Skip to main content
Log in

Adsorption performance of U(VI) by amidoxime-based activated carbon

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

We present a simple strategy for preparing amidoxime modified activated carbon. The composition and morphology of the materials have been confirmed via powder XRD, BET, TGA, SEM and FT-IR studies. Batch adsorption experiment were exploited to explore adsorption performance of U(VI) by amidoxime-based activated carbon. The adsorption capacity of activated carbon was significantly improved after the modification by amidoxime, the amidoxime-based activated carbon was a possible adsorbent for adsorbing U(VI). This study reveals that with a facile synthesis and low-cost, amidoxime-based activated carbon can be regarded as a promising material for uranium-containing wastewater treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Wu F, Pu N, Ye G, Sun T, Wang Z, Song Y, Wang W, Huo X, Lu Y, Chen J (2017) Performance and mechanism of uranium adsorption from seawater to poly(dopamine)-inspired sorbents. Environ Sci Technol 51(8):4606–4614

    Article  CAS  PubMed  Google Scholar 

  2. Xiao J, Jing Y, Yao Y, Wang X, Jia Y (2019) Synthesis of amidoxime-decorated 3d cubic mesoporous silica via self-assembly co-condensation as a superior uranium(VI) adsorbent. J Mol Liq 277:843–855

    Article  CAS  Google Scholar 

  3. Wang D, Xu Y, Xiao D, Qiao Q, Yin P, Yang Z, Li J, Winchester W, Wang Z, Hayat T (2019) Ultra-thin iron phosphate nanosheets for high efficient U(VI) adsorption. J Hazard Mater 371:83–93

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  4. Wang Y, Huang H, Duan S, Liu X, Sun J, Hayat T, Alsaedi A, Li J (2017) A new application of a mesoporous hybrid of tungsten oxide and carbon as an adsorbent for elimination of \({\text{ Sr}^{2+}}\) and \({\text{ Co}^{2+}}\) from an aquatic environment. ACS Sustain Chem Eng 6(2):2462–2473

    Article  CAS  Google Scholar 

  5. Zhao Y, Wang X, Li J, Wang X (2015) Amidoxime functionalization of mesoporous silica and its high removal of U(VI). Polym Chem 6(30):5376–5384

    Article  CAS  Google Scholar 

  6. Yuan D, Chen L, Xiong X, Yuan L, Liao S, Wang Y (2016) Removal of uranium(VI) from aqueous solution by amidoxime functionalized superparamagnetic polymer microspheres prepared by a controlled radical polymerization in the presence of DPE. Chem Eng J 285:358–367

    Article  CAS  Google Scholar 

  7. Zhang M, Gao Q, Yang C, Pang L, Wang H, Li H, Li R, Xu L, Xing Z, Hu J et al (2016) Preparation of amidoxime-based nylon-66 fibers for removing uranium from low-concentration aqueous solutions and simulated nuclear industry effluents. Ind Eng Chem Res 55(40):10523–10532

    Article  CAS  Google Scholar 

  8. Zhao C, Liu J, Yuan G, Liu J, Zhang H, Yang J, Yang Y, Liu N, Sun Q, Liao J (2018) A novel activated sludge-graphene oxide composites for the removal of uranium(VI) from aqueous solutions. J Mol Liq 271:786–794

    Article  CAS  Google Scholar 

  9. Fan Qh, Li P, Yf Chen, Ws Wu (2011) Preparation and application of attapulgite/iron oxide magnetic composites for the removal of U(VI) from aqueous solution. J Hazard Mater 192(3):1851–1859

    Article  CAS  PubMed  Google Scholar 

  10. Zhao G, Huang X, Tang Z, Huang Q, Niu F, Wang X (2018) Polymer-based nanocomposites for heavy metal ions removal from aqueous solution: a review. Polym Chem 9(26):3562–3582

    Article  CAS  Google Scholar 

  11. Yin L, Song S, Wang X, Niu F, Ma R, Yu S, Wen T, Chen Y, Hayat T, Alsaedi A et al (2018) Rationally designed core-shell and yolk-shell magnetic titanate nanosheets for efficient U(VI) adsorption performance. Environ Pollut 238:725–738

    Article  CAS  PubMed  Google Scholar 

  12. Bq Lu, Li M, Xw Zhang, Huang Cm Wu, Xy Fang Q (2018) Immobilization of uranium into magnetite from aqueous solution by electrodepositing approach. J Hazard Mater 343:255–265

    Article  CAS  Google Scholar 

  13. Dutta DP, Nath S (2018) Low cost synthesis of \({\text{SiO}_{2} /\text{ C }}\) nanocomposite from corn cobs and its adsorption of uranium(VI), chromium(VI) and cationic dyes from wastewater. J Mol Liq 269:140–151

