Abstract
We describe the preparation of actinide targets at Oregon State University. The preparation of the actinide fluorides is done by an aqueous precipitation procedure with yields of greater than 90%. A dual glove box system is used for the preparation of the fluorides of the high specific activity actinides and the subsequent vapor deposition. We compare and contrast targets made by vapor deposition and molecular plating. We discuss some new data on the structure of actinide targets.
Similar content being viewed by others
References
Daw HT (1989) Guidelines for the radiation protection of workers in industry (ionizing radiations). ILO, Geneva. ISBN: 9221064425
Silveira MJ, Pica A, Loveland W (2020) The vapor deposition of high specific activity actinides Nucl Instrum Meth A DOI https://doi.org/10.1016/j.nima.2020.164570
Loveland W (2016) High quality actinide targets. J Radioanal Nucl Chem DOI. https://doi.org/10.1007/s10967-015-4337-5
Sibbens G et al (2018) Morphological and compositional study of 238U thin film targets for nuclear experiments AIP Conf Proc DOI https://doi.org/10.1063/1.5035524
Vascon A et al (2012) Elucidation of constant current density molecular plating Nucl Instrum Meth A DOI https://doi.org/10.1016/j.nima.2012.08.072
Sadi S, Paulenova A, Watson PR, Loveland W (2011) Growth and surface morphology of uranium films during molecular plating DOI https://doi.org/10.1016/j.nima.2011.06.025
Vascon A et al (2013) The performance of thin layers produced by molecular plating as a-particle sources Nucl Instrum Meth A DOI https://doi.org/10.1016/j.nima.2013.04.050
Mayorov DA, Tereshatov EE, Werke TA, Frey MM, Folden III (2017) CM Heavy-ion beam induced effects in enriched gadolinium target films prepared by molecular plating Nucl Instrum Meth B DOI https://doi.org/10.1016/j.nimb.2017.07.012
Ziegler JF, Ziegler MD, Biersack JP (2010) SRIM – the stopping and range of ions in matter (2010) Nucl Instrum Meth B DOI https://doi.org/10.1016/j.nimb.2010.02.091
Interactions of ions with matter http://srim.org/ Accessed 21 Apr 2021
Rangelib -dE/dx and range C/C + + library https://sourceforge.net/projects/rangelib/ Accessed 21 Apr 2021
Northcliffe LC, Schilling RF(1970) At Data and Nucl Data Tables DOI https://doi.org/10.1016/S0092-640X(70)80016-X
Chemey A et al (2020) Total kinetic energy an dmass yields from the fast neutron-induced fission of 239Pu. Eur Phys J A. DOI https://doi.org/10.1140/epja/s10050-020-00295-6
Allen RJ, Petrow HG, Magno PJ (1958) Precipitation of uranium tetrafluoride from aqueous solution by catalytic reduction. Ind Eng Chem DOI. https://doi.org/10.1021/ie50588a029
Ralphs DL(1952) The mechanism of carrying Pu(III) on lanthanum fluoride. Oregon State University thesis, Corvallis, OR
Dawson JK, Elliott RM, Hurst R, Truswell AE (1954) The preparation and some properties of plutonium fluorides. J Chem Soc DOI. https://doi.org/10.1039/JR9540000558
Borsook H, Keighley G (1933) Oxidation-reduction potential of ascorbic acid (Vitamin C). Proc Nat Acad Sci DOI. https://doi.org/10.1073/pnas.19.9.875
Choppin GR, Jensen MP (2006) In: Morss LR, Edelstein NM, Fuger J (eds) The chemistry of the actinide and transactinide elements, 4th edn. Springer, Dordrecht, Netherlands
Lommel B et al(2008) Backing and targets for chemical and nuclear studies of transactinides with TASCA Nucl Instrum Meth A DOI 10.16/j.nima.2008.02.045
Brown D (1968) Halides of the Lanthanides and Actinides. Wiley, New York
Chitnis RT, Talnikar SG, Bhogale RG, Patil SK (1979) Controlled-potential coulometric studies on fluoride complexing of plutonium(IV). J Radioanal Nucl Chem DOI. https://doi.org/10.1007/BF02519941
Hobart DE(1981) Electrochemical and spectroscopic studies of some less stable oxidation states of selected lanthanide and actinide elements. University of Tennessee dissertation, Knoxville, TN
Claux B, Beneš O, Capelli E, Souček P, Meier R (2016) On the fluorination of plutonium dioxide by ammonium hydrogen fluoride. J Fluor Chem DOI. https://doi.org/10.1016/j.jfluchem.2015.12.009
Zachariasen WH (1949) Crystal chemical studies of the 5f-series of elements. XII New compounds representing known structure types Acta Cryst DOI. https://doi.org/10.1107/S0365110X49001016
PDF-4+ - ICDD Phase Identification and Quantification. https://www.icdd.com/pdf-4/ Accessed 21 Apr 2022
Acknowledgements
We gratefully acknowledge the financial support of the LLNL, USA, SSAA, USA, LANL, USA, and the Department of Energy, USA DE-SC0014380 (US DOE). Additionally, ATC acknowledges startup support from the Oregon State University School of Nuclear Science and Engineering.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Chemey, A.T., Pica, A., Loveland, W.D. et al. Preparation of Actinide Targets at Oregon State University. J Radioanal Nucl Chem 331, 5101–5106 (2022). https://doi.org/10.1007/s10967-022-08610-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-022-08610-9