Abstract
The variable values of 226Ra, 228Ra and 40K were identified in coal and coal combustion residuals (CCR) samples to redistribute radionuclides using 228Ra/226Ra activity ratios in CCRs and compared to their values in the corresponding feed coal. NORM concentrations in CCRs were found to be 6–12 times higher than the original coal. The effective dose rates in the original coal were calculated and ranged from 14.9 ± 0.9 to 370.3 ± 22.2 μSv year−1, whereas in CCRs ranged from 257.5 ± 20.6 to 1797.5 ± 143.8 μSv year−1. The average concentration of 40K (120 Bq kg−1 per 1% K2O in CCRs) was calculated. The chemical composition indicates that the majority of CCR samples are Type C, which has a high calcium oxide ratio, high melting points and low deposition.
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References
Trevisi R, Risica S, D’Alessandro M, Paradiso D, Nuccetelli C (2012) Natural radioactivity in building materials in the European Union: a database and an estimate of radiological significance. J Environ Radioact 105:11–20
Tadmor J (1986) Radioactivity from coal-fired power plants: a review. J Environ Radioact 4(3):177–204
Eisenbud M, Petrow HG (1964) Radioactivity in the atmospheric effluents of power plants that use fossil fuels. Science 144(3616):288–289
Coles DG, Ragaini RC, Ondov JM (1978) Behavior of natural radionuclides in western coal-fired power plants. Environ Sci Technol 12(4):442–446
Völgyesi P, Kis Z, Zs Szabó, Cs Szabó (2014) Using the 186-keV peak for 226Ra activity concentration determination in Hungarian coal-slag samples by gamma-ray spectroscopy. J Radioanal Nucl Chem Lett 302:375–383
Beck HL, Gogolak C, Miller K, Lowder WM (1980) Perturbations on the natural radiation environment due to the utilization of coal as an energy source. U.S. Department of Energy, Washington
Zielinski RA, Budahn JR (1998) Radionuclides in fly ash and bottom ash: improved characterization based on radiography and low energy gamma-ray spectrometry. Fuel 77(4):259–267
Fardy J, McOrist G, Farrar Y (1989) Neutron activation analysis and radioactivity measurements of Australian coals and fly ashes. J Radioanal Nucl Chem Lett 133(2):217–226
Bem H, Wieczorkowski P, Budzanowski M (2002) Evaluation of technologically enhanced natural radiation near the coal-fired power plants in the lodz region of Poland. J Environ Radioact 61(2):191–201
Sanjuán MA, Argiz C (2012) The new European standard on common cements specifications EN 197-1:2011. Mater Constr 62:425–430
Argiz C, Menéndez E, Moragues A, Sanjuan MA (2015) Fly ash characteristics of Spanish coal-fired power plants. Afinidad 572:269–277
Council Directive 2013/59/Euratom of 5 Dec. (2013) Laying down basic safety standards for protection against the dangers arising from exposure to ionising radiation and repealing directives 89/618/Euratom. 90/641/Euratom. 96/29/Euratom. 97/43/Euratom and 2003/122/Euratom. L13, vol 57. ISSN: 1977-0677
Schroeyers W, Puertas F, Alonso M, Torres Carrasco M, Rivilla P, Gasco C, Trinidad JA, Suarez JA, Navarro N, Yague L, Mora JC, Orellana JG, Masque P, Hierro A, Bolıvar JP, Vazquez M, Quintana B (2015) In: Verdu´ G (ed) Introduction of the COST Action: COST TU1301 ‘‘NORM4-building’’. 48 Joint Congress 20 SEFM/15 SEPR (Spanish Society for Radiological Protection. Ed.) Valencia. Spain
Puertas F, García-Díaz I, Palacios M, Gazulla MF, Gómez MP, Orduña M (2010) Clinkers and cements obtained from raw mix containing ceramic waste as a prime material. Characterization, hydration and leaching studies. Cem Concr Compos 32:175–186
Sanjuan MA, Quintana B, Argiz C (2019) Coal bottom ash natural radioactivity in building materials. J Radioanal Nucl Chem Lett 319:91–99
García R, Pizarro C, Álvarez A, Lavín AG, Bueno JL (2015) Study of biomass combustion wastes. Fuel 148:152–159
Carlson CL, Adriano DC (1993) Environmental impacts of coal combustion residues. J Environ Qual 22:227–247
