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A technique for determination of metallic impurities in Al2O3 matrix by EDXRF

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Abstract

The applicability of energy dispersive X-ray fluorescence spectrometry as an analytical technique for the determination of a few metallic impurities such as Ca, Cr, Cu, Fe, Mn, Pb, and Zn in alumina (Al2O3) matrix was investigated. A series of Al2O3 standards containing the elements of interest in the range 10–1000 ppm was prepared and the spectrometer conditions were optimized to obtain calibration plots for the various analytes that could be further used for the analysis of actual samples. The present method serves as an alternative to currently used AES method for analytes expected in the concentration range 50–1000 ppm.

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References

  1. Srikumar Banerjee (2014) Overview of Indian activities on fusion reactor materials. J Nucl Mater 455:217–224

    Article  Google Scholar 

  2. Ansarifar GR, Ebrahimian M (2016) Design and neutronic investigation of the nano fluids application to VVER-1000 nuclear reactor with dual cooled annular fuel. Ann Nucl Energy 87:39–47

    Article  CAS  Google Scholar 

  3. Rieke JK, Daniels FJ (1957) Thermoluminescence studies of aluminum oxide. J Phys Chem 51:629–633

    Article  Google Scholar 

  4. Mc Dougall RS, Rudin S (1970) Thermoluminescent dosimetry of alumina. Health Phys 19:281–283

    Article  CAS  Google Scholar 

  5. Akselrod MS, Kortov VS, Kravetsky DJ, Gotlib VI (1990) Highly sensitive thermoluminescent anion defective & αAl2O3: C single crystal detectors. Radiat Prot Dosim 32:15–20

    CAS  Google Scholar 

  6. Cooper MH, Taylor GR (1971) Measurments of cesium sorption isotherms in liquid sodium. Nucl Technol 12:83–92

    CAS  Google Scholar 

  7. Davis K (2011) Materials review: alumina (Al2O3). Sch Doct Stud (Eur Uni) J 2:109–114

    Google Scholar 

  8. Faure R, Rossignol F, Chartier T, Bonhom C, Maître A, Etchegoyen G, Gallo PD, Gar D (2011) Alumina foam catalyst supports for industrial steam reforming processes. J Eur Ceram Soc 31:303–312

    Article  CAS  Google Scholar 

  9. Samodurova A, Kocjan A, Swain MV, Kosmac T (2015) The combined effect of alumina and silica co-doping on the ageing resistance of 3Y-TZP bioceramics. Acta Biomater 11:477–487

    Article  CAS  Google Scholar 

  10. Sinha VP, Mishra GP, Pal S, Khan KB, Hegde PV, Prasad GJ (2008) Development of powder metallurgy technique for synthesis of U3Si2 dispersoid. J Nucl Mater 383:196–200

    Article  CAS  Google Scholar 

  11. Berlin EA (1984) Principles and practice of X-ray spectrometric analysis. Plenum Press, New York

    Google Scholar 

  12. Margui E, Zawisza B, Sitko R (2014) Trace and ultratrace analysis of liquid samples by X-ray fluorescence spectrometry. TrAC. Trends Anal Chem 53:73–83

    Article  CAS  Google Scholar 

  13. Padilla R, Van Espen P, Godo Torres PP (2006) The suitability of XRF analysis for compositional classification of archaelogical ceramic fabric: a comparison with a previous NAA. Anal Chim Acta 558:283–289

    Article  CAS  Google Scholar 

  14. Siyanbola WO, Fasasi AY, Fantua II, Afolabi OM, Adesiyan TA, Adetunji AR (2004) Elemental composition of rutile from south-western Nigeria using X-ray techniques. Nucl Instrum Methods Phys Res B 215:240–245

    Article  CAS  Google Scholar 

  15. Bao S, Wang Z, Rong L (1998) X-ray fluorescence analysis of Kaolin concentrate. Guang Pu Xue Yu Guang Pu Fen Xi 18:739–741

    CAS  Google Scholar 

  16. Jayadevan NC, Chawla KL, Singh KD, Dahale ND, Chackraburthy DM (1984) X-ray spectrometric methods for the determination of plutonium and uranium in their mixed oxide samples. J Radioanal Nucl Chem 82:125–134

    Article  CAS  Google Scholar 

  17. Misra NL, Singh KD, Adya VC, Rajeswari B, Venugopal V (2005) Determination of trace elements in uranium oxide by total reflection X-ray fluorescence spectrometry. Spectrochim Acta B 60:834–840

