Abstract
This article is an extended version of Hevesy Medal Award Lecture—2015, delivered at the Tenth International Conference on Methods and Applications of Radioanalytical Chemistry (MARC X) held at Hawai’i during 12–17 April 2015. The award was given on our works on heavy ion activation, tracer packet technique, converter targets and green chemistry. This article briefly addresses on all the four topics described above.
Similar content being viewed by others
References
Bode P (2012) Opportunities for innovation in neutron activation analysis. J Radioanal Nucl Chem 291:275–280
Khuyagbaatar J, Yakushev A, Düllmann ChE, Ackermann D, Andersson L-L, Asai M, Block M, Boll RA, Brand H, Cox DM, Dasgupta M, Derkx X, Di Nitto A, Eberhardt K, Even J, Evers M, Fahlander C, Forsberg U, Gates JM, Gharibyan N, Golubev P, Gregorich KE, Hamilton JH, Hartmann W, Herzberg R-D, Heßberger FP, Hinde DJ, Hoffmann J, Hollinger R, Hübner A, Jäger E, Kindler B, Kratz JV, Krier J, Kurz N, Laatiaoui M, Lahiri S, Lang R, Lommel B, Maiti M, Miernik K, Minami S, Mistry A, Mokry C, Nitsche H, Omtvedt JP, Pang GK, Papadakis P, Renisch D, Roberto J, Rudolph D, Runke J, Rykaczewski KP, Sarmiento LG, Schädel M, Schausten B, Semchenkov A, Shaughnessy DA, Steinegger P, Steiner J, Tereshatov EE, Thörle-Pospiech P, Tinschert K, Torres De Heidenreich T, Trautmann N, Türler A, Uusitalo J, Ward DE, Wegrzecki M, Wiehl N, Van Cleve SM, Yakusheva V (2014) 48Ca 249Bk fusion reaction leading to element Z 117: long-lived α-decaying 270Db and discovery of 266Lr. Phys Rev Lett 112:172501-1–172501-5
Düllmann ChE, Schädel M, Yakushev A, Türler A, Eberhardt K, Kratz JV, Ackermann D, Andersson L-L, Block M, Brüchle W, Dvorak J, Essel HG, Ellison PA, Even J, Gates JM, Gorshkov A, Graeger R, Gregorich KE, Hartmann W, Herzberg R-D, Heßberger FP, Hild D, Hübner A, Jäger E, Khuyagbaatar J, Kindler B, Krier J, Kurz N, Lahiri S, Liebe D, Lommel B, Maiti M, Nitsche H, Omtvedt JP, Parr E, Rudolph D, Runke J, Schausten B, Schimpf E, Semchenkov A, Steiner J, Thörle-Pospiech P, Uusitalo J, Wegrzecki M, Wiehl N (2010) Production and decay of element 114: high cross sections and the new nucleus 277Hs. Phys. Rev., Lett. 104:252701-1–252701-5
Lahiri S, Banerjee S, Das NR (1996) LLX separation of carrier free 47Sc, 48 V and 48,49,51Cr produced in & #x03B1;-particle activated titanium with HDEHP. Appl Radiat Isotopes 47:1–6
Das NR, Banerjee S, Lahiri S (1995) Sequential separation of carrier free 47Sc, 48 V and 48,49,51Cr from & #x03B1;-particle activated titanium with TOA. Radiochim Acta 69:61–64
Lahiri S, Banerjee S, Das NR (1996) Sequential separation of carrier free 52,56Mn, 55,56,58Co and 56,57Ni from & #x03B1;-particle activated iron with triisooctylamine. Appl Radiat Isot 47:413–415
Lahiri S, Banerjee S, Das NR (1997) Separation of carrier free 65Zn and 66,67,68Ga, the alpha particle activation products of copper with HDEHP. J Radioanal Nucl Chem 218:215–218
Lahiri S, Mukhopadhyay B, Das NR (1997) Simultaneous production of 89Zr and 90,91 m, 92mNb in & #x03B1;-particle activated yttrium and their subsequent separation by HDEHP. Appl Radiat Isotopes 48:883–886
Lahiri S, Mukhopadhyay B, Das NR (1997) LLX separation of carrier free, 94,95,97,103Ru, 93,94,95,96,99mTc and 95,96Nb produced in alpha-particle activated molybdenum by TOA. J Radioanal Nucl Chem 221:167–171
Lahiri S, Mukhopadhyay B, Nandy M, Das NR (1997) Sequential separation by HDEHP of carrier-free 101,105,106Rh, 103,104,105,106,110,112Ag and 104,105,107,109,111Cd produced in -particle activated palladium. J Radioanal Nucl Chem 224:155–158
