Abstract
Tellurium and selenium isotopes have wide applications in nuclear medicine. In this study, extraction of these elements from copper anode slime is carried out by using the hollow fiber renewal liquid membrane technique (HFRLM). At first batch experiments were carried out by using different concentrations of extractants (TBP, DEHPA, Alamin 336, Cyanex 272), and out of four, TBP 30%(v/v) in 4 M HCl provided the best results. Moreover, more recovery of tellurium ions than selenium is achieved by using HFRLM technology, which reveals the potential of using this method for selective extraction of tellurium with a separation factor higher than 15.
Similar content being viewed by others
References
Grey D (2017) Tellurium properties, uses and research. Nova Science Publishers Inc., New York, p 12
Wadgaonkar SL, Mal J, Nancharaiah YV, Maheshwari NO, Esposito G, Lens PN (2018) Formation of Se (0), Te (0), and Se (0)–Te (0) nanostructures during simultaneous bioreduction of selenite and tellurite in a UASB reactor. Appl Microbiol Biotechnol 102:2899–2911
Fan Y, Yang Y, Xiao Y, Zhao Z, Lei Y (2013) Recovery of tellurium from high tellurium-bearing materials by alkaline pressure leaching process: thermodynamic evaluation and experimental study. Hydrometallurgy 139:95–99
Shibasaki T, Abe K, Takeuchi H (1992) Recovery of tellurium from decopperizing leach solution of copper refinery slimes by a fixed bed reactor. Hydrometallurgy 29:399–412
Li X-j, Yang H-y, Jin Z-n, Tong L-l, Xiao F-x (2017) Selenium leaching from copper anode slimes using a nitric acid–sulfuric acid mixture. Metallurgist 61:348–356
Hoffmann JE (1989) Recovering selenium and tellurium from copper refinery slimes. JOM 41:33–38
Chen T, Dutrizac J (1988) Mineralogical characterization of anode slimes—II. Raw anode slimes from Inco’s copper cliff copper refinery. Can Metall Q 27:97–105
Khosh Khoo Sany SM (2009) Optimisation of influential factors in electrowinning of tellurium by means of PLS modelling
Mahmoudi A, Shakibania S, Mokmeli M, Rashchi F, Karimi HY (2021) Selective separation and recovery of tellurium from copper anode slime using acidic leaching and precipitation with cuprous ion. J Sustain Metall 7:1886–1898
Wang WK, Hoh Y-C, Chuang W-S, Shaw I-S (1981) Hydrometallurgical process for recovering precious metals from anode slime. Google Patents
Hait J, Jana R, Sanyal S (2009) Processing of copper electrorefining anode slime: a review. Miner Process Extr Metall 118:240–252
Wang S (2011) Tellurium, its resourcefulness and recovery. JOM 63:90–93
Cooper WC (1990) The treatment of copper refinery anode slimes. JOM 42:45–49
Liu G, Wu Y, Tang A, Li B (2020) Recovery of scattered and precious metals from copper anode slime by hydrometallurgy: a review. Hydrometallurgy 197:105460
Zahakifar F, Charkhi A, Torab-Mostaedi M, Davarkhah R (2018) Kinetic study of uranium transport via a bulk liquid membrane containing Alamine 336 as a carrier. J Radioanal Nucl Chem 316:247–255
Ren Z, Zhang W, Liu YM, Dai Y, Cui C (2007) New liquid membrane technology for simultaneous extraction and stripping of copper(II) from wastewater. Chem Eng Sci 62:6090–6101
Allahyari SA, Minuchehr A, Ahmadi SJ, Charkhi A (2016) Th(IV) transport from nitrate media through hollow fiber renewal liquid membrane. J Membr Sci 520:374–384
Chakrabarty K (2010) Liquid membrane based technology for removel of pollutants from wastewater
Zhang W, Cui C, Ren Z, Dai Y, Meng H (2010) Simultaneous removal and recovery of copper(II) from acidic wastewater by hollow fiber renewal liquid membrane with LIX984N as carrier. Chem Eng J 157:230–237
Cai W-b, Wang Y-j, Zhu S-l (2003) Mass transfer characteristics of fiber membrane extraction module. J Tsinghua Univ 43:738–741
Sole KC, Ferguson TL, Hiskey JB (1994) Solvent extraction of silver by cyanex 272, cyanex 302 and cyanex 30. Solvent Extr Ion Exch 12:1033–1050
Rickelton WA (1986) Extraction of silver and palladium metals from aqueous solutions using tertiary phosphine sulfides. Google Patents
Abdollahy M (1996) The treatment of Sar-Cheshmeh copper anode slimes. Ph.D. thesis, LeedsUniversity, UK
Li D, Guo Y, Deng T, Chen Y-W, Belzile N (2014) Solvent extraction of tellurium from chloride solutions using tri-n-butyl phosphate: conditions and thermodynamic data. Sci World J. https://doi.org/10.1155/2014/458705
Chowdhury MR, Sanyal SK (1993) Separation by solvent extraction of tellurium(IV) and selenium(IV) with tri-n butyl phosphate: some mechanistic aspects. Hydrometallurgy 32:189–200
Chowdhury MR, Sanyal SK (1994) Diluent effect on extraction of tellurium(IV) and selenium(IV) by tri-n butyl phosphate. Hydrometallurgy 34:319–330
Acknowledgements
The authors would like to thank the Nuclear Science and Technology Organization of Iran for their invaluable contribution to prepare the materials and equipment. B. Richardson, Title of paper, J.Appl. Phys. 20, 2221 (1998).
Funding
The authors did not receive support from any organization for the submitted work.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors have no competing interests to declare that are relevant to the content of this article.
Human and animals rights
All data generated or analyzed during this study doesn’t involve human participants and/or animals.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Yazdani Ahmad Abadi, N., Kheradmand Saadi, M., Charkhi, A. et al. Separation of tellurium and selenium ions from leach liquor of copper anode slime by hollow fiber renewal liquid membrane (HFRLM) technique. J Radioanal Nucl Chem 333, 395–402 (2024). https://doi.org/10.1007/s10967-023-09203-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-023-09203-w