    Article  Google Scholar 

  18. Natarajan V, Kulkarni MJ, Porwal NK, Dhawale BA, Hon NS, Godbole SV, Manchanda VK (2008) Determination of uranium content in Th, U Mixed oxides using EDXRF. Nucl Instrum Methods Phys Res B 266:3290–3294

    Article  CAS  Google Scholar 

  19. Greenaway AM, Bucknor AN, Henry K, Coley MD (2013) Identifying possible associations of minor and trace elements with major elements in Jamaican hillside and catchment bauxites using multivariate analysis tools. Miner Eng 53:124–135

    Article  CAS  Google Scholar 

  20. Idris Y, Funtua II, Umar IM (2004) Rapid analysis with energy-dispersive X-ray fluorescence spectrometry for bauxite investigation on the Mambilla Plateau, North Eastern Nigeria. Chem Erde 64:385–398

    Article  CAS  Google Scholar 

  21. Peschel BU, Fittschen UEA, Pepponi G, Jokubonis C, Streli C, Wobrauschek P, Falkenberg G, Broekaert JAC (2005) Direct analysis of Al2O3 powders by total reflection X-ray fluorescence spectrometry. Anal Bioanal Chem 382:1958–1964

    Article  CAS  Google Scholar 

  22. Devi Remya PS, Trupti AC, Nicy A, Dalvi AA, Swain KK, Wagh DN, Verma R (2015) Evaluation of uncertainty in the energy dispersive X-ray fluorescence determination of platinum in alumina. Anal Methods 7:5345–5351

    Article  Google Scholar 

  23. Ramaniah MV (1982) Analytical chemistry of fast reactor fuels—a review. Pure Appl Chem 54:889–908

    Article  CAS  Google Scholar 

  24. Page AG, Godbole SV, Deshkar S, Babu Y, Joshi BD (1977) Spectrographic determination of metallic impurities in PuO2. Fresenius Z Anal Chem 287:304–309

    Article  CAS  Google Scholar 

  25. Natarajan V, Kulkarni MJ, Porwal NK, Dhawale BA, Hon NS, Godbole SV, Manchanda VK (2008) Determination of uranium content in Th, U mixed oxides using EDXRF. Nucl Instrum Methods Phys Res B 266:3290–3294

    Article  CAS  Google Scholar 

  26. Natarajan V, Rajeswari B, Dhawale BA, Hon NS, Godbole SV, Manchanda VK (2009) Application of energy dispersive X-ray fluorescence for the determination of metallic impurities in ThO2. J Radioanal Nucl Chem 280:27–31

    Article  CAS  Google Scholar 

  27. Natarajan V, Dhawale BA, Rajeswari B, Hon NS, Thulasidas SK, Porwal NK, Godbole SV, Manchanda VK (2008) Determination of metallic impurities in U3O8 using energy dispersive X-ray fluorescence spectrometry. Spectrochim Acta B 63:817–819

    Article  Google Scholar 

  28. Porwal NK, Natarajan V, Kumar M, Rajeswari B, Kulkarni MJ, Bhide MK, Dhawale BA, Godbole SV (2010) EDXRF determination of Dy, Eu, Gd & Sm in aqueous solutions. Ind J Chem 49:1052–1055

    Google Scholar 

  29. Natarajan V, Porwal NK, Babu Y, Rajeswari B, Dhawale BA, Mithlesh Kumar, Godbole SV, Manchanda VK (2010) Direct determination of metallic impurities in graphite by EDXRF. Appl Radiat Isot 68:1128–1131

    Article  CAS  Google Scholar 

  30. Nimai Pathak, Adya VC, Thulasidas SK, Arijit Sengupta, Seshagiri TK, Godbole SV (2014) Direct determination of trace elements in ZrO2 by D.C. Arc-carrier distillation technique using CCD-based spectrometer. At Spectrosc 35:17–24

    Google Scholar 

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Acknowledgments

The authors are thankful to Dr. A. Goswami, Former Head, Radiochemistry Division, B.A.R.C., for providing constant support and encouragement for carrying out this work.

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Authors and Affiliations

  1. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085, India

    B. Rajeswari, N. S. Hon, R. M. Kadam, M. Mohapatra & V. Natarajan

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  1. B. Rajeswari
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  2. N. S. Hon
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  3. R. M. Kadam
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  4. M. Mohapatra
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  5. V. Natarajan
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Correspondence to B. Rajeswari.

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Rajeswari, B., Hon, N.S., Kadam, R.M. et al. A technique for determination of metallic impurities in Al2O3 matrix by EDXRF. J Radioanal Nucl Chem 308, 357–362 (2016). https://doi.org/10.1007/s10967-015-4589-0

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  • DOI: https://doi.org/10.1007/s10967-015-4589-0

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