Lahiri S, Nayak D, Nandy M, Das NR (1998) Separation of carrier free lutetium produced in proton activated ytterbium with HDEHP. Appl Radiat Isotopes 49:911–913
Nayak D, Lahiri S, Das NR (1999) Synergistic extraction of neodymium and carrier free promethium by the mixture of HDEHP and PC88A. J Radioanl Nucl Chem 240:555–560
Nayak D, Lahiri S (1999) Extraction and separation of 141Ce and 153Gd with HDEHP. J Radioanal Nucl Chem 240:75–77
Schlom J, Siler K, Milenic D (1991) Monoclonal antibody based therapy of a human tumor Xenograft with a 177Lu labelled immunoconjugate. Cancer Res 51:2889
Lahiri S, Nayak D, Das SK, Ramaswami A, Manohor SB, Das NR (1999) Separation of carrier free 152,153Dy and 151−153Tb from 16O7+ irradiated CeO2 by liquid-liquid extraction. J Radioanl Nucl Chem 24:201–206
Gavron A (1980) Phys Rev C 21:230
Nayak D, Lahiri S, Ramaswami A, Manohor SB (1999) Separation of no-carrier-added 147,149Gd and 147Eu produced in 70 MeV 11B irradiated praseodymium foil target. Radiochim Acta 87:93–96
Nayak D, Lahiri S, Ramaswami A, Manohor SB (1999) Separation of carrier-free 163,165Tm produced in 80 MeV 16O irradiated Eu2O3 target matrix. Radiochim Acta 87:75–78
Lahiri S, Mukhopadhyay K, Nayak D (1999) Separation of heavy ion induced carrier free europium isotopes from bulk quantity of caesium. J Radioanal Nucl Chem 242:127–129
Nayak D, Lahiri S, Ramaswami A, Manohor SB, Das NR (1999) Production and separation of carrier-free 146,147Eu from a 12C6+ irradiated La2O3 matrix. Appl Radiat Isot 51:261–268
Lahiri S, Nayak D, Das SK, Ramaswami A, Manohor SB, Das NR (1999) Separation of carrier free dysprosium and terbium isotopes from 12C6+ irradiated Nd2O3. Appl Radiat Isot 51:27–32
Nayak D, Lahiri S, Das SK, Ramaswami A, Manohor SB, Das NR (1999) Separation of carrier-free gadolinium produced in an 80 MeV 12C6+ irradiated CeO2 target. Appl Radiat Isot 51:1–7
Nayak D, Lahiri S (2000) Separation of carrier-free cerium radionuclides from different target matrix produced by heavy ion beams. Radiochim Acta 88:115–119
Nayak D, Lahiri S, Ramaswami A, Manohor SB, Das NR (1999) Separation of carrier free 151,152Tb produced in 16O6+ irradiated lanthanum oxide matrix. Appl Radiat Isot 51:631–636
Lahiri S, Nayak D, Ramaswami A, Manohor SB (2000) Production and separation of carrier-free lutetium, ytterbium and thulium radionuclides from 75 MeV 12C6+ irradiated terbium foil target. J Radioanal Nucl Chem 243:701–705
Lahiri S, Nayak D, Das NR (2000) Production and separation of carrier-free 145,146Eu from a CsNO3 target using a 16O Beam. Appl Radiat Isot 52:1393–1397
Lahiri S, Nayak D, Ramaswami A, Manohor SB (2000) Separation of carrier-free ytterbium and thulium produced in 80 MeV 12C6+ irradiated gadolinium foil target by liquid-liquid extraction with HDEHP. Appl Radiat Isot 52:797–802
Nayak D, Lahiri S, Ramaswami A, Manohor SB (2000) Separation of carrier-free holmium and dysprosium produced in 70 MeV 11B5+ irradiated europium target by liquid-Liquid extraction with HDEHP. Indian J Chem 39A:1061–1065
Lahiri S, Banerjee K, Nayak D, Ramaswami A, Das NR (2000) Separation of carrier free hafnium and lutetium radionuclides produced in 16O activated terbium metal target. Appl Radiat Isot 52:1399–1405
Lahiri S, Banerjee K, Das NR (1999) Production of carrier free 192,193Hg and 192,193Au in 16O irradiated tantalum target and their separation by liquid-liquid extraction. J Radioanal Nucl Chem 242:497–504
