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Determination of environmental gaseous 129I trapped in charcoal cartridges by ICP-MS/MS

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Abstract

For environmental monitoring and radioecological studies, organic and inorganic 129I is often trapped in active charcoal. The analysis of this radionuclide can be difficult because of the low-level activities involved and its physico-chemical properties (e.g., volatility and multiple oxidation degrees). This study proposes a new method for 129I analysis by ICP-MS/MS, which consists in the extraction of iodine from charcoal by acid digestion followed by purification using a commercial specific resin. This new method allows reaching environmental levels of gaseous 129I near the fuel reprocessing plant of La Hague (France) with a limit of detection of only 2 mBq sample−1.

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Authors and Affiliations

  1. Institut de Radioprotection et de Sûreté Nucléaire, PSE-ENV/SAME/LERCA, 31 rue de l’écluse, 78116, Le Vésinet, France

    C. Carrier, A. Habibi & C. Augeray

  2. Institut de Radioprotection et de Sûreté Nucléaire, PSE-ENV/SAME/LMN, 31 rue de l’écluse, 78116, Le Vésinet, France

    L. Ferreux

  3. Institut de Radioprotection et de Sûreté Nucléaire, PSE-ENV/SRTE/LRC, Rue Max Pol Fouchet, 50130, Cherbourg-Octeville, France

    L. Solier, D. Hebert & D. Maro

  4. Institut de Radioprotection et de Sûreté Nucléaire, PSE-ENV/SAME, 31 rue de l’écluse, 78116, Le Vésinet, France

    M. Morin

  5. Aix Marseille Univ, CNRS, Centrale Marseille, M2P2, Technopôle de l’Arbois, 13545, Aix en Provence, France

    L. Benedetti

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  1. C. Carrier
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Carrier, C., Habibi, A., Ferreux, L. et al. Determination of environmental gaseous 129I trapped in charcoal cartridges by ICP-MS/MS. J Radioanal Nucl Chem 332, 2003–2015 (2023). https://doi.org/10.1007/s10967-023-08845-0

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