgements

This work was funded by the University of Jeddah, Jeddah, Saudi Arabia under grant no. (UJ-22-DR-8). The authors, therefore, acknowledge with thanks the University of Jeddah for its technical and financial support.

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University of Jeddah (UJ-22-DR-8).

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Correspondence to Mohamed Soliman.

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Al-Ghamdi, A.H., Mohery, M. & Soliman, M. Determination of chemical elements and natural radionuclides in shopping plastic bags using k0-neutron activation analysis. J Radioanal Nucl Chem 333, 387–394 (2024). https://doi.org/10.1007/s10967-023-09215-6

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