Banerjee K, Lahiri S, Ramaswami A, Manohor SB, Das NR (2000) Separation of 187,188Pt and 187,188Ir produced in 11B4+ irradiated tantalum target. Radiochim Acta 88:431–434
Banerjee K, Lahiri S (2001) Separation of carrier-free 176,177W and 176,177Ta produced in 16O irradiated holmium target. J Radioanal Nucl Chem 250:365–367
Lahiri S, Banerjee K, Nayak D, Ramaswami A, Das NR (2001) Production and separation of 183Os and 183Re from 7Li irradiated tantalum target. J Nucl Radiochemical Sci 2:50
Lahiri S, Mukhopadhyay K, Banerjee K, Ramaswami A, Manohar SB (2001) Separation of carrier-free 181Re produced in 16O-irradiated thulium target. Appl Radiat Isot 55:751–754
Mukhopadhyay K, Lahiri S (2002) Production and separation of 24Na and 28Mg from 7Li-irradiated aluminium target. Radiochim Acta 90:65–68
Mukhopadhyay K, Nayak D, Lahiri S (2002) Separation of no-carrier-added As and Se produced in 16O irradiated cobalt target. J Radioanal Nucl Chem 251:159–162
Banerjee S, Lahiri S, Manohar SB (2002) Ramaswami A Separation of 48V and 48,49Cr in 7Li irradiated Sc2O3 target by liquid-liquid extraction Appl. Radiat Isot 56:571–575
Mukhopadhyay B, Lahiri S, Mukhopadhyay K, Ramaswami A (2003) Separation of carrier free 111In, 116,117Te and 116,116m,117Sb from 11B induced silver target. J Radioanal Nucl Chem 256:307–310
Maji S, Lahiri S (2007) Production of no-carrier-added 123I produced by heavy ion activation of natural antimony oxide. Radiochim Acta 95:133–136
Nayak D, Lahiri S (2003) Sequential separation of 61Cu, 62,63Zn, 66,67,68Ga, 71,72As and 73Se produced by heavy ion activation on cobalt target. J Nucl Radiochem Sci 4:1–3
Nayak D, Lahiri S (2001) Alternative methods for the production of carrier free 66,67Ga. Appl Radiat Isot 54:189–193
Nayak D, Lahiri S, Ramaswami A (2002) Alternative radiochemical heavy ion activation methods for production and separation of thallium radionuclides. Appl Radiat Isot 57:483–489
Nayak D, Lahiri S, Ramaswami A (2002) Alternative production and separation method of 111In by heavy ion activation of silver. Indian J Chem 41A:2300–2302
Maji S, Basu S, Lahiri S (2005) Alternative separation methods of no-carrier-added 111In produced by heavy ion activation Appl. Radiat Isot 63:513–517
Maiti M, Lahiri S (2009) Theoretical approach to explore the production routes of astatine radionuclides. Phys Rev C 79(024611–1):024611–024619
Lahiri S, Maiti M (2012) Recent developments in nuclear data measurements and chemical separation methods in accelerator production of astatine and technetium radionuclides. Radiochim Acta 100:85–94
Koning AJ, Hilarie S, Duijvestijn MC (2005) AIP Conf Proc 769:1154
Blann M, Vonach HK (1983) Phys Rev C 28:1475
Maiti M, Lahiri S (2011) Production cross section of At radionuclides from 7Li + natPb and 9Be + natTl reactions. Phys. Rev. C 84:067601-1–067601-4
Maiti M, Lahiri S (2009) Production and separation of no-carrier-added 208,209,210At produced from heavy ion activation on natural thallium target. J Radioanal Nucl Chem 281:501–504
Lahiri S, Roy K, Sen S (2008) Complexation study on no-carrier-added astatine with insulin: a candidate radiopharmaceutical. Appl Radiat Isot 66:1901–1904
Elgqvist J, Andersson H, Bernhardt P, Bäck T, Claesson I, Hultborn R, Jensen H, Johansson R, Lindegren S, Olsson M, Palm S, Warnhammar E, Jacobsson L (2006) Administered activity and metastatic cure probability during radioimmunotherapy of ovarian cancer in nude mice with 211At-MX35 F(ab0). Int J Radiat Oncol Biol Phys 66:1228
