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Magnetic properties of double perovskite Ca2FeMoO6 by neutron diffraction and Mössbauer spectral studies

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Abstract

Crystallographic and magnetic properties of the double perovskite oxide Ca2FeMoO6 were studied. The single phase polycrystalline Ca2FeMoO6 powder was prepared by a solid-state reaction method. The crystal structure of the Ca2FeMoO6 is found to be monoclinic with lattice constants a0 = 5.4056 Å, b0 = 5.5170 Å, c0 = 7.6971 Å, and β = 89.92°. The Mössbauer spectra have been taken at various temperatures ranging from 17 to Curie temperature (TC) was found to be 350 K. The isomer shift value at room temperature is 0.43 mm/s relative to the Fe metal that are consistent with the Fe3+ valence state. Hyperfine parameters of the Mössbauer spectra were analyzed as a function of temperature and observed the magnetic properties with crystallographic changes through neutron diffraction experiments.

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References

  1. Kobayashi K-I, Kimura T, Sawada H, Terakura K, Tokura Y (1998) Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure. Nature 395:677–680

    Article  CAS  Google Scholar 

  2. Maignan A, Raveau B, Martin C, Hervieu M (1999) Large intragrain magnetoresistance above room temperature in the double perovskite Ba2FeMoO6. J Solid State Chem 144:224–227

    Article  CAS  Google Scholar 

  3. Kim SB, Park KT, Kim CS (2001) Anisotropic hyperfine field fluctuation in Sr2FeMoO6. J Appl Phys 89:7681–7683

    Article  CAS  Google Scholar 

  4. Tomioka Y, Okuda T, Okimoto Y, Kumai R, Kobayashi K-I, Tokura Y (2000) Magnetic and electric properties of a single crystal of ordered double perovskite Sr2FeMoO6. Phys Rev B 61:1–6

    Article  Google Scholar 

  5. Kim SB, Hahn EJ, Kim SS (2019) Crystallographic and magnetic properties of double perovskite oxide Ba2-xSrxFeMoO6. J Korean Phys Soc 75:466–470

    Article  CAS  Google Scholar 

  6. Dabrowski B, Chmaissem O, Mais J, Kolensnik S, Jorgensen JD, Short S (2003) Tolerance factor rules for Sr1-x-yCaxBayMnO3 perovskites. J Solid State Chem 170:154–164

    Article  CAS  Google Scholar 

  7. Pinsard-Gaudart L, Surynarayanan R, Revcoevschi A, Rodriguez-Carvajal J, Greneche J-M, Smith PAI, Thomas RM, Borges RP, Coey JMD (2000) Ferrimagnetic order in Ca2FeMoO6. J Appl Phys 87:7118–7120

    Article  CAS  Google Scholar 

  8. Galasso FS (1970) Structure and properties of inorganic solids. Pergamon Press Inc., New York

    Google Scholar 

  9. Nakayama S, Nakagawa T, Nomura S (1967) Neutron diffraction study of Sr2(FeMo)O6. J Phys Soc Jpn 24:219–220

    Article  Google Scholar 

  10. Kim CS, Ko HM, Lee WH, Lee CS (1993) Site preference for Zn2+ and Ge4+ in mixed ferrite ZnxGe1-xFe2O4. J Appl Phys 73:6298–6300

    Article  CAS  Google Scholar 

  11. Kim CS, Kim DY, Ko HM, Kim JK (1993) Crystallographic and magnetic properties of the spinel phase for NixFe1-xCr2S4. J Appl Phys 73:6986–6988

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This paper was supported by the Konyang University Research Fund and Mid-Career Researcher Program, through the National Research Foundation of Korea (NRF), with a grant funded by the Ministry of Education, Science and Technology (MEST) (NRF-2017R1A2B2012241).

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Authors and Affiliations

  1. Department of Biomedical Materials, Konyang University, Daejeon, 35365, Korea

    Sung Baek Kim

  2. Department of Physics, Kookmin University, Seoul, 02707, Korea

    Chul Sung Kim

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  1. Sung Baek Kim
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  2. Chul Sung Kim
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Correspondence to Sung Baek Kim.

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Kim, S.B., Kim, C.S. Magnetic properties of double perovskite Ca2FeMoO6 by neutron diffraction and Mössbauer spectral studies. J Radioanal Nucl Chem 330, 439–443 (2021). https://doi.org/10.1007/s10967-021-07781-1

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  • DOI: https://doi.org/10.1007/s10967-021-07781-1

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