Isolation of Au and Pt radionuclides from deuteron-irradiated platinum using TBP resin

Abstract

A separation procedure was developed and implemented for the isolation of gold (Au) and platinum (Pt) radionuclides from deuteron irradiated Pt using tri-butyl phosphate (TBP) resin. Computational modeling and experimental results of the Au and Pt radionuclide production were reported and compared to literature values. Results of the separation procedure demonstrated a Pt recovery of 98 ± 2% and a Au recovery of 92 ± 7%, in their respective fractions (n = 4 ± 1σ) The decontamination factors were 2900 ± 500 for Au removal from the Pt fraction and 830 ± 30 for Pt removal from the Au fraction (n = 4 ± 1σ).

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References

  1. 1.

    Haney MM, Seiner BN, Finn EC, Friese JI (2016) Rapid quantitation of uranium from mixed fission product samples. J Radioanal Nucl Chem 307(3):1737–1742

    Article  CAS  Google Scholar 

  2. 2.

    Morrison SS, Clark SB, Eggemeyer TA, Finn EC, Hines CC, King MD, Metz LA, Morley SM, Snow MS, Wall DE (2017) Activation product analysis in a mixed sample containing both fission and neutron activation products. J Radioanal Nucl Chem 314(3):2501–2506

    Article  CAS  Google Scholar 

  3. 3.

    Fan J, Lu J, Zhang L, Yu G, Huang P, Shi Q, Liu Z, Li X, Bai T (2016) Automated separation of short-lived 72Ga from fresh fission products based on tandem column chromatography. J Radioanal Nucl Chem 309(2):467–476

    CAS  Google Scholar 

  4. 4.

    Kumar S, Verma R, Gangadharan S (1993) Application of poly (aniline) as an ion exchanger for the separation of palladium, iridium, platinum and gold prior to their determination by neutron activation analysis. Analyst 118(8):1085–1087

    Article  CAS  Google Scholar 

  5. 5.

    Morrison SS, Seiner BN, Eggemeyer TA, Haney MM, Hines CC, King MD, Metz LA, Morley SM, Uhnak NE, Wall DE (2016) A chemical separation procedure using ionic liquid extraction for 59 Fe and 55 Fe quantification. J Radioanal Nucl Chem 307(3):2479–2485

    Article  CAS  Google Scholar 

  6. 6.

    Morrison SS, Beck CL, Bowen JM, Eggemeyer TA, Hines CC, Leizers M, Metz LA, Morley SM, Restis KR, Snow MS (2017) Determination of tungsten in geochemical reference material basalt Columbia River 2 by radiochemical neutron activation analysis and inductively coupled plasma mass spectrometry. J Radioanal Nucl Chem 311(1):749–754

    Article  CAS  Google Scholar 

  7. 7.

    Pierson BD, Finn EC, Friese JI, Greenwood LR, Kephart JD, Kephart RF, Metz LA (2013) Identifying and quantifying short-lived fission products from thermal fission of HEU using portable HPGe detectors. J Radioanal Nucl Chem 295(3):1881–1885

    Article  CAS  Google Scholar 

  8. 8.

    Xiong Y, Adhikari CR, Kawakita H, Ohto K, Inoue K, Harada H (2009) Selective recovery of precious metals by persimmon waste chemically modified with dimethylamine. Biores Technol 100(18):4083–4089

    Article  CAS  Google Scholar 

  9. 9.

    Wei W, Cho C-W, Kim S, Song M-H, Bediako JK, Yun Y-S (2016) Selective recovery of Au (III), Pt (IV), and Pd (II) from aqueous solutions by liquid–liquid extraction using ionic liquid Aliquat-336. J Mol Liq 216:18–24

    Article  CAS  Google Scholar 

  10. 10.

    Fontàs C, Anticó E, Vocanson F, Lamartine R, Seta P (2007) Efficient thiacalix [4] arenes for the extraction and separation of Au (III), Pd (II) and Pt (IV) metal ions from acidic media incorporated in membranes and solid phases. Sep Purif Technol 54(3):322–328

    Article  CAS  Google Scholar 

  11. 11.

    Hasegawa H, Barua S, Wakabayashi T, Mashio A, Maki T, Furusho Y, Rahman IM (2018) Selective recovery of gold, palladium, or platinum from acidic waste solution. Microchem J 139:174–180

    Article  CAS  Google Scholar 

  12. 12.

    Jha MK, Gupta D, Lee J-C, Kumar V, Jeong J (2014) Solvent extraction of platinum using amine based extractants in different solutions: a review. Hydrometallurgy 142:60–69

    Article  CAS  Google Scholar 

  13. 13.

    Cieszynska A, Wieczorek D (2018) Extraction and separation of palladium (II), platinum (IV), gold (III) and rhodium (III) using piperidine-based extractants. Hydrometallurgy 175:359–366

    Article  CAS  Google Scholar 

  14. 14.