Maiti M, Lahiri S (2010) New routes for production of proton-rich Tc isotopes. Phys Rev C 81(024603–1):024603–024607
Maiti M, Lahiri S (2009) Production and separation of no-carrier-added 93,94,95Tc from 9Be activated Yttrium target. Radiochim Acta 97:663–667
Maiti M (2011) New measurement of cross sections of evaporation residues from the natPr + 12C reaction: a comparative study on the production of 149Tb Phys. ReV C 84:044615
Alexander JM, Simonoff GN (1963) Phys Rev 130:2383
Kossakowski R, Jastrzebski J, Rymuza P, Skulski W, Gizon A, Andre S, Genevey J, Gizon J, Barci V (1985) Phys Rev C 32:1612
Maiti M, Lahiri S, Tomar BS (2011) Investigation on the production and isolation of 149,150,151Tb from 12C activated natural praseodymium target. Radiochim Acta 99:527–533
http://ph-news.web.cern.ch/content/cern-medicis-project (last seen 17.05.2015)
http://isolmyrrha.sckcen.be/en/Applications/Medical_applications (last seen 17.05.2015)
Lagunas-Solar MC, Avila MJ, Nvarro NJ, Johnson PC (1983) Cyclotron production of no-carrier-added 97Ru by proton bombardment of 103Rh targets. Int J Appl Radiat Isot 34:915
Maiti M, Lahiri S (2011) Production and separation of 97Ru from 7Li activated natural niobium. Radiochim Acta 99:359–364
Maiti M, Lahiri S (2015) Measurement of yield of residues produced in 12C + natY reaction and subsequent separation of 97Ru from Y target using cation exchange resin. Radiochim Acta 103:7–13
Ambe S, Chen SY, Ohkubo Y, Kobayashi Y, Iwamoto M, Yanokura M, Ambe F (1991) Preparation of a radioactive multitracer solution from gold foil irradiated by 135 MeV/nucleon 14N ions. Chem, Lett 149
Ambe S, Ohkubo Y, Kobayashi Y, Iwamoto M, Maeda H, Yanokura M (1995) Multitracer study of transport and distribution of metal ions in plants. J Radioanal Nucl Chem 195:305
Hirunima R, Endo K, Enomoto S, Ambe S, Ambe F (1999) Study on the distribution of radioactive trace elements in vitamin D-overloaded rats using the multitracer technique. Appl Radiat Isot 50:843
Chen SY, Ambe S, Ambe F (1994) Preparation of a radioactive multitracer solution from iron foil irradiated by 80 MeV/nucleon 16O ions. J Radioanal Nucl Chem Lett 186:113
Lahiri S, Zhi Q, Wen YH, Wu XL (2002) Production of multitracers through 80 MeV/A 12C irradiation on thick gold foil at HIRFL, Institute of Modern Physics, Lanzhou, China. J Radioanal Nucl Chem 252:589–590
Lahiri S, Nayak D (2002) Tracer Packet: a new conception for the production of tracers of micronutrient elements. J Radioanal Nucl Chem 254:289–292
Nayak D, Lahiri S (2002) Production of tracer packet of heavy and toxic elements. J Radioanal Nucl Chem 254:619–623
Lahiri S, Nayak D, Maji S (2004) Production of tracer packet of heavier rare earth elements. J Radioanal Nucl Chem 260:369–372
Nayak D, Datta Samanta T, Laskar S, Lahiri S (2007) Application of tracer packet technique for studying metal-protein interactions with Erythrina variegata Linn. seed proteins. J Radioanal Nucl Chem 271:387–390
Datta Samanta T, Laskar S, Nayak D, Lahiri S (2007) Studies on metal-protein interactions: inter-comparison between different approaches. J Radioanal Nucl Chem 273:323–325
Nayak D, Lahiri S, Mukhopadhyay A, Pal R (2003) Application of tracer packet technique on the studies on bio-sorption of heavy and toxic metal radionuclides by algae. J Radioanal Nucl Chem 256:535–539
Roy K, Basu S, Ramaswami A, Lahiri S (2003) Application of tracer packet technique for multielemental uptake studies on the inorganic ion exchanger, zirconium vanadate. Appl Radiat Isot 59:105–108
