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Synthesis of diamide-based resin for selective separation of 99Tc

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Abstract

N,N,N′,N′-tetramethylmalonamide (TMMA) has been successfully grafted onto the chloroacetylated poly(styrene-co-divinylbenzene) resin to obtain a novel diamide-based resin (PS–TMMA). PS–TMMA exhibited high adsorption capacity and selectivity toward TcO4− in 0.1–1 M HCl. The adsorption process of PS–TMMA conforms (Revise: conformed) to Langmuir isotherm and pseudo-second-order kinetics model. The results of column experiments revealed TcO4− can be completely separated from the coexisting fission products (Sr(II), Eu(III), Dy(III), and 1 M NH3·H2O can re-collect TcO4− absorbed in the resin column. The adsorption mechanism of TcO4− is considered that PS–TMMA is converted into anion exchange resin in acidic condition.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 11975152, 11675103, 91226111).

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Authors and Affiliations

  1. School of Nuclear Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Lingxiao Fu, Xiaohan Pan & Jianhua Zu

  2. Shanghai Institute of Measurement and Testing Technology, Shanghai, 201203, China

    Linfeng He

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  1. Lingxiao Fu
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Correspondence to Jianhua Zu.

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Fu, L., Pan, X., Zu, J. et al. Synthesis of diamide-based resin for selective separation of 99Tc. J Radioanal Nucl Chem 328, 481–490 (2021). https://doi.org/10.1007/s10967-021-07601-6

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