Skip to main content
SpringerLink
Log in

Sorption of strontium by sorbents on the base of di-(tert-butylcyclohexano)-18-crown-6 with use of various diluents

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Set of sorbents were obtained on the base of di-(tert-butylcyclohexano)-18-crown-6, various diluents and styrene–divinylbenzene support for strontium sorption from nitric acid solutions. First it was proposed to use nitrobenzene and 1,1,7-trihydrododecafluoroheptanol as diluents in obtaining sorbents on the base of crown ethers, it was shown higher efficiency of these diluents in comparison with 1-octanol. The effect of method of support pretreatment, a concentration of crown ether in a sorbent and nitric acid in solution on strontium sorption were examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Nesterov SV (2000) Crown ethers in radiochemistry. Advances and prospects. Russ Chem Rev 69:769–782. doi:10.1070/RC2000v069n09ABEH000586

    Article  CAS  Google Scholar 

  2. Bezhin NA, Dovhyi II (2015) Sorbents based on crown ethers: preparation and application for the sorption of strontium. Russ Chem Rev 84:1279–1293. doi:10.1070/RCR4505

    Article  CAS  Google Scholar 

  3. Dietz ML, Yaeger J, Sajdak LR Jr, Jensen MP (2005) Characterization of an improved extraction chromatographic material for the separation and preconcentration of strontium from acidic media. Sep Sci Technol 40:349–366. doi:10.1081/SS-200042247

    Article  CAS  Google Scholar 

  4. Zhang A, Xiao Ch, Liu Y, Hu Q, Chen Ch, Kuraoka E (2010) Preparation of macroporous silica-based crown ether materials for strontium separation. J Porous Mater 17:153–161. doi:10.1007/s10934-009-9287-2

    Article  CAS  Google Scholar 

  5. Zhang A, Hu Q, Chai Zh (2009) SPEC: a new process for strontium and cesium partitioning utilizing two macroporous silica-based supramolecular recognition agents impregnated polymeric composites. Sep Sci Technol 44:2146–2168. doi:10.1080/01496390902885239

    Article  CAS  Google Scholar 

  6. Zhang A, Wei YZ, Kumagai M, Koyama T (2004) Kinetics of the adsorption of strontium(II) by a novel silica-based 4,4′, (5′)-di(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium. J Radioanal Nucl Chem 262:739–744. doi:10.1007/s10967-004-0502-y

    Article  CAS  Google Scholar 

  7. Horwitz EPh, Dietz ML, Chiarizia R (1992) The application of novel extraction chromatographic materials to the characterization of radioactive waste solutions. J Radioanal Nucl Chem 161:575–583. doi:10.1007/BF02040504

    Article  CAS  Google Scholar 

  8. Horwitz EPh, Dietz ML, Rhoads S, Felinto C, Gale NH, Houghton J (1994) A lead-selective extraction chromatographic resin and its application to the isolation of lead from geological samples. Anal Chim Acta 292:263–273. doi:10.1016/0003-2670(94)00068-9

    Article  CAS  Google Scholar 

  9. Dietz ML, Dzielawa JA, Laszak I, Young BA, Jensen MP (2003) Influence of solvent structural variations on the mechanism of facilitated ion transfer into room-temperature ionic liquids. Green Chem 5:682–685. doi:10.1039/b310507p

    Article  CAS  Google Scholar 

  10. Kremliakova NY, Novikov AP, Myasoedov BF (1990) Extraction chromatographic separation of radionuclides of strontium, cesium and barium with the use of TVEX-DCH18C6. J Radioanal Nucl Chem 145:23–28. doi:10.1007/BF02328764

    Article  CAS  Google Scholar 

  11. Kremlyakova NY (1993) Determination of radiostrontium in environmental objects by extraction chromatography using tvex-DCH18C6. J Radioanal Nucl Chem 170:189–196. doi:10.1007/BF02134590

    Article  CAS  Google Scholar 

  12. Yakshin VV, Tsarenko NA, Zhukova NG, Laskorin BN (1992) Methods of preparing solid extractants on the base of crown ethers in a polymer matrix. Dokl Akad Nauk 325:748–750

    CAS  Google Scholar 

  13. Zakurdaeva OA, Nesterov SV (2015) Improved extraction-spectrophotometric method for determination of dicyclohexano-substituted crown ethers in aqueous solutions. J Radioanal Nucl Chem 303:1737–1744. doi:10.1007/s10967-014-3799-1