Ural S (2005) Comparison of fly ash properties from Afsin-Elbistan coal basin, Turkey. J Hazard Mater B119:85–92
Bundesanstalt für Geowissenschaften und Rohstoffe – Federal Institute for Geosciences and Natural Resources (BGR) (2009) Reserves, resources and availability of energy resources—annual report 2009, BGR, Hannover, Germany. www.bgr.bund.de
Puertas F, Alonso MM, Torres-Carrasco M, Rivilla P, Gasco C, Yagüe L, Suárez JA, Navarro N (2015) Radiological characterization of anhydrous/hydrated cements and geopolymers. Constr Build Mater 101:1105–1112
Lauer NC, Hower JC, Hsu-Kim H, Taggart RK, Vengosh A (2015) Naturally occurring radioactive materials in coals and coal combustion residuals in the United States. Environ Sci Technol 49(18):11227
Pandit GG, Sahu SK, Puranik VD (2011) Natural radionuclides from coal fired thermal power plants—estimation of atmospheric release and inhalation risk. Radioprotection 46(6):S173–S179
Swanson VE (1976) Collection, chemical analysis, and evaluation of coal samples in 1975. U.S. Department of the Interior, Geological Survey, Washington
Allam KhA, Ahmed Z, El-Sharkawy S, Salman A (2017) Analysis and statistical treatment of 238U series isotopic ratios using gamma-ray spectrometry in phosphate samples Radiat. Prot Environ 40(3&4):110
European Commission (1999) Radiation protection 122-radiological protection principles concerning the natural radioactivity of building materials. Directorate General Environment. Nuclear Safety and Civil Protection. https://ec.europa.eu/energy/sites/ener/files/documents/112.pdf. Accessed 27 Jul 2018
Markkanen M (1995) Radiation dose assessments for materials with elevated natural radioactivity. Report STUK-B-STO 32. Radiation and Nuclear Safety Authority-STUK. Helsinki. Iceland
Stojanovska Z, Nedelkovski D, Ristova M (2010) Natural radioactivity and human exposure by raw materials and end product from cement industry used as building materials. Radiat Meas 45:969–972
UNSCEAR (1998) Sources, effects and risk of ionizing radiation. United Nations, New York
UNSCEAR (1993) Exposure from natural sources of radiation. United Nations, New York
Yang Y (2005) Radioactivity concentrations in soils of the Xiazhuang granite area, China. Appl Radiat Isot 63:255–259
Mohanty AK, Sengupta D, Das SK, Saha SK (2004) Natural radioactivity and radiation exposure in the high background area at Chatrapur beach placer deposit of Orissa, India. J Environ Radioact 75:15–33
Xiao R, Chen X, Wang F, Yu G (2011) The physicochemical properties of different biomass ashes at different ashing temperature. Renew Energy 36:244–249
Bridgeman TG, Darvell LI, Jones JM, Williams PT, Fahmi R, Bridgewater AV et al (2007) Influence of particle size on the analytical and chemical properties of two energy crops. Fuel 86:60–72
Fryda L, Sobrino C, Glazer M, Bertrand C, Cieplik M (2012) Study of ash deposition during coal combustion under oxyfuel conditions. Fuel 92:308
Vamvuka D, Pitharoulis M, Alevizos G, Repouskou E, Pentari D (2009) Effects during combustion of lignite/biomass blends in fluidized bed. Renew Energy 34:2662
Acknowledgements
This research was funded by Deanship of Scientific Research, Princess Nourah bent Adulrahman University through the Fast-track Research Funding Program. The authors would also like to thank editor-in-chief of Journal of Radioanalytical and Nuclear Chemistry and referees for their valuable comments and cooperation.
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Aloraini, D.A., El-Azony, K.M. Measurement of natural radioactivity concentrations and chemical composition of coal and its post-combustion residues in KSA. J Radioanal Nucl Chem 323, 885–895 (2020). https://doi.org/10.1007/s10967-019-07001-x
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DOI: https://doi.org/10.1007/s10967-019-07001-x