Abstract
The removal of Co2+ in aqueous solution by spent green tealeaves (SGTL) was studied in batch conditions. The bio-sorbent was characterized by the infrared spectroscopy, Boehm’s titration and by pHpzc. The optimum pH value was found in the range of 4 to 6. The sorption was fast, obeyed the pseudo second order model, and favored at low temperature. The bio-sorption capacity recorded a rate of 83.52% using 0.25 g of SGTL. The isotherm followed the Langmuir model. The Co2+ bio-sorption is exothermic, reversible and favorable and that it was carried out by physic sorption with low activation energy.
Similar content being viewed by others
References
Ghada MR, Mamdoh RM, Ahmed ME, Essam M, Ebtissam AS (2016) Removal of radiocobalt from aqueous solutions by adsorption onto low-cost adsorbents. J Radioanal Nucl Chem 309:1065–1076
Josilene AVR, Luide RM, Laís MF, Amália LPX, Francine TRA, Ana LSLM, Tânia MSM, Laurent FG, Leandro VAG (2020) Oxidized renewable materials for the removal of cobalt(II) and copper(II) from aqueous solution using in batch and fixed-bed column adsorption. Adv Polym Technol. https://doi.org/10.1155/2020/8620431
Metwally SS, Ayoub RR, Aly HF (2014) Utilization of low-cost sorbent for removal and separation of 134Cs, 60Co and 152 + 154Eu radionuclides from aqueous solution. J Radioanal Nucl Chem 302:441–449
Martin P, Barbora M, Eková R, Vladimír F, Miroslav H, Lucia R, Richard S, Gerhard S (2017) Sorption separation of cobalt and cadmium by straw-derived biochar: a radiometric study. J Radioanal Nucl Chem 311:85–97
Samir BE, Talat AB (2015) Biosorption of 137Cs and/or 60Co from radioactive waste solution simulates using spent black tea (camellia sinensis) dregs. Int J Mater Chem Phys 1(3):333–342
Juan FCG, Adriana SRP, Juan MVM, Víctor MMJ, Ismael AR, Christian MC, Gustavo GF, Milka EEC, Alejandra MM (2019) Bioremoval of cobalt(II) from aqueous solution by three different and resistant fungal biomasses. Bioinorg Chem Appl. https://doi.org/10.1155/2019/8757149
Youness E, Ahmed L, Elhoussein R, Lamya K, Abdelkarim O (2018) Adsorption of cobalt from aqueous solutions onto Bark of Eucalyptus. Mediterr J Chem 7(2):145–155
Amna Y, Makshoof A, Muhammad S, Umar F, Nouman M, Zoya Z, Mahnoor S (2018) Biosorptive removal of cobalt from aqueous solution by using native and thiourea modified Pennisetum glaucum. Desalin Water Treat 103:199–207
Fengbo L, Zhimo G, Xiaoyu L, Lejin F (2014) The effect of environmental factors on the uptake of 60Co by Paecilomyces catenlannulatus. J Radioanal Nucl Chem 299:1281–1286
Food and Agriculture Organization of the United Nations. http://www.fao.org/news/story/fr/item/1136354/icode/
Li L, Shisuo F, Yang L (2018) Removal behavior of methylene blue from aqueous solution by tea waste: kinetics, isotherms and mechanism. Int J Environ Res Public Health 15(7):1321. https://doi.org/10.3390/ijerph15071321
Muhammad M, Isa MT, Lukman I, Muhammad N, Muhammad S, Rizwan A, Rehan H (2014) Influence of PZC (point of zero charge) on the static adsorption of anionic surfactants on a Malaysian Sandstone. J Dispersion Sci Technol 35:343–349
Lopez-Ramon MV, Stoeckli F, Moreno-Castilla C, Carrasco-Marin F (1999) On the characterization of acidic and basic surface sites on carbons by various techniques. Carbon 37:1215–1221
Ding DX, Liu XT, Hu N, Li GY, Wang YD (2012) Removal and recovery of uranium from aqueous solution by tea waste. J Radioanal Nucl Chem 293:735–741
Aguedal H, Imessaoudene D, Merouani DR, Boulahdid M, Bouzidi A, Boukortt R (2018) Biosorption du cesium en solution aqueuse par une algue marine invasive: caulerpa racemosa. Afr Rev Sci Technol Dev 03(02):46–53
Thaera AMA, Faliah HAA, Ahmed AA, Sameera AAR (2016) Effects of contact time, initial cobalt ion concentration, ph, and biosorbent dosage of surface orange peel and maize agro-waste adsorbents to remove cobalt from water. IJRPC 6(2):185–191
Hassan HS, Imam DM, Kenawy SH, El-Bassyouni GT, Hamzawy EMA (2019) Sorption of radioactive cobalt onto nano calcium silicate/CuO composite modified by humic acid. J Radioanal Nucl Chem 321:391–401
Dekhil AB, Hannachi Y, Ghorbel A, Taoufik B (2011) Removal of lead and cadmium ions from aqueous solutions using the macro alga caulerpa racemosa. Chem Ecol 27(3):221–234
Chang Q (2016) Surf Solids. https://doi.org/10.1016/b978-0-12-809315-3.00010-4
Yehua Z, Jun H, Jianlong W (2014) Removal of Co2+ from radioactive wastewater by polyvinyl alcohol (PVA)/chitosan magnetic composite. Prog Nucl Energy 71:172–178
Rangabhashiyam S, Balasubramanian P (2019) Characteristics, performances, equilibrium and kinetic modeling aspects of heavy metal removal using algae. Bioresour Technol Rep 5:261–279
Annadurai G, Juang RS, Lee DJ (2003) Adsorption of heavy metals from water using banana and orange peels. Water Sci Technol 47(1):185–190
Imessaoudene D, Hanini S, Bouzidi A, Ararem A (2016) Kinetic and thermodynamic study of cobalt adsorption by spent coffee. Desalin Water Treat 57:6116–6123
Abdelfattah I, Ismail AA, Alsayed F, Almedolab A, Aboelghait KM (2016) Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent. Environ Nanotechnol Monit Manag 6:176–183
Saad AA (2010) Equilibrium study of adsorption of cobalt ions from wastewater using Saoudi roasted date pits. Res J Environ Toxicol 4(1):1–12
Dildar A, Abid H, Riaz A (2018) Lagenaria siceraria peel biomass as a potential biosorbent for the removal of toxic metals from industrial wastewaters. Int J Environ Stud 75(5):763–773
Parab H, Joshi S, Sudersanan M, Shenoy N, Lali A, Sarma U (2010) Removal and recovery of cobalt from aqueous solutions by adsorption using low cost lignocellulosic biomass-coir pith. J Environ Sci Health Part A Toxic Hazard Subst Environ Eng 45:603–611
Mohapatra M, Khatun S, Anand S (2009) Kinetics and thermodynamics of lead(II) adsorption on lateritic nickel ores of Indian origin. Chem Eng J 155:184–190
Acknowledgements
The project is fully sponsored by Algerian Atomic Energy Commission.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Imessaoudene, D., Bensacia, N. & Chenoufi, F. Removal of cobalt(II) from aqueous solution by spent green tealeaves. J Radioanal Nucl Chem 324, 1245–1253 (2020). https://doi.org/10.1007/s10967-020-07183-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-020-07183-9