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Development of an analytical strategy for the determination of 228Th and 232Th in ivory based on the combined use of ICP-MS and α-spectrometry

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Abstract

Elephants are endangered due to the value of their ivory tusks. Therefore, a reliable method for age determination of ivory is of interest for the law enforcement against elephant poachers. The ratio of the specific activities 228Th/232Th can be used for the age assessment of ivory. In this report, the combination of two complementary detection techniques, namely inductively coupled plasma-mass spectrometry (ICP-MS) and α-spectrometry, for the determination of 228Th and 232Th in ivory is presented. Using ICP-MS in addition to α-spectrometry, the uncertainty of the 232Th determination could be reduced significantly which enabled a more accurate and effective ivory dating.

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References

  1. Chase MJ et al (2016) Continent-wide survey reveals massive decline in African savannah elephants. PeerJ 4:e2354

    Article  Google Scholar 

  2. Convention on International Trade in Endangered Species of Wild Fauna and Flora. https://www.cites.org/sites/default/files/eng/disc/CITES-Convention-EN.pdf. Accessed 03 July 2018

  3. Schmidberger A, Durner B, Gehrmeyer D, Schupfner R (2018) Development and application of a method for ivory dating by analyzing radioisotopes to distinguish legal from illegal ivory. For Sci Int 289:363–367

    CAS  Google Scholar 

  4. Brunnermeier MJ, Schmied SAK, Müller-Boge M, Schupfner R (2012) Dating of ivory from 20th century by determination of 14C by the direct absorption method. Appl Radiat Isotopes 70:1595–1602

    Article  CAS  Google Scholar 

  5. Brunnermeier MJ, Schmied SAK, Schupfner R (2012) Distribution of 14C, 90Sr and 228Th in an elephant tusk. J Radioanal Nucl Chem 292:1285–1290

    Article  CAS  Google Scholar 

  6. Ramanujam A et al (1997) Determination of trace impurities in uranium, thorium and plutonium by solvent extraction and inductively coupled plasma atomic emission sprectrometry. Talanta 44:169–176

    Article  Google Scholar 

  7. Becker J, Dietze HJ (1999) Precise isotope ratio measurements for uranium, thorium and plutonium by quadrupole-based inductively coupled plasma mass spectrometry. Fresenius J Anal Chem 364:482–488

    Article  CAS  Google Scholar 

  8. Garbe-Schönberg C-D (1993) Simultaneous determination of thirty-seven trace elements in twenty-eight international rock standards by ICP-MS. Geostand Newslett 17:81–97

    Article  Google Scholar 

  9. Jones DR et al (2017) Analysis of whole human blood for Pd, Cd, Hg, Se, and Mn by ICP-DRC-MS for biomonitoring and acute exposures. Talanta 162:114–122

    Article  CAS  Google Scholar 

  10. Cruz SM, Schmidt L, Dalla Nora FM, Pedrotti MF, Bizzi CA, Brian JS, Flores EMM (2015) Microwave-induced combustion method for the determination of trace and ultratrace element impurities in graphite samples by ICP-OES and ICP-MS. Microchem J 123:28–32

    Article  CAS  Google Scholar 

  11. Goullé J-P, Mahieu L, Castermant J, Neveu N, Bonneau L, Lainé G, Bouige D, Lacroix C (2005) Metal and metalloid multi-elementary ICP-MS validation in whole blood, plasma, urine and hair: reference values. For Sci Int 153:39–44

    Google Scholar 

  12. Bazzano A, Grotti M (2014) Determination of lead isotope ratios in environmental matrices by quadrupole ICP-MS working at low sample consumption rates. J Anal At Spectrom 29:926–933

    Article  CAS  Google Scholar 

  13. Gajek R, Barley F, She J (2013) Determination of essential and toxic metals in blood by ICP-MS with calibration in synthetic matrix. Anal Methods 5:2193–2202

    Article  CAS  Google Scholar 

  14. Frei D, Gerdes A (2009) Precise and accurate in situ U-Pb dating of zircon with high sample throughput by automated LA-SF-ICP-MS. Chem Geol 261:261–270

    Article  CAS  Google Scholar 

  15. Pilviö R, Bickel M (2000) Actinoid separations by extraction chromatography. Appl Radiat Isotopes 53:273–277

    Article  Google Scholar 

  16. Lemoine L, Thijssen E, Noben J-P, Adriaensens P, Carleer R, Van der Speeten K (2018) A validated inductively coupled plasma mass spectrometry (ICP-MS) method for the quantification of total platinum content in plasma, plasma ultrafiltrate, urine and peritoneal fluid. J Pharm Biomed Anal 152:39–46

    Article  CAS  Google Scholar 

  17. Tomé FV, Blanco Rodríguez MP, Lozano JC (2002) Study of the representativiy of uranium and thorium assays in soil and sediment samples by alpha spectrometry. Appl Radiat Isotopes 56:393–398

    Article  Google Scholar 

  18. Bergamini G, Taddei MHT, Rosa MML, Ferreira MT (2016) Determination of 226Ra in drinking water samples by alpha spectrometry. Radioanal Nucl Chem 307:829–834

    Article  CAS  Google Scholar 

  19. Boulyga SF, Testa C, Desideri D, Becker JS (2001) Optimisation and application pf ICP-MS and alpha-spectrometry for determination of isotopic ratios of depleted uranium and plutonium samples collected in Kosovo. J Anal At Spectrom 16:1283–1289

    Article  CAS  Google Scholar 

  20. Kandelbinder R, Geissler V, Schupfner R, Wolfbeis O, Zinka B (2009) Analysing of 228Th, 232Th, 228Ra in human bone tissues for the purpose of determining the post mortal interval. J Radiat Nucl Chem 208:113–119

    Article  Google Scholar 

  21. Brunnermeier M (2012) Entwicklung und Validierung einer Methode zur Bestimmung des Todeszeitpunkts von Elefanten durch Bestimmung von 14C und 228Th/232Th in Elfenbein. Dissertation. University of Regensburg

  22. DIN 1319-3 (1996) Fundamentals of metrology—Part 3: evaluation of measurements of a single measurand, measurement uncertainty

  23. Rytz A (1991) Recommended energy and intensity values of alpha particles from radioactive decay. At Data Nucl Data Tables 47:205–239

    Article  CAS  Google Scholar 

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Acknowledgements

The authors thank the zoological garden of Wuppertal and the German Federal Agency for Nature Conversation, which supported this work with ivory samples.

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Correspondence to Robert Schupfner.

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Schmidberger, A., Schupfner, R. & Matysik, FM. Development of an analytical strategy for the determination of 228Th and 232Th in ivory based on the combined use of ICP-MS and α-spectrometry. J Radioanal Nucl Chem 318, 2007–2011 (2018). https://doi.org/10.1007/s10967-018-6191-8

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  • DOI: https://doi.org/10.1007/s10967-018-6191-8

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