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Applicability of polyvinylpolypyrrolidone adsorbent to treatment process of wastes containing uranium

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Abstract

In order to assess the feasibility of method for recovering U from wastes containing uranium (scrap uranium) using polyvinylpolypyrrolidone (PVPP) adsorbent, we have examined the adsorption and desorption behavior of metal species in HCl aqueous solutions dissolving scrap uranium. It was found that the U(VI) species are selectively adsorbed onto PVPP regardless of the presence of a large amount of Na(I) and Al(III), that the adsorbed U(VI) species are desorbed from PVPP column selectively by water. From these results, the PVPP resin is expected to be used as the adsorbent in the treatment process of scrap uranium.

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References

  1. Amamoto I, Wakabayashi S (2005) Uranium refining and conversion at Ningyo Toge works. Shigen-to-Sozai 109:1170–1174

    Article  Google Scholar 

  2. Amamoto I (2000) Development of uranium conversion technology. Saikuru-Kiko-Giho 9:65–74

    Google Scholar 

  3. Japan Atomic Energy Commission (2010) Basic concept for treatment and disposal of uranium waste. Japan. Atomic Energy Commission Report, Japan

  4. Ikeda A, Aida M, Fujii Y, Kataoka S, Annnen S, Sato J (2002) Ion exchange separation for decontamination of centrifuge enrichment plant. J Nucl Sci Technol 39:1099–1105

    Article  CAS  Google Scholar 

  5. Enda M, Sato T, Sakai H, Natsui K, Ishikura T (2006) Development of chemical decontamination technique using formic acid. Trans At Energy Soc Jpn l5:364–373

    Article  Google Scholar 

  6. Seung-Soo K, Wan-Suk K, Gye-Nam K, Hye-Min P, Uk-Ryang P, Jei-Kwon M (2013) Decontamination of uranium-contaminated concrete. J Radioanal Nucl Chem 298:973–980

    Article  Google Scholar 

  7. Hopkins JS, Golding JA (1987) The critical factors influencing uranium precipitation by hydrogen peroxide. The use of experimental design techniques. Hydrometallurgy 17:315–334

    Article  CAS  Google Scholar 

  8. Yan TY (1990) Uranium precipitation from eluate using hydrogen peroxide American Institute of Mining and Metallurgical Engineers. Miner Metall Process 288:222–224

    CAS  Google Scholar 

  9. Kwang-Wook K, Jun-Taek H, Eil-Hee L, Geun-II P, Kune-Woo L, Myung-June Y, Kee-Chan S, Jei-Kwon M (2011) Recovery of uranium from (U, Gd)O2 nuclear fuel scrap using dissolution and precipitation in carbonate media. J Nucl Mater 418:93–97

    Article  Google Scholar 

  10. Jing B, Xiaojie Y, Yongfeng Z, Fangli F, Xiaolei W, Wei T, Cunmin T, Xin Z, Yang W, Shiwei C, Fuyou F, Zhi Q, Junsheng G (2016) Selective uranium sorption from salt lake brines by amidoximated Saccharomyces cerevisiae. Chem Eng J 283:889–895

    Article  Google Scholar 

  11. Mingbiao L, Shujuan L, Jiangiang L, Feng L, Hailu L, Peipei Y (2016) Uranium sorption characteristics onto synthesized pyrite. J Radioanal Nucl 307:305–312

    Article  Google Scholar 

  12. Helfrid SHMA, Andrea SJC, Perrine C, Margaret GC (2016) Effect of pH and pressure on uranium removal from drinking water using NF/RO membranes. Environ Sci Technol 50:5817–5824

    Article  Google Scholar 

  13. Jun L, Changsong Z, Zhibin Z, Jiali L, Yunhai L, Xiaohong C, Jijun Y, Yuanyou Y, Ning L (2016) Fluorine effects on U(VI) sorption by hydroxyapatite. Chem Eng J 288:505–515

