Skip to main content
Log in

Empirical method for preparing a plutonium predominance-region diagram

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

An empirical method for preparing a plutonium predominance-region diagram is illustrated by an example. The method estimates the boundaries of the forbidden, unique, and ambiguous regions as defined by the equilibrium fraction of hexavalent plutonium and the plutonium oxidation number.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. Sinkov SI (2007) Plutonium speciation in support of oxidative-leaching demonstration test. PNNL-16844, WTP-RPT-165, Rev 0, Pacific Northwest National Laboratory, USA. see the upper-left-hand quadrant of Fig. 1.3 on p 1.6

  2. Silver GL (2009) Appl Radiat Isot 67:103–105

    Article  CAS  Google Scholar 

  3. Silver GL (2010) J Radioanal Nucl Chem 283:533–535

    Article  CAS  Google Scholar 

  4. Silver GL (2010) J Radioanal Nucl Chem 284:175–177

    Article  CAS  Google Scholar 

  5. Silver GL (2011) J Radioanal Nucl Chem 288:257–260

    Article  CAS  Google Scholar 

  6. King EJ (1959) Qualitative analysis and electrolytic solutions. Harcourt, Brace & Co, New York, p 198

    Google Scholar 

  7. Silver GL (2008) J Radioanal Nucl Chem 278:215–217

    Article  CAS  Google Scholar 

  8. Silver GL (1971) J Inorg Nucl Chem 33:577–583, 33:4000

    Google Scholar 

  9. Canagaratna SG (1992) J Chem Educ 69:957–960, see p 960

    Article  CAS  Google Scholar 

  10. Lemire RJ et al (2001) Chemical thermodynamics 4. Chemical thermodynamics of neptunium and plutonium. Organization for economic cooperation and development. Elsevier, Amsterdam, see Eq. 16.5 on p 303

  11. Silver GL (1973) Radiochem Radioanal Lett 13:101–108

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. L. Silver.

Additional information

Los Alamos National Laboratory is operated by the Los Alamos National Security, LLC for the National Nuclear Security Administration of the US Department of Energy contract DE-AC52-06NA25396.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Silver, G.L. Empirical method for preparing a plutonium predominance-region diagram. J Radioanal Nucl Chem 292, 1105–1108 (2012). https://doi.org/10.1007/s10967-011-1570-4

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-011-1570-4

Keywords

Navigation