Abstract
This study investigated an analytical method for detecting 90Sr in soil samples for the routine monitoring of environmental radioactivity. Mineral acid leaching and fusion methods were first used to digest the soil sample, and the analytical results were compared. DGA resin was employed to separate 90Y, being a daughter of 90Sr. Then, 90Y was analyzed by liquid scintillation counter (LSC). These analytical results were compared with those obtained using Sr resin, which is a well-known, simple and reliable separation method. With the DGA resin approach a minimum detectable activity of ~0.28 Bq kg−1 was detected in a 50 g sample, with 180 min of counting time, 70% recovery and ~97% counting efficiency using a LSC.
Similar content being viewed by others
References
Vajda N, Kim CK (2010) Determination of radiostrontium isotopes: a review of analytical methodology. Appl Radiat Isotopes. 68(12):2306–2326
Bojanowski R, Knapinska-Skiba D (1990) Determination of low-level90Sr in environmental materials: a novel approach to the classical method. J Radional Nucl Chem 138(2):207–218
Wilken RD, Diehl R (1987) Strontium-90 in environmental samples from northern germany before and after the chernobyl accident. Radiochim Acta 41(4):157–162
Vaney B, Friedli C, Geering JJ, Lerch P (1989) Rapid trace determination of radiostrontium in milk and drinking water. J Radioanal Nucl Chem 134(1):87–95
Dietz ML, Yaeger J, Sajdak LR Jr, Jensen MP (2005) Characterization of an improved extraction chromatographic material for the separation and preconcentration of strontium from acidic media. Sep Sci Technol 40(1–3):349–366
Maxwell SL, Culligan BK, Shaw PJ (2013) Rapid determination of radiostrontium in large soil samples. J Radioanal Nucl Chem 295(2):965–971
Hawkins CA, Shkrob IA, Mertz CJ, Dietz ML, Kaminski MD (2012) Novel tandem column method for the rapid isolation of radiostrontium from human urine. Anal Chim Acta 746:114–122
Grahek Ž, Rožmarić Mačefat M (2005) Determination of radioactive strontium in seawater. Anal Chim Acta 534(2):271–279
Maxwell SL, Culligan BK, Utsey RC (2013) Rapid determination of radiostrontium in seawater samples. J Radioanal Nucl Chem 298(2):867–875
Tazoe H, Obata H, Yamagata T, Karube Z, Nagai H, Yamada M (2016) Determination of strontium-90 from direct separation of yttrium-90 by solid phase extraction using DGA Resin for seawater monitoring. Talanta 152:219–227
Kim H, Chung KH, Jung Y, Jang M, Kang M, Choi GS (2015) A rapid and efficient automated method for the sequential separation of plutonium and radiostrontium in seawater. J Radioanal Nucl Chem 304(1):321–327
Chung KH, Kim H, Lim JM, Ji YY, Choi GS, Kang MJ (2015) Rapid determination of radiostrontium in milk using automated radionuclides separator and liquid scintillation counter. J Radioanal Nucl Chem 304(1):293–300
Kim H, Jung Y, Ji YY, Lim JM, Chung KH, Kang MJ (2017) Validation of a procedure for the analysis of 226Ra in naturally occurring radioactive materials using a liquid scintillation counter. J Environ Radioactiv. 166:188–194
Horwitz EP (1998) Extraction chromatography of actinides and selected fission products: principles and achivement of selectivity
Currie LA (1968) Limits for qualitative detection and quantitative determination: application to radiochemistry. Anal Chem 40(3):586–593
Jung Y, Kim H, Suh KS, Kang MJ, Chung KH (2015) Optimization of radiostrontium separation process using sr resin. J Nucl Fuel Cycle Waste Technol 13(2):123–130
Acknowledgements
This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Korea Government (MSIP) (No. 2017M2A8A5015143).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jung, Y., Kim, H., Lim, JM. et al. Feasibility study of an analytical method for detecting 90Sr in soil using DGA resin and Sr resin. J Radioanal Nucl Chem 313, 401–408 (2017). https://doi.org/10.1007/s10967-017-5328-5
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-017-5328-5