Abstract
Quality evaluation of the k 0-standardized neutron activation analysis (k 0-NAA) at Dalat research reactor (DRR) has been implemented by analyzing the SMELS, a synthetic multi-element standard material as well as the certified reference materials for purposes of validation and verification of the method. The results revealed that the k 0-NAA established at DRR has met the requirements of multi-element analysis for the intended applications with about 42 elements: Al, As, Au, Ba, Br, Ca, Ce, Cl, Co, Cr, Cs, Cu, Dy, Eu, Fe, Hf, I, In, K, La, Mg, Mn, Mo, Na, Nd, Pr, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, Ti, U, V, W, Yb, Zn and Zr in matrices of environment, geology and biology among others. Evaluation criteria for the laboratory quality used in this work are the statistical analysis parameters namely: u-scores, laboratory result/certified value ratios and relative biases as well as the control charts those are shown in the paper.
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References
Dung HM, Hien PD (2003) The application and development of k0-standardization method of neutron activation analysis at Dalat research reactor. J Radioanal Nucl Chem 257:643–647
Dung HM, Cho SY (2003) A simple method for alpha determination. J Radioanal Nucl Chem 257:573–575
Dung HM, Sasajima F (2003) Determination of alpha and f for k0-NAA in irradiation sites with high thermalized neutrons. J Radioanal Nucl Chem 257:509–512
ISO/IEC 17025:2005, General Requirements for the Competence of Testing and Calibration Laboratories, ISO, Geneva
Holden NE (1999) Temperature dependence of the westcott g-factor for neutron reactions in activation analysis. Pure Appl Chem 71:2309–2315
Doanh HV, Dung HM, Thien TQ, Sy NT, Dien NN (2016), Combination and optimization of cyclic NAA modes at the Dalat research reactor for determination of selenium in biological materials using 77mSe, J Radioanal Nucl Chem (submitted)
Freitas MC, Révay Z, Szentmiklosi L, Dionisio I, Dung HM, Pacheco AMG (2008) Different methodologies in neutron activation to approach the full analysis of environmental and nutritional samples. J Radioanal Nucl Chem 278:381–386
Dung HM, Binh NT (2004) Services as provided to customer by nuclear analytical techniques at the Dalat Nuclear Research Institute. IAEA Technical Meeting on the Commercial Applications of Nuclear Analytical Techniques, Vienna, pp 72–75
Ebihara M, Chung YS, Dung HM, Moon JH, Ni BF, Otoshi T, Oura Y, Santos FL, Sasajima F, Sutisna Wee BS, Wimolwattanapun W, Wood AKBH (2008) Application of NAA to air particulate matter collected at thirteen sampling sites in eight Asian countries: a collaborative study. J Radioanal Nucl Chem 278:463–467
Dung HM, Ngo NT, Binh NT (2003) Implementation of Quality System for Nuclear Analytical Techniques (NATs) at the Dalat Nuclear Reserch Institute of Vietnam, IAEA Regional Workshop on QA/QC of NATs (RAS/2/010). KAERI, Korea
Vermaercke P, Robouch P, Eguskiza M, De Corte F, Kennedy G, Smodis B, Jacimovic R, Yonezawa C, Matsue H, Lin X, Blaauw M, Kucera J (2006) Characterisation of synthetic multi-element standards (SMELS) used for the validation of k 0-NAA. Nucl Instrum Meth A 564:675–682
Wasim M, Zaidi JH, Arif M (2010) Use of synthetic multi-element standards (SMELS) in the quality control and method validation of k0-neutron activation analysis. Radiochim Acta 98:183–186
Bennett JW, Ebihara M, Tanaka T, Armishaw P, Iavetz R, Cao VD, Hossain S, Huang D, Sutisna SalimN (2012) A trial proficiency test of eight NAA laboratories in Asia using stream sediments. J Radioanal Nucl Chem 291:535–541
Wimolwattanapun W, Bunprapob S, Dung HM, Sutisna Oura Y, Ebihara M (2014) Quality assessment of INAA data for small-sized environmental reference samples. Anal Sci. 30:787–792
Brookes CJ, Betteley IG, Loxton SM (1979) Fundamentals of Mathematics and Statistics. John Wiley & Sons, Birmingham
Dung HM, Freitas MC, Blaauw M, Almeida SM, Dionisio I, Canha NH (2010) Quality control and performance evaluation of k0-based neutron activation analysis at the Portuguese research reactor. Nucl Instrum Meth A 622:392–398
Roelandts I, Gladney ES (1998) Consensus values for NIST biological and environmental Standard Reference Materials. Fresenius J Anal Chem 360:327–338
Wee BS, Dung HM, Wood AKBH, Salima NA, Eliasa MS (2006) Testing the applicability of the k0-NAA method at the MINT’s TRIGA MARK II reactor. Nucl Instrum Meth A 564:716–720
Acknowledgments
The financial support through national projects by the MOST of Vietnam is gratefully acknowledged. Our gratitude extends to Mr. Le Vinh Vinh and the DRR’s operators for their kind supporting the implementation of this work. The International Atomic Energy Agency is gratefully acknowledged via TC projects.
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Ho, MD., Tran, QT., Ho, VD. et al. Quality evaluation of the k 0-standardized neutron activation analysis at the Dalat research reactor. J Radioanal Nucl Chem 309, 135–143 (2016). https://doi.org/10.1007/s10967-016-4795-4
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DOI: https://doi.org/10.1007/s10967-016-4795-4