    CAS  Google Scholar 

  14. Horwitz EPh, Chiarizia R, Dietz ML (1992) A novel strontium-selective extraction chromatographic resin. Solv Extr Ion Exch 10:313–336. doi:10.1080/07366299208918107

    Article  CAS  Google Scholar 

  15. Chiarizia R, Horwitz EPh, Dietz ML (1992) Acid dependency of the extraction of selected metal ions by a strontium. Selective extractlon chromatographic resin: calculated vs. experimental curves. Solv Extr Ion Exch 10:337–361. doi:10.1080/07366299208918108

    Article  CAS  Google Scholar 

  16. Bezhin NA, Dovhyi II, Lyapunov AYu (2015) Sorption of strontium by the endoreceptor dibenzo-18-crown-6 immobilized in a polymer matrix. J Radioanal Nucl Chem 303:1927–1931. doi:10.1007/s10967-014-3770-1

    CAS  Google Scholar 

  17. Horwitz EPh, Dietz ML (1989) Method for the concentration and separation of actinides from biological and environmental samples. US Patent 4835107A

  18. Yi R, Ye G, Wu F, Lv D, Chen J (2016) Magnetic solid-phase extraction of strontium using core–shell structured magnetic microspheres impregnated with crown ether receptors: a response surface optimization. J Radioanal Nucl Chem 308:599–608. doi:10.1007/s10967-015-4468-8

    Article  CAS  Google Scholar 

  19. Song Y, Du Y, Lv D, Ye G, Wang J (2014) Macrocyclic receptors immobilized to monodisperse porous polymer particles by chemical grafting and physical impregnation for strontium capture: a comparative study. J Hazard Mater 274:221–228. doi:10.1016/j.jhazmat.2014.04.010

    Article  CAS  Google Scholar 

  20. Voroshilov YuA, Logunov MV, Smolyanihin KV, Yakovlev NG (2013) Bench tests of technology of joint extraction radionuclides 137Cs and 90Sr from liquid high level waste by extractant on the base of crown ethers. Quest Radiat Saf 2:23–33

    Google Scholar 

  21. Ananyev AV, Tsarenko NA, Strelnikova AM, Koshcheev AM, Tsivadze AYu (2014) Extraction of cesium by crown ethers in the presence of activating additive. Russ Chem Bull 63:1308–1311. doi:10.1007/s11172-014-0595-6

    Article  CAS  Google Scholar 

  22. Demin SV, Fatyushina EV, Zhilov VI, Yakshin VV, Vilkova OM, Tsarenko NA, Tsivadze AYu (2008) Separation of components of the solution modeling PUREX raffinate via extraction by crown ethers to 1,1,7-trihydrododecafluoroheptanol. Russ J Inorg Chem 53:1149–1153. doi:10.1134/S0036023608070280

    Article  Google Scholar 

  23. Yakshin VV, Vilkova OM, Pluzhnik-Gladyr SM, Кotlyar SA (2010) Crown ethers in extraction and sorption. I. Bromo derivatives of benzo- and dibenzocrown ethers in the sorption processes of elements from acidic water solutions. Macroheterocycles 3:114–120

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The study was performed as part of scientific research on the theme “Development of sorbents on the base of crown ethers for sorption strontium from spent nuclear fuel” funded by Foundation for Assistance to Small Innovative Enterprises in Science and Technology winner of the contest “Participant of Youth Scientifically-Innovation Contest”.

Author information

Authors and Affiliations

  1. Sevastopol State University, University Street, 33, Sevastopol, Russian Federation, 299053

    N. A. Bezhin & I. I. Dovhyi

  2. Marine Hydrophysical Institute, Russian Academy of Sciences, Kapitanskaya Street, 2, Sevastopol, Russian Federation, 299011

    I. I. Dovhyi

  3. A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya doroga Street, 86, Odessa, 65080, Ukraine

    A. Yu. Lyapunov

Authors
  1. N. A. Bezhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Dovhyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Yu. Lyapunov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to N. A. Bezhin or I. I. Dovhyi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bezhin, N.A., Dovhyi, I.I. & Lyapunov, A.Y. Sorption of strontium by sorbents on the base of di-(tert-butylcyclohexano)-18-crown-6 with use of various diluents. J Radioanal Nucl Chem 311, 317–322 (2017). https://doi.org/10.1007/s10967-016-4983-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-016-4983-2

Keywords

Search

Navigation