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Rapid quantification of alpha emitters in low- and intermediate-level dry radioactive waste

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An Erratum to this article was published on 05 January 2016

Abstract

We developed a rapid quantification method of Pu, Am, and Cm in low- and intermediate-level radioactive waste using TRU resin, alpha spectrometry, and thermal ionization mass spectrometry for radioactive waste disposal. In particular, we focused on the optimization of sample preparation methods for alpha spectrometry and mass spectrometry to reduce the analysis time. The optimized method used Am and Pu stripping solutions for micro-coprecipitation and showed good recovery and alpha spectrum resolution for alpha counting. In addition, appropriate selection of Pu elution solution decreased the sample preparation time for thermal ionization mass spectrometry measurements.

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References

  1. Choi K-S, Lee CH, Im H-J, Ahn H-J, Song K (2014) Sample pretreatment for the determination of gamma emitting nuclides in dry radioactive waste using a dry ashing and high-performance microwave digestion system. J Radioanal Nucl Chem 301:567–571

    Article  CAS  Google Scholar 

  2. Lee MH, Jung EC, Kim WH, Jee KY (2007) Sequential separation of the actinides in environmental and radioactive waste samples. J Alloys Compd 444–445:544–549

    Article  CAS  Google Scholar 

  3. Lee MH, Jeon YS, Song K (2009) Determination of activity concentrations and activity ratios of plutonium, americium and curium isotopes in radioactive waste samples. J Radioanal Nucl Chem 280:457–465

    Article  CAS  Google Scholar 

  4. Lee CH, Choi KS, Song BC, Ha Y-K, Song K (2013) Rapid separation of nickel for 59Ni and 63Ni activity measurement in radioactive waste samples. J Radioanal Nucl Chem 298:1221–1226

    Article  CAS  Google Scholar 

  5. Lee CH, Lee MH, Han SH, Ha Y-K, Kyuseok S (2011) Systematic radiochemical separation for the determination of 99Tc, 90Sr, 94Nb, 55Fe and 59,63Ni in low and intermediate radioactive waste samples. J Radioanal Nucl Chem 288:319–325

    Article  CAS  Google Scholar 

  6. Shakhashiro A, Tarjan S, Ceccatelli A, Kis-Benedek G, Betti M (2012) IAEA-447: a new certified reference material for environmental radioactivity measurements. Appl Radiat Isot 70:1632–1643

    Article  CAS  Google Scholar 

  7. Kim C-S, Kim C-K, Martin P, Sansone U (2007) Determination of Pu isotope concentrations and isotope ratio by inductively coupled plasma mass spectrometry: a review of analytical methodology. J Anal Atom Spectrosc 22:827–841

    Article  CAS  Google Scholar 

  8. Vajda N, Kim C-K (2011) Determination of transuranium isotopes (Pu, Np, Am) by radiometric techniques: a review of analytical methodology. Anal Chem 83:4688–4719

    Article  CAS  Google Scholar 

  9. Horwitz EP, Dietz ML, Chiarizia R, Diamond H, Maxwell III SL, Nelson MR (1995) Separation and preconcentration of actinides by extraction chromatography using a supported liquid anion exchanger: application to the characterization of high-level nuclear waste solutions. Anal Chim Acta 310:63–78

    Article  CAS  Google Scholar 

  10. Warwick PE, Croudace IW, Oh J-S (2001) Radiochemical determination of 241Am and Pu(α) in environmental materials. Anal Chem 73:3410–3416

    Article  CAS  Google Scholar 

  11. Lee MH, Park T-H, Song BC, Park JH, Song K (2012) A study of simple α source preparation using a micro-coprecipitation method. Bull Korean Chem Soc 33:3745–3748

  12. Lee MH, Park TH, Park JH, Song K, Lee MS (2013) Radiochemical separation of Pu, U, Am and Sr isotopes in environmental samples using extraction chromatographic resins. J Radioanal Nucl Chem 295:1419–1422

    Article  CAS  Google Scholar 

  13. Dulanská S, Remenec B, Mátel L’, Galanda D (2011) The selective separation of Pu isotopes using molecular recognition technology product AnaLig® Pu02 gel and extraction chromatography TRU® resin. J Radioanal Nucl Chem 287:841–845

    Article  CAS  Google Scholar 

  14. Dulanská S, Remenec B, Mátel L, Durkot E (2012) Rapid determination of 239,240Pu, 238Pu, 241Am and 90Sr in radioactive waste using combined SPE sorbents AnaLig® Pu02, AnaLig® Sr01 and TRU® resin. J Radioanal Nucl Chem 293:81–85

    Article  CAS  Google Scholar 

  15. Vajda N, Törvényi A, Kis-Benedek G, Kim CK, Bene B, Mácsik Z (2009) Rapid method for the determination of actinides in soil and sediment samples by alpha spectrometry. Radiochim Acta 97:395–401

    CAS  Google Scholar 

  16. Macsik Z, Groska J, Vajda N, Vogt S, Kis-Benedek G, Kim CS, Maddison A, Donohue D (2013) Improved radioanalytical method for the simultaneous determination of Th, U, Np, Pu and Am(Cm) on a single TRU column by alpha spectrometry and ICP-MS. Radiochim Acta 101:241–251

    Article  CAS  Google Scholar 

  17. Maxwell SL, Culligan BK, Hutchison JB (2014) Rapid determination of actinides in asphalt samples. J Radioanal Nucl Chem 299:1891–1901

    Article  CAS  Google Scholar 

  18. Horwitz EP, Chiarizia R, Dietz ML, Diamond H, Nelson DM (1993) Separation and preconcentration of actinides from acidic media by extraction chromatography. Anal Chim Acta 281:361–372

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Nuclear Research and Development Program through National Research Foundation of Korea (No. 2012M2A8A5025923) funded by the Ministry of Science, ICT and Future Planning.

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Correspondence to Tae-Hong Park.

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Park, TH., Jeon, EH., Choi, Y.S. et al. Rapid quantification of alpha emitters in low- and intermediate-level dry radioactive waste. J Radioanal Nucl Chem 307, 645–651 (2016). https://doi.org/10.1007/s10967-015-4177-3

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  • DOI: https://doi.org/10.1007/s10967-015-4177-3

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