Skip to main content
Log in

Self-radiolytical processes in ethyl-phenyl siloxanes labeled with tritium

  • Radiation Chemistry
  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Radioluminescent sources, containing as excitant agent ethyl-siloxan polymers labeled with tritium, represent the most studied constructive variants. The required high specific activities induce significant self-radiolytical processes in labeled polymers, their study being necessary for technological, radiobiological, and radioecological reasons. In the present study, the protective effect of phenyl fragments in tritium labeled ethylsiloxane structures has been analyzed. In this sense, the ethyl and phenyl siloxane structures with phenyl group positioned at the same Si atom or at different Si atoms have been synthesized and analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Radioluminescent lighting technology, Technology transfer conference proceedings, September 25–26, 1990, Annapolis, Maryland, USA

  2. C. Postolache, Lidia Matei, Gh. Dogaru, Punctiform tritium radioluminescent sources, The 10th ICSI Conference Progress in Cryogenics and Isotopes Separation Proceedings, ISSN 1582-2575, (2004) 163–167.

  3. C Postolache, Lidia Matei, Radiation Physics and Chemistry, 76 (2007) 1267.

    Article  CAS  Google Scholar 

  4. C Postolache, Lidia Matei, Evaluation of homolytic dissociation energies in organic compounds by quantum mechanical methods, 11th Tihany Symposium on Radiation Chemistry, 26–31 aug. 2006, Eger, Hungary, Abstracts book, 64.

  5. J. K. Kochi, Free radicals, Vol. II, John Wiley & Sons, NY Interscience Pub., 1973.

  6. N. M. Atherton, Electron spin resonance; theory and applications, Ellis Horwood Ltd., John Wiley & Sons, 1973.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Postolache.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Postolache, C., Matei, L. & Georgescu, R. Self-radiolytical processes in ethyl-phenyl siloxanes labeled with tritium. J Radioanal Nucl Chem 280, 251–258 (2009). https://doi.org/10.1007/s10967-009-0507-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-009-0507-7

Keywords

Navigation