Advertisement

Journal of Radioanalytical and Nuclear Chemistry

, Volume 318, Issue 1, pp 407–413 | Cite as

Integration of a hyphenated HPIC-ICPMS protocol for the measurement of transplutonium isotopic mass distributions for 252Cf campaigns at Oak Ridge National Laboratory

  • Benjamin D. Roach
  • Joseph M. Giaquinto
  • Tamara J. Keever
Article
  • 40 Downloads

Abstract

Rapid measurement of transplutonium isotopic mass distributions during 252Cf production campaigns at Oak Ridge National Laboratory is a critical need. Mass measurements for the isotopes of plutonium, americium, curium, and californium are routinely requested to support the α-hydroxy-isobutyrate runs for the purification and recovery of the heavy curium target material and final 249Bk, 252Cf, and 254Es enriched isotope products. This paper presents the integration of an online high-pressure ion chromatography inductively coupled plasma mass spectrometry technique together with the protocol and chemistry that allows for rapid baseline separation and direct quantification of the transplutonium elemental concentrations and isotopic compositions.

Keywords

Inductively coupled plasma mass spectrometry High pressure ion chromatography Transplutonium Isotopic analysis Californium Berkelium Einsteinium 

Notes

Acknowledgements

The authors would like to acknowledge the ORNL Isotope program, in particular the californium-252 program manager Julie Ezold, for supporting the method development and presentation of this work. The authors would also like to thank Jeff Delashmitt and Doug Canaan from the Transuranium Analytical Laboratory for useful discussions and providing the radiochemical data for comparison purposes.

Funding

Funding was provided by The ORNL Isotope Production Program part of the Department of Energy Isotope Development and Production for Research and Applications Program.

Supplementary material

10967_2018_6072_MOESM1_ESM.docx (74 kb)
Supplementary material 1 (DOCX 73 kb)

References

  1. 1.
    Roberto J, Alexander C, Boll R, Burns J, Ezold J, Felker L, Hogle S, Rykaczewski K (2015) Nucl Phys A 944:99–116CrossRefGoogle Scholar
  2. 2.
    Bigelow J, Collins E, King L (1980) Actinide separations. In: ACS symposium series, vol 117, pp 147–155Google Scholar
  3. 3.
    Collins E, Benker D, Chattin F, Orr P, Ross R (1981) Transplutonium elements—production and recovery. In: ACS symposium series, vol 161, pp 147–160Google Scholar
  4. 4.
    Hulet E, Gutmacher R, Coops M (1961) J Inorg Nucl Chem 17:350–360CrossRefGoogle Scholar
  5. 5.
    Benker D, Chattin F, Collins E, Knauer J, Orr P, Ross R, Wiggins J (1981) Transplutonium elements—production and recovery. In: ACS symposium series, vol 161, pp 161–172Google Scholar
  6. 6.
    Choppin G, Harvey B, Thompson S (1956) J Inorg Nucl Chem 2:66–68CrossRefGoogle Scholar
  7. 7.
    Delashmitt J, Canaan R, Denton D, Giaquinto J, Smith R, Sutherland J, Woody B (2010) Sep Sci Technol 45:1776–1781CrossRefGoogle Scholar
  8. 8.
    Collins E, DelCul G, Moyer B (2011) Advanced reprocessing for fission product separation and extraction. In: Nash KL, Lumetta GJ (eds) Woodhead publishing series in energy, vol 2. Woodhead Publishing Ltd., Woodland, pp 201–228CrossRefGoogle Scholar
  9. 9.
    Modolo G, Kluxen P, Geist A (2010) Radiochim Acta 98(4):193–201CrossRefGoogle Scholar
  10. 10.
    Kimura T, Akatsu J (1991) J Radioanal Nucl Chem 149:13–23CrossRefGoogle Scholar
  11. 11.
    Kimura T, Akatsu J (1991) J Radioanal Nucl Chem 149:25–34CrossRefGoogle Scholar
  12. 12.
    Gourgiotis A, Isnard H, Nonell A, Aubert M, Stadelmann G, Dupont E, AlMahamid I, Tiang G, Rao L, Lukens W, Cassette P, Panebianco S, Letourneau A, Chartier F (2013) Talanta 106:39–44CrossRefPubMedGoogle Scholar
  13. 13.
    Skerencak-Frech A, Maiwald M, Trumm M, Froehlich D, Panak P (2015) Inorg Chem 54:1860–1868CrossRefPubMedGoogle Scholar
  14. 14.
    Hummel W, Anderegg G, Puigdomenech I, Rao L, Tochiyama O (2005) OECD, NEA-TDB, 9. https://www.oecd-nea.org/dbtdb/pubs/vol9-organic-ligands.pdf. Accessed Mar 2018

Copyright information

© This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply 2018

Authors and Affiliations

  • Benjamin D. Roach
    • 1
  • Joseph M. Giaquinto
    • 1
  • Tamara J. Keever
    • 1
  1. 1.Nuclear Analytical Chemistry and Isotopics Laboratories (NACIL), Chemical Sciences DivisionOak Ridge National LaboratoryOak RidgeUSA

Personalised recommendations