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Investigation on the magnetic and Mössbauer spectroscopy of 57Fe doped LiMnPO4

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Abstract

The 57Fe doped LiMnPO4 cathode with potential applications in Li-ion batteries was prepared by solid-state reaction. The magnetic susceptibility ordered antiferromagnetically at Néel temperature (TN = 34 K). The spin reorientation temperature (TS) and effective moment were determined to be 8 K and 5.78 μB. We obtained the Mössbauer spectra at various temperatures and fitted the spectra below TN to eight absorption lines. The behavior of the magnetic hyperfine field and the quadrupole splitting change with increasing temperature above TS indicates that the quenched orbital angular moment is due to a strong crystal field at the Mn(Fe)O6 site.

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Acknowledgements

This work was supported by Mid-Career Researcher Program, through the National Research Foundation of Korea (NRF), with a Grant funded by the Ministry of Education, Science and Technology (MEST) (NRF-2017R1A2B2012241).

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  1. Department of Physics, Kookmin University, Seoul, 02707, Republic of Korea

    Hyunkyung Choi, Jae Yeon Seo & Chul Sung Kim

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  1. Hyunkyung Choi
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  2. Jae Yeon Seo
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  3. Chul Sung Kim
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Correspondence to Chul Sung Kim.

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Choi, H., Seo, J.Y. & Kim, C.S. Investigation on the magnetic and Mössbauer spectroscopy of 57Fe doped LiMnPO4. J Radioanal Nucl Chem 330, 461–467 (2021). https://doi.org/10.1007/s10967-021-07836-3

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  • DOI: https://doi.org/10.1007/s10967-021-07836-3

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