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Migration and sorption of strontium in clay-sand mixtures

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Abstract

The migration and sorption of Sr in clay-sand mixture were investigated by batch experiment, column experiments and numerical simulation. The results showed that as the clay content in clay-sand mixture increased, the effective porosity, absorption capacity and retardation factor of the mixture for Sr increased, but the dispersion coefficient and migration velocity decreased. The migration of Sr was influenced strongly when clay content was in range of 0–25 %, but influenced weakly when clay content was more than 25 %. The experimental data was consistent with the calculated results by CXTFIT program.

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References

  1. Jacquier P, Hainos D, Robinet JC, Herbette M, Grenut B, Bouchet A, Ferry C (2013) The influence of mineral variability of callovo–oxfordian clay rocks on radionuclide transfer properties. Appl Clay Sci 83:129–136

    Article  Google Scholar 

  2. Kosakowski G, Berne U (2013) The evolution of clay rock/cement interfaces in a cementitious repository for low- and intermediate level radioactive waste. Phys Chem Earth 64:65–86

    Article  Google Scholar 

  3. Landais P, Aranyossy JF (2011) Clays in natural and engineered barriers for radioactive waste confinement. Phys Chem Earth 36:14–37

    Article  Google Scholar 

  4. Mallants D, Marivoet J, Sillen X (2001) Performance assessment of the disposal of vitrified high-level waste in a clay layer. Nucl Mater 298:125–135

    Article  CAS  Google Scholar 

  5. Albrecht BA, Benson CH (2001) Effect of desiccation on compacted natural clay. J Geotech Geoenviron Eng 127:67–75

    Article  Google Scholar 

  6. Rayhani MHT, Yanful EK, Fakher A (2007) Desiccation-induced cracking and its effect on the hydraulic conductivity of clayey soils from Iran. Can Geotech J 44:276–283

    Article  Google Scholar 

  7. Huang WR, Guo ZP (2000) Experimental research on Pr eventing desiccation cracking of compacted clay liner in municipal solid waste landfill. J Hohai Univ 28:19–22

    Google Scholar 

  8. Rothfuchs T, Jockwer N, Zhang CL (2007) Self-sealing barriers of clay/mineral mixtures—the SB project at the Mont Terri Rock Laboratory. Phys Chem Earth 32:108–111

    Article  Google Scholar 

  9. Saba S, Barnichon JD, Cui YJ (2014) Microstructure and anisotropic swelling behaviour of compacted bentonite/sand mixture. J Rock Mech Geotech Eng 6:126–132

    Article  Google Scholar 

  10. Sun DA, Zhang JY, Zhang JR (2013) Swelling characteristics of GMZ bentonite and its mixtures with sand. Appl Clay Sci 83:224–230

    Article  Google Scholar 

  11. Wang Q, Tang AM, Cui YJ (2013) The effects of technological voids on the hydro-mechanical behaviour of compacted bentonite–sand mixture. Soils Found 53:232–245

    Article  Google Scholar 

  12. Chirkst DE, Litvinova TE, Cheremisina OV, Ivanov MV, Mironnenkova NA (2003) Isotherm of strontium sorption on clay. Russ J Appl Chem 76:755–758

    Article  Google Scholar 

  13. Galambos M, Kufcakova J, Rajec P (2009) Sorption of strontium on Slovak bentonites. J Radioanal Nucl Chem 281:347–357

    Article  CAS  Google Scholar 

  14. Khan SA (2003) Sorption of the long-lived radionuclides cesium-134, strontium-85 and cobalt-60 on bentonite. J Radioanal Nucl Chem 258:3–6

    Article  CAS  Google Scholar 

  15. Missana T, Gutierrez MG, Alonso U (2008) Adsorption of bivalent ions (Ca(II), Sr(II) and Co(II)) onto FEBEX bentonite. Phys Chem Earth. 33:156–162

    Article  Google Scholar 

  16. Syed HS, Syed A (1995) Competitive adsorption of 90Sr on soil sediments, pure clay phases and feldspar minerals. Appl Radiat Isot 46:287–292

