Abstract
A method based on ion-chromatography has been developed for determination of Cs and Sr in high level waste (HLW) without matrix separation. The acidity of HLW (3 M HNO3) was decreased to 0.01 M by addition of NaOH. Chromatographic separation of Cs+ and Sr++ in presence of bulk Na+ has achieved using methane sulphonic acid as mobile phase in isocratic and gradient mode. The calibration plot was linear for the concentration range of 0.5–12 mg/L for Cs and 0.025–6 mg/L for Sr with regression coefficients close to 1. RSD obtained for Cs and Sr was 1 and 5 % respectively. Detection limit calculated as 3(S/N) was found to be 20 μg/L for Cs and 30 μg/L for Sr. The standard addition procedure was used to validate the developed method. The samples received from PREFRE, Tarapur and WIP, BARC were analyzed by the new method and the results are presented.
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References
Spent fuel reprocessing options, IAEA-TECDOC-1587, ISBN 978–92–0–103808–1, ISSN 1011–4289, IAEA, Vienna, 2008
Alison Sinclair, X-ray versus gamma irradiation of blood components for prevention of transfusion-associated graft versus host disease, Report No: 51, 12 Apr 2011, http://www.mcgill.ca/tau
Wierzbicki JG, Meyer Richard (1993) Med Phys 20:245
Stolz B, Weckbecker G, Smith-Jones PM, Albert R, Raulf F, Bruns C (1998) Eur J of Nucl Med 25:668
Brown GN, Carson KJ, DesChane JR, Elovich RJ (1997) Performance evaluation of 24 ion exchange materials for removing Cesium and Strontium from actual and simulated N-reactor storage basin water”, Report-PNNL-11711, UC-2030, U.S. Department of Energy
Todd TA, Batcheller TA, Law JD, Herbst RS, (2004) Cesium and Strontium separation technologies literature Review, Report-INEEL/EXT-04-01895, U.S. Department of Energy, Office of Nuclear Energy
Purohit PJ, Goyal Neelam, Page AG (1992) Chem Environ Res 1:405
Verma Poonam, Rastogi RK, Ramakumar KL (2006) BARC Report No. E/024
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Thakur, U.K., Verma, P., Shah, D.J. et al. Simultaneous determination of Cs and Sr in the high level waste by ion-chromatography. J Radioanal Nucl Chem 300, 121–124 (2014). https://doi.org/10.1007/s10967-014-2954-z
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DOI: https://doi.org/10.1007/s10967-014-2954-z