    Article  Google Scholar 

  14. Marek P, Carter WA, Xin Z, Nathan CT, Zhong L, Wenbin L (2016) Design, synthesis, and characterization of a bifunctional chelator with ultrahigh capacity for uranium uptake from seawater simulant. Ind Eng Chem Res 55:4170–4178

    Article  Google Scholar 

  15. Ahmed AG, Mohammad GM, Nabawia AG, Sayed SAR, Asem AA, Thierry V, Eric G (2015) Cysteine-functionalized Chitosan magnetic nano-based particles for the recovery of uranium(VI): uptake kinetics and sorption isotherms. Sep Sci Technol 50:2776–2789

    Google Scholar 

  16. Xiangxue W, Qiaohui F, shunjun Y, Zhongshan C, Yuejie A, Yubing S, Aatef H, Ahmed A, xiangke W (2016) High sorption of U(VI) on graphene oxides studied by batch experimental and theoretical calculations. Chem Eng J 287:448–455

    Article  Google Scholar 

  17. Yubing S, Zhen-Yu W, Xiangxue W, Congcong D, Wencai C, Shu-Hong Y, Xiangke W (2016) Macroscopic and microscopic investigation of U(VI) and Eu(III) adsorption on carbonaceous nanofibers. Environ Sci Technol 50:4459–4467

    Article  Google Scholar 

  18. Zhaowu Z, Yoko P, Chu YC (2016) Uranium recovery from strong acidic solutions by solvent extraction with cyanex 923 and a modifier. Miner Eng 89:77–83

    Article  Google Scholar 

  19. Afshin K, Xiaolong W, Yuezhou W (2016) Solid phase extraction of uranium (VI) from phosphoric acid medium using macroporous silica-based D2EHPA-TOPO impregnated polymeric adsorbent. Hydrometallurgy 164:90–96

    Article  Google Scholar 

  20. Hong- Y, shan-shan Y, Hui-min R, Jiang-nan S, Cong-jie G, Bart BV (2015) Recovery of uranium ions from simulated seawater with palygorskite/amidoxime polyacrylonitrile composite. Appl Clay Sci 111:67–75

    Article  Google Scholar 

  21. Mohamed CF (2015) Synthesis of pyridylazo resorcinol - functionalized Amberlite XAD-16 and its characteristics for uranium recovery. J Environ Chem Eng 3:642–652

    Article  Google Scholar 

  22. Santosh KS, Sangita P, Saswati BR, Tewari PK (2014) Removal of uranium (VI) from dilute aqueous solutions using novel sequestering sorbent poly-acryl hydroxamic acid. J Environ Chem Eng 2:1343–1351

    Article  Google Scholar 

  23. Vaaramaa K, Pulli S, Lehto J (2000) Effects of pH and uranium concentration on the removal of uranium from drinking water by ion exchange. Radiochim Acta 88:845–849

    CAS  Google Scholar 

  24. Seko N, Tamada M, Yoshii F (2004) The evaluation of graft-adsorbent for removal uranium from waste sludge. Trans At Energy Soc Jpn 3:340–345

    Article  CAS  Google Scholar 

  25. Oshita K, Sabarudin A, Takayanagi T, Oshima M, Motomizu S (2009) Adsorption behavior of uranium(VI) and other ionic species on cross-linked chitosan resins modified with chelating moieties. Talanta 79:1031–1035

    Article  CAS  Google Scholar 

  26. Nogami M, Sugiyama Y, Kawasaki T, Harada M, Morita Y, Kikuchi T, Ikeda Y (2010) Adsorptivity of polyvinylpolypyrrolidone for selective separation of U(VI) from nitric acid media. J Radioanal Nucl Chem 283:541–546

    Article  CAS  Google Scholar 

  27. Berthelet M, Whyte LG, Greer CW (1996) Rapid, direct extraction of DNA from soils for PCR analysis using polyvinylpolypyrrolidone spin columns. FEMS Microbiol Lett 138:17–22