    Ishimori T, Watanabe K (1960) Inorganic extraction studies on the system of tri-n-butyl phosphate—nitric acid. Bull Chem Soc Jpn 33(10):1443–1448

    Article  CAS  Google Scholar 

  15. 15.

    Ishimori T, Watanabe K, Nakamura E (1960) Inorganic extraction studies on the system between tri-n-butyl phosphate and hydrochloric acid. Bull Chem Soc Jpn 33(5):636–644

    Article  CAS  Google Scholar 

  16. 16.

    Dirks C, Vajda N, Kovács-Széles E, Bombard A, Happel S (2014) In characterization of a TBP resin and development of methods for the separation of actinides and the purification of Sn. Poster presented at the 17th radiochemistry conference, Marianske Lazne (Tcheque Republic), pp 11–16.

  17. 17.

    Andris B, Beňa J (2016) The development of 126 Sn separation procedure by means of TBP resin. J Radioanal Nucl Chem 308(3):781–788

    Article  CAS  Google Scholar 

  18. 18.

    Baum EM, Knox HD, Miller TR (2002) Nuclides and isotopes: chart of the nuclides. KAPL, Schenectady, NY

    Google Scholar 

  19. 19.

    Vanin V, Maidana N, Castro R, Achterberg E, Capurro O, Marti G (2007) Nuclear data sheets for A = 191. Nucl Data Sheets 108(11):2393–2588

    Article  CAS  Google Scholar 

  20. 20.

    Achterberg E, Capurro O, Marti G, Vanin V, Castro R (2006) Nuclear data sheets for A = 193. Nucl Data Sheets 107(1):1–224

    Article  CAS  Google Scholar 

  21. 21.

    Singh B (2006) Nuclear data sheets for A = 194. Nucl Data Sheets 107(6):1531–1746

    Article  CAS  Google Scholar 

  22. 22.

    Chunmei Z (1999) Nuclear data sheets for A = 195. Nucl Data Sheets 86(3):645–784

    Article  CAS  Google Scholar 

  23. 23.

    Xiaolong H (2007) Nuclear data sheets for A = 196. Nucl Data Sheets 108(6):1093–1286

    Article  CAS  Google Scholar 

  24. 24.

    Huang X, Zhou C (2005) Nuclear data sheets for A = 197. Nucl Data Sheets 104(2):283–426

    Article  CAS  Google Scholar 

  25. 25.

    Xiaolong H (2009) Nuclear data sheets for A = 198. Nucl Data Sheets 110(10):2533–2688

    Article  CAS  Google Scholar 

  26. 26.

    Singh B (2007) Nuclear data sheets for A = 199. Nucl Data Sheets 1(108):79–196

    Article  CAS  Google Scholar 

  27. 27.

    Small H (1989) The chromatographic process. In: Ion chromatography. Springer, Boston, MA, pp 11–39. https://doi.org/10.1007/978-1-4899-2542-8_2

  28. 28.

    Tárkányi F, Takács S, Ditrói F, Hermanne A, Shubin YN, Dityuk A (2004) Activation cross-sections of deuteron induced reactions on platinum. Nucl Instrum Methods Phys Res Sect B 226(4):490–498

    Article  CAS  Google Scholar 

  29. 29.

    Ditrói F, Tárkányi F, Csikai J, Uddin M, Hagiwara M, Baba M, Shubin YN, Kovalev S (2006) Excitation functions of long lived products in deuteron induced nuclear reactions on platinum up to 40 MeV. Nucl Instrum Methods Phys Res Sect B 243(1):20–27

    Article  CAS  Google Scholar 

  30. 30.

    Khandaker MU, Haba H, Murakami M, Otuka N, Kassim HA (2015) Excitation functions of deuteron-induced nuclear reactions on natural platinum up to 24 MeV. Nucl Instrum Methods Phys Res Sect B 362:151–162

    Article  CAS  Google Scholar 

  31. 31.

    Ditrói F, Tárkányi F, Takács S, Hermanne A (2017) Extension of activation cross section data of long lived products in deuteron induced nuclear reactions on platinum up to 50 MeV. Nucl Instrum Methods Phys Res Sect B 401:56–70

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The work was supported by the Office of Defense Nuclear Nonproliferation (DNN), U.S. Department of Energy, and Pacific Northwest National Laboratory, which is operated by Battelle Memorial Institute for the U.S. Department of Energy under Contract DE-AC05–76RLO1830. We would like to acknowledge the support of Eric Smith and Joben Pedersen at CENPA for experimental coordination of the deuteron irradiation.

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The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

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Correspondence to Samuel S. Morrison.

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Morrison, S.S., Morrison, E.C., Uhnak, N.E. et al. Isolation of Au and Pt radionuclides from deuteron-irradiated platinum using TBP resin. J Radioanal Nucl Chem 319, 679–686 (2019). https://doi.org/10.1007/s10967-018-6382-3

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Keywords

  • Activation products
  • Extraction chromatography
  • Deuteron irradiation
  • Platinum-191
  • TBP
  • Separation science