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Journal of Radioanalytical and Nuclear Chemistry

, Volume 314, Issue 1, pp 119–125 | Cite as

Separation of cobalt from thiocyanate solutions by crown ether-based impregnated sorbents

  • V. S. Yankovskaya
  • I. I. Dovhyi
  • V. V. Milyutin
  • N. A. Nekrasova
  • N. A. Bezhin
  • A. Yu. Lyapunov
Article

Abstract

A number of impregnated sorbents based on di-(tert-butyldibenzo)-18-crown-6 (DTBDB18C6) and di-(tert-butylcyclohexano)-18-crown-6 (DTBDCH18C6) was obtained using different diluents for the crown ether and the styrene–divinylbenzene support. Sorption characteristics of the sorbents in relation to cobalt ions and 60Co radionuclide in thiocyanate solutions were determined within the range of pH of 1–7. It was found the DTBDB18C6-based sorbents were the most efficient for the sorption of cobalt macro quantities whereas the DTBDCH18C6-based ones for the sorption of 60Co radionuclide, using nitrobenzene as a diluent. A possibility was shown of the complete cobalt desorption by hydrochloric and nitric acid solutions with the concentration of 0.1–1.0 mol L–1.

Keywords

Cobalt 60Co Sorption di-(tert-Butyldibenzo)-18-crown-6 (DTBDB18C6) di-(tert-Butylcyclohexano)-18-crown-6 (DTBDCH18C6) Diluents 

Notes

Acknowledgements

The research was carried out within the state assignment of FASO of Russian Federation (theme “Fundamental oceanography” No. 0827-2014-0010), and Foundation for Assistance to Small Innovative Enterprises in Science and Technology (program Start-1).