Roy K, Basu S, Ramaswami A, Nayak D, Lahiri S (2004) Studies on multielemental uptake by thiosemicarbazide incorporated Amberlite IRC-50 using tracer packet technique. Indian J Chem 43A:1152–1155
Maji S, Basu S, Ramaswami A, Lahiri S (2007) Application of tracer packet technique for multielemental uptake studies by ceric vanadate. J Radioanal Nucl Chem 271:391–396
Maji S, Basu S, Lahiri S (2007) Studies on multielemental uptake of amide incorporated Amberlite IRC-5- using tracer packet technique. Indian J Chem 46A:97–100
Final report of EURISOL design study, JC Cornell (ed.), GA- NIL, France (2009)
Maiti M, Ghosh K, Mendonça TM, Stora T, Lahiri S (2014) Comparison on the production of radionuclides in 1.4 GeV proton irradiated LBE targets of different thickness. J Radioanal Nucl Chem 302:1003–1011. doi:10.1007/s10967-014-3636-6
Tall Y, Cormon S, Fallot M, Foucher Y, Guertin A, Kirchner T, Zanini L, Andersson M, Berg K, Franberg H, Groeschel F, Manfrin E, Wagner W, Wohlmuther M, Everaerts P, Koester U, Ravn H, Noah Messomo E, Jost C, Kojima Y (2007) International conference on nuclear data for science and technology. doi: 10.1051/ndata:07762
Nayak D, Lahiri S, Mukhopadhyay A, Pal R (2002) An eco friendly novel separation of carrier free thallium radionuclide from mercury and lead radionuclides using algae as bio-reagent. Green Chem 4:581–583
Lahiri S, Sarkar S (2008) Separation of no-carrier-added Tl and Pb radionuclides using poly (N-vinylpyrrolidone). J Radioanal Nucl Chem 277:513–516
Lahiri S, Maji SK, Nayak D (2000) Separation of no-carrier-added thallium radionuclides from no-carrier-added lead and mercury radionuclides by dialysis. PCT number: PCT/IN2006/000039, Publication number: US20100038315 A1
Ghosh K, Lahiri S (2007) Bioaccumulation of 198Au by an alkaloid extracted from fruits of piper nigrum (Family: Piperaceae). J Radioanal Nucl Chem 274:233–236
Nayak D, Ghosh K, Lahiri S (2009) Studies on bioaccumulation of 51Cr by Piper nigrum. J Radioanal Nucl Chem 280:503–506
Roy K, Sinha P, Lahiri S (2008) Immobilization of long-lived radionuclide 152,154Eu by selective bioaccumulation in Saccharomyces cerevisiae from a synthetic mixture of 152,154Eu, 137Cs and 60Co. Biochem Eng J 40:363–367
Lahiri S, Roy K (2008) Investigation on pH dependent uptake of Cr(III) and Cr(VI) by Baker’s yeast. Indian J Chem Tech 15:417–420
Sen K, Sinha P, Lahiri S (2011) Time dependent formation of gold nanoparticles in yeast cells: a comparative study. Biochemical Eng J 55:1–6
Roy K, Lahiri S (2006) A green method for synthesis of radioactive gold nanoparticles. Green Chem 8:1063–1066
Roy K, Lahiri S (2008) In situ gamma radiation: one step environmentally benign method to produce gold-palladium bimetallic nanoparticles. Anal Chem 80:7504–7507
Roy K, Lahiri S (2008) Production and separation of astatine radionuclides: some new addition to astatine chemistry. Appl Radiat Isot 66:571–576
Datta A, Maiti M, Lahiri S (2014) Separation of 97Ru from niobium target using PEG based aqueous biphasic system. J Radional Nucl Chem 302:931–937
Roy K, Paul R, Banerjee B, Lahiri S (2009) Extraction of long-lived radionuclides 152,154Eu and 134Cs using environmentally benign aqueous biphasic system. Radiochim Acta 97:637–641
Roy K, Lahiri S (2009) Extraction of Hg(I), Hg(II) and methylmercury using polyethylene glycol based aqueous biphasic system. Appl Radiat Isot 67:1781–1784
Roy K, Lahiri S (2008) Species dependent radiotracer study of Cr(VI) and Cr(III) using an aqueous biphasic system. Radiochim Acta 96:49–54
