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Determination and differentiation of 226Ra and 222Rn by gamma-ray spectrometry in drinking water

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Abstract

The analysis of 226Ra in natural waters can be tedious and time-consuming. For the determination and differentiation of activities of 226Ra and 222Rn in drinking water by γ-ray spectrometry a simple and fast method is presented. Activities of 226Ra > 0.5 Bq L−1 can be determined according to stabilization of the sample without further procedures. For a more sensitive detection sample volumes of up to 5 litres are applicable by a rapid precipitation procedure without large expenditure. Further laborious enrichment methods are not necessary. Thus, detection limits of 0.1 Bq L−1 can be obtained when using sample volumes of 5 litres. Therefore the method is suitable for the monitoring of radioactivity in drinking water samples in accordance with the legal guidance of the European Union.

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References

  1. Council Directive 98/83/EC of 3. November 1998 on the quality of water intended for human consumption; OJ L 330, 5.12.1998, 32–54.

    Google Scholar 

  2. U.S Environmental Protection Agency. Prescribed Procedures for Measurement of Radioactivity in Drinking Water, EPA 600/4-80-032, 1980, Washington, DC.

  3. U.S. Department of Energy, Environmental Measurements Laboratory, The Procedures Manual of the Environmental Measurements Laboratory, Hasl-300,Volume I, 28th Edition, 1997.

  4. Z. Varga, Anal. Bioanal. Chem., 390 (2008) 511.

    Article  CAS  Google Scholar 

  5. J. M. Godoy, D. C. Lauria, M. Luiza, D. P. Godoy, R. P. Cunha, J. Radioanal. Nucl. Chem., 182 (1994) 165.

    Article  CAS  Google Scholar 

  6. S. L. Maxwell III, J. Radioanal. Nucl. Chem., 270 (2006) 651.

    Article  CAS  Google Scholar 

  7. B. Kahn, R. Rosson, J. Cantrell, Health Phys., 59 (1990) 125.

    Article  CAS  Google Scholar 

  8. M. AKRAM, R. M. QURESHI, N. AHMAD, T. J. SOLAIJA, A. MASHIATULLAH, M. A. AYUB, SAIMA IRSHAD, The Nucleus, 41 (2004) 19.

    Google Scholar 

  9. R. Rosson, Method for the Determination of Radium-228 and Radium-226 in Drinking Water by Gamma-ray Spectrometry Using HPGE or Ge(Li) Detectors, Environmental Resource Center Georgia Institute for Technology Atlanta, GA, 2003.

  10. P. K. Padmanabhan, L. U. Josh, Ch. Venkateswarlu, A. K. Ganguly, J. Radioanal. Chem., 44 (1978) 49.

    Article  CAS  Google Scholar 

  11. S. Purkl, A. Eisenhauer, Appl. Radiat. Isotopes, 59 (2003) 245.

    Article  CAS  Google Scholar 

  12. Eichrom Technologies, Inc., Radium in Water, RAW03, Analytical Procedures, Rev. 1.3, 2005.

  13. J. Michel, W. S. Moore, P. T. King, Anal. Chem., 53 (1981) 1885.

    Article  CAS  Google Scholar 

  14. S. Rihs, M. Condomines, Chem. Geol., 182 (2002) 409.

    Article  CAS  Google Scholar 

  15. Eichrom Technologies Inc., Radium-226/228 in Water (MnO2 Resin & DGA Resin Method), RAW04, Analytical Procedures, Rev. 1.0, 2006.

  16. E. BODROGI, T. KOVÁCS, V. JOBBÁGY, J. SOMLAI, Radioprotection, Suppl. 1, 40 (2005) 833.

    Article  Google Scholar 

  17. Council Directive 96/29/EURATOM of 13. May 1996, Laying down basic safety standards for the protection of the health of workers and the general public against the dangers arising from ionizing radiation; OJ L 159, 29.06.1996, 1–114.

  18. F. De Oliveira Lucas, F. B. Ribeiro, Appl. Radiat. Isotopes, 64 (2006) 735.

    Article  CAS  Google Scholar 

  19. H. W. Kirby, M. L. Salutsky, The radiochemistry of radium. Springfield, VA, National Technical Information Service, U.S. Atomic Energy Commission NAS-NS-3057, 1964.

  20. J. Michel, P. T. King, W. S. Moore, Anal. Chem., 53 (1981) 1885.

    Article  CAS  Google Scholar 

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Küsters, M., Schraven, W. Determination and differentiation of 226Ra and 222Rn by gamma-ray spectrometry in drinking water. J Radioanal Nucl Chem 280, 475–480 (2009). https://doi.org/10.1007/s10967-009-7460-3

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