    Article  CAS  Google Scholar 

  14. Ma D, Hu S, Li Y, Xu Z (2019) Adsorption of uranium on phosphoricacid-activated peanut shells. Sep Sci Technol. https://doi.org/10.1080/01496395.2019.1606016

    Article  Google Scholar 

  15. Zhao Y, Liu C, Feng M, Chen Z, Li S, Tian G, Wang L, Huang J, Li S (2010) Solid phase extraction of uranium(VI) onto benzoylthiourea-anchored activated carbon. J Hazard Mater 176(1–3):119–124

    Article  CAS  PubMed  Google Scholar 

  16. Starvin A, Rao TP (2004) Solid phase extractive preconcentration of uranium(VI) onto diarylazobisphenol modified activated carbon. Talanta 63(2):225–232

    Article  CAS  PubMed  Google Scholar 

  17. Saleh TA, Tuzen M, Sarı A et al (2017) Polyethylenimine modified activated carbon as novel magnetic adsorbent for the removal of uranium from aqueous solution. Chem Eng Res Des 117:218–227

    Article  CAS  Google Scholar 

  18. Xie L, Wang Y, Wang Y, Li X, Tian Q, Liu D, Sun G, Wang X (2018) Study of poly(acrylamidoxime) brushes conformation with uranium adsorption by neutron reflectivity. Mater Lett 220:47–49

    Article  CAS  Google Scholar 

  19. Ladshaw AP, Wiechert AI, Das S, Yiacoumi S, Tsouris C (2017) Amidoxime polymers for uranium adsorption: influence of comonomers and temperature. Materials 10(11):1268

    Article  PubMed Central  CAS  Google Scholar 

  20. Bai J, Yao H, Fan F, Lin M, Zhang L, Ding H, Lei F, Wu X, Li X, Guo J et al (2010) Biosorption of uranium by chemically modified rhodotorula glutinis. J Environ Radioact 101(11):969–973

    Article  CAS  PubMed  Google Scholar 

  21. Wang Y, Wang Z, Ang R, Yang J, Liu N, Liao J, Yang Y, Tang J (2015) Synthesis of amidoximated graphene oxide nanoribbons from unzipping of multiwalled carbon nanotubes for selective separation of uranium(VI). RSC Adv 5(108):89309–89318

    Article  CAS  Google Scholar 

  22. Wang X, Ji G, Zhu G, Song C, Zhang H, Gao C (2019) Surface hydroxylation of SBA-15 via alkaline for efficient amidoxime-functionalization and enhanced uranium adsorption. Sep Purif Technol 209:623–635

    Article  CAS  Google Scholar 

  23. Zhang Z, Dong Z, Wang X, Ying D, Niu F, Cao X, Wang Y, Hua R, Liu Y, Wang X (2018) Ordered mesoporous polymer-carbon composites containing amidoxime groups for uranium removal from aqueous solutions. Chem Eng J 341:208–217

    Article  CAS  Google Scholar 

  24. Aljarrah M, Al-Harahsheh MS, Mayyas M, Alrebaki M (2018) In situ synthesis of quaternary ammonium on silica-coated magnetic nanoparticles and it’s application for the removal of uranium(VI) from aqueous media. J Environ Chem Eng 6(5):5662–5669

    Article  CAS  Google Scholar 

  25. Li W, Liu Q, Liu J, Zhang H, Li R, Li Z, Jing X, Wang J (2017) Removal U(VI) from artificial seawater using facilely and covalently grafted polyacrylonitrile fibers with lysine. Appl Surf Sci 403:378–388

    Article  CAS  Google Scholar 

  26. Ma F, Dong B, Gui Y, Cao M, Han L, Jiao C, Lv H, Hou J, Xue Y (2018) Adsorption of low-concentration uranyl ion by amidoxime polyacrylonitrile fibers. Ind Eng Chem Res 57(51):17384–17393

    Article  CAS  Google Scholar 

  27. Xie CY, Jing SP, Wang Y, Lin X, Bao HL, Guan CZ, Jin C, Wang JQ (2017) Adsorption of uranium(VI) onto amidoxime-functionalized ultra-high molecular weight polyethylene fibers from aqueous solution. Nucl Sci Technol 28(7):94

    Article  Google Scholar 

  28. Heshmati H, Torab-Mostaedi M, Ghanadzadeh Gilani H, Heydari A (2015) Kinetic, isotherm, and thermodynamic investigations of uranium(VI) adsorption on synthesized ion-exchange chelating resin and prediction with an artificial neural network. Desalination Water Treat 55(4):1076–1087

    Article  CAS  Google Scholar 

  29. Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP (2017) Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review. Water Res 120:88–116