Banerjee A, Nayak D, Lahiri S (2007) A new method of synthesis of iron doped calcium alginate beads and determination of iron content by radiometric method. Biochem Eng J 33:260–262
Nayak D, Banerjee A, Lahiri S (2007) Separation of no-carrier-added 66,67Ga produced in heavy ion induced cobalt target using alginate biopolymers. Appl Radiat Isot 65:891–896
Banerjee A, Nayak D, Lahiri S (2007) Speciation-dependent studies on removal of arsenic by iron-doped calcium alginate beads. Appl Radiat Isot 65:769–775
Ghosh K, Maiti M, Lahiri S (2013) Separation of no-carrier-added 109Cd from natural silver target using RTIL 1-butyl-3-methylimidazolium hexafluorophosphate. J Radioanal Nucl Chem 298:1049–1054
Ghosh K, Maiti M, Lahiri S, Afzal Hussain V (2014) Ionic liquid-salt based aqueous biphasic system for separation of 109Cd from silver target. J Radional Nucl Chem 302:925–930
Lahiri S, Maiti M, Ghosh K Separation of no-carrier-added 111In and 109Cd from a-particle induced Ag target using glass wool surface. J Radioanal Nucl Chem (in press)
Maiti M, Lahiri S, Tomar BS (2011) Separation of no-carrier-added 107,109Cd from proton induced silver target: classical chemistry still relevant. J Radioanal Nucl Chem 288:115–119
Acknowledgments
Since this write up is an extended version of Hevesy Medal Award lecture-2015, I would like to express my sincere gratitude to all who helped me in my long journey by extending their co-operation, and sincere affection. The list is too long. However, I must express my gratitude to some people without them I could not be here. At the outset I would like to express my sincere thanks to my Ph. D supervisor Professor N. R. Das, who is an excellent and outstanding radiochemist. Professor Das took me to the wonder world of radioactivity and radiochemistry. A very special thanks to Dr. Moumita Maiti, who is responsible for studying physical parameters in heavy ion activation and bringing the subject at par excellence. I am thankful to my graduate students and post doctoral fellows who worked hard and extended their sincere efforts, chronologically, Dr. Shobhandeb Banerjee, Dr. Banani Mukhopadhyay, Dr. (late) Dalia Nayak, Dr. Kakoli Banerjee, Dr. Krishnendu Mukhopadhyay, Dr. Kamalika Roy (Sen), Dr. Samir Maji, Dr. Kalpita Ghosh, Dr. Anupam Banerjee, Dr. Arpita Datta, Dr. Binita Dutta and Mr. Kaustab Ghosh. I look forward to my present graduate students, Ms. Kangkana Sarkar and Ms. Nabanita Naskar with a hope that they will follow the excellence of their predecessors. I would also like to express my sincere gratitude to my nominators Professor M. L. Thakur, USA; Professor Jan Kuchera, Czech republic and Professor Elisabete De Nadai Ferndance, Brazil. Thanks to Hevesy Medal Award Selection Panel and Journal of Radioanalytical and Nuclear Chemistry for keeping faith on me. I am thankful to my own institute Saha Institute of Nuclear Physics (SINP) and the authority for extending all necessary infrastructures. I am grateful to the Department of Atomic Energy, Govt. of India, for supporting me intensively specially for granting consecutively two ‘5 year plan projects’, “Trace Analysis: Detection, Dynamics and Speciation (TADDS)” (2007–2012) and “Trace ULtratrace analysis and Isotope Production (TULIP) (2012–2017).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lahiri, S. Across the energy scale: from eV to GeV. J Radioanal Nucl Chem 307, 1571–1586 (2016). https://doi.org/10.1007/s10967-015-4298-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-015-4298-8