    Article  Google Scholar 

  17. Vanessa ED, Jarbas RR, Solange C, Gilberto A, Marco TG (2014) Montmorillonite and vermiculite as solid phases for the preconcentration of trace elements in natural waters: adsorption and desorption studies of As, Ba, Cu, Cd Co, Cr, Mn, Ni, Pb, Sr, V, and Zn. Appl Clay Sci 84:1–8

    Google Scholar 

  18. Zuo R, Teng YG, Wang JS (2009) Sorption and retardation of strontium in fine-particle media from a VLLW disposal site. J Radioanal Nucl Chem 279:893–899

    Article  CAS  Google Scholar 

  19. Zhang ML, Ren A, Shao X, Wang X (2005) Effect of fluvic acid and ionic strength on the sorption of radiostrontium on Chinese calcareous soil and its solid components. J Radioanal Nucl Chem 268:33–36

    Article  Google Scholar 

  20. Dewiere L, Bugai D, Grenier C, Kashparov V, Ahamdach N (2004) 90Sr migration to the geo-sphere from a waste burial in the chernobyl exclusion zone. J Environ Radioact 74:139–150

    Article  CAS  Google Scholar 

  21. Takriti S, Kheitou M, Ali AF (1999) Migration study of radioisotopes incorporated in cement. Appl Radiat Isot 50:401–406

    Article  CAS  Google Scholar 

  22. Rumyin VG, Mironova AV, Pankina EB, Chernomorova NV, Mysik SG (2004) A study of diffusion and sorption properties of Cambrian clays using radioactive tracers (36Cl and 90Sr). Radiochemistry 46:362–367

    Google Scholar 

  23. Shih CT, Shoung O, Chun NH (2001) Sorption and diffusion behavior of Cs and Sr on Jih-Hsing bentonite. Appl Radiat Isotop. 54:209–215

    Article  Google Scholar 

  24. Van Loon LR, Baeyens B, Bradbury MH (2005) Diffusion and retention of sodium and strontium in opalinus clay: comparison of sorption data from diffusion and batch sorption measurements and geochemical calculations. Appl Geochem 20:2351–2363

    Article  Google Scholar 

  25. Chia CC, Kim FH (1999) X-ray absorption spectroscopy investigation of aqueous Co(II) and Sr(II) sorption at clay-water interfaces. Geochim Cosmochim Acta. 63:3205–3215

    Article  Google Scholar 

  26. Li YF, Tian SH, Qian TW (2011) Transport and retention of strontium in surface-modified quartz sand with different wettability. J Radioanal Nucl Chem 289:337–343

    Article  CAS  Google Scholar 

  27. Zhang Y, Baeumer B, Benson DA (2006) Relationship between flux and resident concentrations for anomalous dispersion. Geophys Res Lett 33:L18407

    Google Scholar 

  28. Parker JC, Genuchten V, Baeumer B (1984) Flux averaged and volume averaged concentrations in continuum approaches to solute transport. Water Resour Res 20:866–872

    Article  Google Scholar 

  29. Relyea JF, Serne RJ, Rai D (1980) Methods for Determining Radionuclide Retardation Factors. Appendix C, standard method used at pacific northwest national laboratory for measuring batch K d values. PNNL Status Report, Richland, p. 13

  30. Missana T, Geckeis H (2006) Supporting laboratory experiments with radionuclides and bentonite colloids. Grimsel Test Site Investigation Phase V, The CRR Final Project Report Series II

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Acknowledgments

The research was supported by the Program for Changjiang Scholars and Innovative Research Team in University (IRT-13026). The authors would also like to thank the financial support provided by the Open Research Fund Program of Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education of China.

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Correspondence to Jianlong Wang.

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Yu, J., Wang, J. & Jiang, Y. Migration and sorption of strontium in clay-sand mixtures. J Radioanal Nucl Chem 308, 439–445 (2016). https://doi.org/10.1007/s10967-015-4477-7

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  • DOI: https://doi.org/10.1007/s10967-015-4477-7

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