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Silver-doped MIL-101(Cr) for rapid and effective capture of iodide in water environment: exploration on adsorption mechanism

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Abstract

To effectively protect the marine ecological environment, herein, the silver-loaded organometallic framework material ((MIL-101(Cr)@Ag) was synthesized to study the rapid enrichment of iodide ions. Under the best experimental conditions, the reaction was in adsorption equilibrium within 10 min, and the maximum adsorption capacity could attain 57 mg/g. The XPS and XRD analysis indicated that the iodide ions mainly interacted with silver atoms in MIL-101(Cr)@Ag to form AgI. The adsorption behavior was well fitted by the pseudo-second-order kinetic model and Langmuir isotherm model, showed that adsorption process was mainly monolayer chemisorption. Therefore, MIL-101(Cr)@Ag could be used as a potential material for removing iodide ions from aqueous solutions.

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Acknowledgements

This work was supported in part of the project titled “The National Key Project of Research and Development Plan” (Grant No. 2016YFC1402504). The authors thank the funding source of this research and the research platform provided by Wuhan University of technology.

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  1. School of Resources and Environment Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, 430070, Hubei, China

    Jie Wan, Ye Li, Yumeng Jiang, Luyao Lin & Yixin Yin

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Wan, J., Li, Y., Jiang, Y. et al. Silver-doped MIL-101(Cr) for rapid and effective capture of iodide in water environment: exploration on adsorption mechanism. J Radioanal Nucl Chem 328, 1041–1054 (2021). https://doi.org/10.1007/s10967-021-07705-z

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