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Retention of cesium from aqueous solutions using synthetic zeolites produced from power plant ash

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Abstract

New materials were synthesized from power plant ash, characterized by a variety of analytical techniques and studied as cesium sorbents from aqueous solutions. The Cs-determination was performed by γ-ray spectroscopy using 137Cs-labelled solutions under varying initial concentration, contact time, pH, presence of competing cations and temperature. The experimental sorption isotherms were modeled using the Langmuir and Freundlich equations and thermodynamic parameters (ΔG 0, ΔH 0, ΔS 0) were calculated from kinetics data obtained for 298, 308 and 323 K. The application of SEM/EDS, XRD, TGA and FTIR demonstrated the formation of stable zeolitic phases after the synthesis and support the proposed mechanism for the sorption process.

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Acknowledgments

The support of Mrs G. Buema by the POSDRU CUANTUMDOC “Doctoral studies for European performances in research and innovation” project ID79407 funded by the European Social Fund and the Romanian Government is thankfully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Aristotle University, 54124, Thessaloniki, Greece

    Fotini Noli, Gabriela Buema & Panagiotis Misaelides

  2. Faculty of Chemical Engineering and Environmental Protection, “Gheorghe Asachi” Technical University of Iasi, 73 Prof. dr. docent D. Mangeron Street, 700050, Iasi, Romania

    Gabriela Buema & Maria Harja

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  1. Fotini Noli
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  2. Gabriela Buema
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  3. Panagiotis Misaelides
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  4. Maria Harja
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Correspondence to Fotini Noli.

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Noli, F., Buema, G., Misaelides, P. et al. Retention of cesium from aqueous solutions using synthetic zeolites produced from power plant ash. J Radioanal Nucl Chem 309, 589–596 (2016). https://doi.org/10.1007/s10967-015-4611-6

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  • DOI: https://doi.org/10.1007/s10967-015-4611-6

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