References

  1. 1.
    Bezhin NA, Dovhyi II (2015) Sorbents based on crown ethers: preparation and application for the sorption of strontium. Russ Chem Rev 84:1279–1293. doi: 10.1070/RCR4505 CrossRefGoogle Scholar
  2. 2.
    Baulin VE, Kovalenko OV, Turanov AN, Karandashev VK, Usolkin AN, Yakovlev NG, Voroshilov YuA, Tsivadze AYu (2015) Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions. Radio Chem. 57(1):61–68. doi: 10.1134/S1066362215010099 Google Scholar
  3. 3.
    Maxwell SL, Culligan BK (2006) Rapid column extraction method for actinides in soil. J Radioanal Nucl Chem 270(3):699–704. doi: 10.1007/s10967-006-0449-2 CrossRefGoogle Scholar
  4. 4.
    Brochure TrisKem International EN. http://www.triskem-international.com/iso_album/technical_doc_general_v6_en_ht_web.pdf. Accessed 21 July 2017
  5. 5.
    Çakır Ümit, Çiçek Baki (2004) Extraction-ability and -selectivity of tetra-aza-crown ethers for transition metal cations. Transit Metal Chem 29:263–268CrossRefGoogle Scholar
  6. 6.
    Khalifa SM, Aly HF (1989) Ion-pair extraction of Co(II) by crown ethers from perchlorate medium. Talanta 36:406–408. doi: 10.1016/0039-9140(89)80210-3 CrossRefGoogle Scholar
  7. 7.
    Aly HF, El-Dessouky MM, Khalifa SM, Navratil JD, Shehata FA (1985) Synergic extraction of cobalt(II) by structurally related crown ethers and thenoyltrifluoroacetone. Solvent Extr Ion Exch 3:867–879. doi: 10.1080/07366298508918545 CrossRefGoogle Scholar
  8. 8.
    Shehata FA, EI-Dessouky SI, Aly HF (1999) Effect of temperature on the extraction of octahedral and tetrahedral cobalt(II) by 8-hydroxyquinoline and/or dibenzo-18-crown-6 or dibenzylamine. J Radioanal Nucl Chem 240:209–214. doi: 10.1007/BF02349155 CrossRefGoogle Scholar
  9. 9.
    Khalifa SM, Aly HF, Navratil JD, Shehata FA (1987) Thermodynamics of cobalt(II) extraction by thenoyltrifluoroacetone and dibenzo-18-crown-6 in nitrobenzene-toluene mixtures. Solvent Extr Ion Exch 5:1057–1073. doi: 10.1080/07366298708918610 CrossRefGoogle Scholar
  10. 10.
    Young RS, Hall AJ (1946) Colorimetric determination of cobalt with ammonium thiocyanate. Ind Eng Chem Anal Ed 18(4):264–266. doi: 10.1021/i560152a014 CrossRefGoogle Scholar
  11. 11.
    Yoshio M, Ugamura M, Noguchi H, Nagamatsu M (1978) Analytical applications of crown ether extraction of cobalt thiocyanate complex with ammonium-crown ether complex. Anal Lett 11:281–286. doi: 10.1080/00032717808067869 CrossRefGoogle Scholar
  12. 12.
    Yakshin VV, Vilkova OM, Tsarenko NA, Tsivadze AYu (2010) Reactivity of cis and trans isomers of dinitro- and diamino-substituted dibenzo-18-crown-6 in metal salt sorption processes. Doklady Chem 430:32–34. doi: 10.1134/S0012500810010088 CrossRefGoogle Scholar
  13. 13.
    Bezhin NA, Dovhyi II, Lyapunov AYu (2015) Sorption of strontium by the endoreceptor dibenzo-18-crown-6 immobilized in a polymer matrix. J Radioanal Nucl Chem 303:1927–1931. doi: 10.1007/s10967-014-3770-1 Google Scholar
  14. 14.
    Yakshin VV, Vilkova OM, Tsarenko NA, Tsivadze AYu (2010) Metal extraction from nitric acid solutions by the macrocyclic endoreceptor dicyclohexyl-18-crown-6 immobilized in a polymer matrix. Doklady Chem. 430:54–57. doi: 10.1134/S0012500810020060 CrossRefGoogle Scholar
  15. 15.
    Popova NN, Zhilov VI, Demin SV, Tsivadze AYu, Yakshin VV, Vilkova OM (2011) Americium (III) sorption from multicomponent solutions by macrocyclic polyester based sorbents. Russ J Inorg Chem 56:1128–1132. doi: 10.1134/S0036023611070217 CrossRefGoogle Scholar
  16. 16.
    Surman JJ, Pates JM, Zhang H, Happel S (2014) Development and characterization of a new Sr selective resin for the rapid determination of 90Sr in environmental water samples. Talanta 129:623–628. doi: 10.1016/j.Talanta.2014.06.041 CrossRefGoogle Scholar
  17. 17.
    Bezhin NA, Dovhyi II, Baulin VE (2016) Selectivity of strontium recovery by a sorbent based on di-tert-butyldicyclohexano-18-crown-6 and 1,1,7-trihydrododecafluoroheptanol. In: Proceedings of III international scientific conference of young scientists, postgraduates, and students isotopes: technologies, materials, and applications, pp 59–60Google Scholar
  18. 18.
    Yakshin VV, Vilkova OM, Tsarenko NA, Tsivadze AYu (2012) Sorption of elements from mineral acid solutions by alkylated dibenzocrown ethers. Russ Chem Bull 61:656–658. doi: 10.1007/s11172-012-0095-5 CrossRefGoogle Scholar
  19. 19.
    Guba LB, Dovhyi II, Lyapunov AYu, Grishkovets VI (2015) Physicochemical characteristics of cesium recovery with a sorbent based on dibenzo-24-crown-8. Radiochemistry 57:518–521. doi: 10.1134/S1066362215050112 CrossRefGoogle Scholar
  20. 20.
    Hanzel R, Rajec P (2000) Sorption of cobalt on modified silica gel materials. J Radioanal Nucl Chem 246:607–615. doi: 10.1023/A:1006750620617 CrossRefGoogle Scholar
  21. 21.
    Yakshin VV, Vilkova OM, Plyzhnik-Gladyr SM, Kotlyar SA (2010) Crown ethers in the extraction and sorption. I. Bromo-derivatives of benzo- and dibenzo- crown ethers in sorption processes of elements from aqueous acidic solutions. Macroheterocycles 3:114–120CrossRefGoogle Scholar
  22. 22.
    Yakshin VV, Vilkova OM, Kotlyar SA, Tsivadze AYu (2012) dibromo and diiodo derivatives of [4.4]dibenzo-24-crown-8 as novel efficient sorbents of elements from mineral acid solutions. Russ J Coord Chem 38:295–299. doi: 10.1134/S1070328412040112 CrossRefGoogle Scholar
  23. 23.
    Zhang A, Xiao Ch, Liu Y, Hu Q, Chen Ch, Kuraoka E (2010) Preparation of macroporous silica-based crown ether materials for strontium separation. J Porous Mater 17:153–161. doi: 10.1007/s10934-009-9287-2 CrossRefGoogle Scholar
  24. 24.
    Milyutin VV, Nekrasova NA, Dovhyi II, Bezhin NA, Baulin VE, Tsivadze AYu (2017) Removal of 90Sr from nitric acid solutions with sorbents based on di-tert-butyldicyclohexyl-18-crown-6. Radiochemistry 59:166–169. doi: 10.1134/S1066362217020096 CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2017

Authors and Affiliations

  • V. S. Yankovskaya
    • 1
  • I. I. Dovhyi
    • 1
    • 2
  • V. V. Milyutin
    • 3
  • N. A. Nekrasova
    • 3
  • N. A. Bezhin
    • 1
  • A. Yu. Lyapunov
    • 4
  1. 1.LLP « SIC « Sorbentex»SevastopolRussia
  2. 2.Marine Hydrophysical InstituteRussian Academy of SciencesSevastopolRussia
  3. 3.A.N. Frumkin Institute of Physical Chemistry and Electrochemistry RASRussian Academy of SciencesMoscowRussian Federation
  4. 4.A.V. Bogatsky Physico-Chemical InstituteNational Academy of Sciences of UkraineOdessaUkraine

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