    Article  CAS  PubMed  Google Scholar 

  30. Wei X, Liu Q, Zhang H, Liu J, Chen R, Li R, Li Z, Liu P, Wang J (2018) Rapid and efficient uranium(VI) capture by phytic acid/polyaniline/\(\text{ FeOOH }\) composites. J Colloid Interface Sci 511:1–11

    Article  CAS  PubMed  Google Scholar 

  31. Guibal E, Milot C, Tobin JM (1998) Metal-anion sorption by chitosan beads: equilibrium and kinetic studies. Ind Eng Chem Res 37(4):1454–1463

    Article  Google Scholar 

  32. Freundlich H (1907) Über die adsorption in lösungen. Z Phys Chem 57(1):385–470

    CAS  Google Scholar 

  33. Yang P, Liu Q, Liu J, Chen R, Li R, Bai X, Wang J (2019) Highly efficient immobilization of uranium(VI) from aqueous solution by phosphonate-functionalized dendritic fibrous nanosilica (DFNS). J Hazard Mater 363:248–257

    Article  CAS  PubMed  Google Scholar 

  34. Dabrowski A (2001) Adsorption-from theory to practice. Adv Colloid Interface Sci 93(1–3):135–224

    Article  CAS  PubMed  Google Scholar 

  35. Yin Z, Xiong J, Chen M, Hu S, Cheng H (2016) Recovery of uranium(VI) from aqueous solution by amidoxime functionalized wool fibers. J Radioanal Nucl Chem 307(2):1471–1479

    Article  CAS  Google Scholar 

  36. Hazer O, Kartal Ş (2010) Use of amidoximated hydrogel for removal and recovery of U(VI) ion from water samples. Talanta 82(5):1974–1979

    Article  CAS  PubMed  Google Scholar 

  37. Duan S, Xu X, Liu X, Wang Y, Hayat T, Alsaedi A, Meng Y, Li J (2018) Highly enhanced adsorption performance of U(VI) by non-thermal plasma modified magnetic \({\text{Fe}_{3}\text{O}_{4}}\) nanoparticles. J Colloid Interface Sci 513:92–103

    Article  CAS  PubMed  Google Scholar 

  38. Imam EA, El-Sayed IET, Mahfouz MG, Tolba AA, Akashi T, Galhoum AA, Guibal E (2018) Synthesis of \(\alpha\)-aminophosphonate functionalized chitosan sorbents: effect of methyl vs phenyl group on uranium sorption. Chem Eng J 352:1022–1034

    Article  CAS  Google Scholar 

  39. Zhang Z, Duan S, Chen H, Zhang F, Hayat T, Alsaedi A, Li J (2018) Synthesis of porous magnetic \({\text{Ni}_{0.6}\text{Fe}_{2.4}\text{O}_{4}}\) nanorods for highly efficient adsorption of U(VI). J Chem Eng Data 63(5):1810–1820

    Article  CAS  Google Scholar 

  40. Li P, Wang J, Wang X, He B, Pan D, Liang J, Wang F, Fan Q (2018) Arsenazo-functionalized magnetic carbon composite for uranium(VI) removal from aqueous solution. J Mol Liq 269:441–449

    Article  CAS  Google Scholar 

  41. Yang P, Zhang H, Liu Q, Liu J, Chen R, Yu J, Hou J, Bai X, Wang J (2019) Nano-sized architectural design of multi-activity graphene oxide (GO) by chemical post-decoration for efficient uranium(VI) extraction. J Hazard Mater 375:320–329

    Article  CAS  PubMed  Google Scholar 

  42. Sun Y, Shao D, Chen C, Yang S, Wang X (2013) Highly efficient enrichment of radionuclides on graphene oxide-supported polyaniline. Environ Sci Technol 47(17):9904–9910

    Article  CAS  PubMed  Google Scholar 

  43. Nakkeeran E, Selvaraju N (2017) Biosorption of chromium(VI) in aqueous solutions by chemically modified strychnine tree fruit shell. Int J Phytorem 19(12):1065–1076

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge support from the Foundation of Heilongjiang Postdoctoral Science Foundation (LBH-Z17050), the China Postdoctoral Science Foundation (2019M651257), the National Natural Science Foundation of China (21771045), the Fundamental Research Funds for the Central Universities (3072019CFJ1501), and the Decommissioning of Nuclear Facilities and special funds for radioactive waste management ([2017]955). And the authors acknowledged the Innovation Center of Nuclear Materials for National Defense Industry.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fuqiu Ma.

Ethics declarations

Conflicts of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, P., Yu, Q., Xue, Y. et al. Adsorption performance of U(VI) by amidoxime-based activated carbon. J Radioanal Nucl Chem 324, 813–822 (2020). https://doi.org/10.1007/s10967-020-07111-x

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-020-07111-x

Keywords

Navigation