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Separation of Cr(III) from Cr(VI) by Triton X-100 cerium(IV) phosphate as a surface active ion exchanger

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Abstract

Triton X-100 cerium(IV) phosphate (TX-100CeP) was synthesized and characterized by using IR, X-ray, TGA/DT and the elemental analysis. The chemical stability of TX-100CeP versus the different concentrations of HCl acid was studied before and after its exposure to the radiation dose (30 K Gray). The effect of HCl concentration on separation of Cr(III) from Cr(VI) by using TX-100CeP as surface active ion exchanger was also studied. A novel method was achieved for the quantifying of Cr(III) and Cr(VI) ions by using the high-performance liquid chromatography (HPLC) at wavelength 650 nm, a stationary phase consists of reversed phase column (Nucleosil phenyl column; 250 × 4.6 mm, 5 μm), and a mobile phase consists of 0.001 M di-(2-ethylhexyl) phosphoric acid (DEHPA) in methanol:water (70:30 v/v). The retention times were 7.0 and 8.5 min, for the Cr(III) and Cr(VI), respectively. The exchange capacity of Cr(III) was quantified (2.1 meq/g) onto the TX-100CeP.

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Acknowledgment

The authors wish to thank the editor of the RANC for his cooperation and valuable comments.

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Authors and Affiliations

  1. Radioactive Isotopes and Generators Department, Hot Labs. Centre, Atomic Energy Authority, P.O. Box 13759, Cairo, Egypt

    K. M. El-Azony, M. Ismail Aydia & A. A. El-Mohty

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  1. K. M. El-Azony
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  2. M. Ismail Aydia
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  3. A. A. El-Mohty
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Correspondence to K. M. El-Azony.

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El-Azony, K.M., Ismail Aydia, M. & El-Mohty, A.A. Separation of Cr(III) from Cr(VI) by Triton X-100 cerium(IV) phosphate as a surface active ion exchanger. J Radioanal Nucl Chem 289, 381–388 (2011). https://doi.org/10.1007/s10967-011-1079-x

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