    Article  CAS  Google Scholar 

  28. Mustafa R, Chandra G, Andrew M (2005) Beer stabilization technology-clearly a matter of choice. MBAA TQ 42:332–338

    Google Scholar 

  29. Nogami M, Sugiyama Y, Kawasaki T, Harada M, Kawata Y, Morita Y, Kikuchi T, Ikeda Y (2013) Stability of polyvinylpolypyrrolidone against gamma-ray irradiation in HNO3 media. J Radioanal Nucl Chem 296:423–427

    CAS  Google Scholar 

  30. Bordbar AK, Saboury AA, Moosavi-Movahedi AA (1996) The shapes of Scatchard plots for systems with two sets of binding sites. Biochem Educ 24:172–175

    Article  CAS  Google Scholar 

  31. Berezhkovskiy LM, Astafieva IV, Cardoso C (2002) Analysis of peptide affinity to major histocompatibility complex proteins for the two-step binding mechanism. Anal Biochem 308:239–246

    Article  CAS  Google Scholar 

  32. Ayar A, Mercimek B (2006) Interaction of nucleic acid bases and nucleosides with cobalt ions immobilized in a column system. Process Biochem 41:1553–1559

    Article  CAS  Google Scholar 

  33. Xu Z, Kuang D, Liu L, Deng Q (2007) Selective adsorption of norfloxacin in aqueous media by an imprinted polymer based on hydrophobic and electrostatic interactions. J Radiophar Anal 45:54–61

    CAS  Google Scholar 

  34. Gezici O, Kara H, Ayar A, Topkafa M (2007) Sorption behavior of Cu(II) ions on insolubilized humic acid under acidic conditions: an application of Scatchard plot analysis in evaluating the pH dependence of specific and nonspecific bindings. Sep Pur Technol 55:132–139

    Article  CAS  Google Scholar 

  35. Varga TR, Benyei AC, Fazekas Z, Tomiyasu H, Ikeda Y (2003) Molecular and crystal structure of bis(N-cyclohexyl-2-pyrrolidone)dioxouranium(VI) nitarate. Inorg Chim Acta 342:291–294

    Article  CAS  Google Scholar 

  36. Ikeda Y, Wada E, Harada M, Chikazawa T, Kikuchi T, Mineo H, Morita Y, Nogami M, Suzuki K (2004) A study on pyrrolidone derivatives as selective precipitant for uranyl ion in HNO3. J Alloys Compd 374:420–425

    Article  CAS  Google Scholar 

  37. Takao K, Noda K, Morita Y, Nishimura K, Ikeda Y (2008) Molecular and crystal structures of uranyl nitrate complexes with N-alkylated-2-pyrrolidone derivatives: design and optimization of promising precipitant for uranylion. Cryst Growth Des 8:2364–2376

    Article  CAS  Google Scholar 

  38. Szabo Z, Toraishi T, Vallet V, Grenthe I (2006) Solution coordination chemistry of actinides: thermodynamics, structure and reaction mechanisms. Coord Chem Rev 250:784–815

    Article  CAS  Google Scholar 

  39. ASTM C967-02 (2002) Standard specification for uranium ore concentrate

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Acknowledgments

The authors are grateful to members of the Waste Management Engineering Section, Environmental Research and Development Department, Ningyo-toge Environmental Engineering Center, Sector of Decommissioning and Radioactive Waste Management, Japan Atomic Energy Agency.

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Correspondence to Yusuke Ohashi.

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Ohashi, Y., Harada, M., Asanuma, N. et al. Applicability of polyvinylpolypyrrolidone adsorbent to treatment process of wastes containing uranium. J Radioanal Nucl Chem 311, 491–502 (2017). https://doi.org/10.1007/s10967-016-5017-9

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  • DOI: https://doi.org/10.1007/s10967-016-5017-9

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