Skip to main content
Log in

Extraction chromatographic material with HDEHP on polyacrylonitrile (PAN)

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Four composite materials with di-(2-ethylhexyl) phosphoric acid (HDEHP) as an extraction agent and PAN as a binding polymer were studied in this work. The intended use of these materials is in extraction chromatography. They were prepared by various methods and contained different amounts of HDEHP. The properties were compared by studying europium uptake from nitric acid solutions. Materials prepared by direct incorporation of extraction agent into PAN polymer during beads production and with up to 40% (w/w) of HDEHP are suitable for analytical separations. Materials with high capacity can be prepared by impregnation of ready-made PAN beads.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Šebesta F (1999) In: Misaelides P, et al. (eds) Natural microporous materials in environmental technology. Kluwer Academic Publishers, Dordrecht, pp 473–486

    Google Scholar 

  2. John J, Šebesta F, Motl A (1999) In: Choppin GR, Khankhasayev MKh (eds) Chemical separation technologies and related methods of nuclear waste management. Kluwer Academic Publishers, Dordrecht, pp 155–168

    Google Scholar 

  3. Vilar VJP, Šebesta F, Botelho CMS, Boaventura RAR (2005) Equilibrium and kinetic modelling of Pb2+ biosorption by granulated agar extraction algal waste. Process Biochem 40:3276–3284

    Article  CAS  Google Scholar 

  4. Fišera O, Šebesta F (2006) Sorption properties of new composite materials suitable for radioanalytical determination of 59Ni and 63Ni. Czech J Phys 56:D557–D564

    Google Scholar 

  5. Lučaníková M, Kučera J, Šebesta F, John J (2006) Use of new composite materials for the determination of Cu, Cd, Mo, As, and Sb in biological samples by radiochemical neutron activation analysis. J Radioanal Nucl Chem 269:463–468

    Article  Google Scholar 

  6. Lučaníková M, Kučera J, Šebesta F (2008) New extraction chromatographic material for rhenium separation. J Radioanal Nucl Chem 277:479–485

    Article  Google Scholar 

  7. John J, Šebesta F, Šul’aková J, Kameník J, Fišera O (2008) In: NRC7—seventh international conference on nuclear and radiochemistry, Budapest, Hungary, 24–29 Aug 2008. CD Proceedings

  8. Šebesta F (1997) Composite absorbers consisting of inorganic ion-exchangers and polyacrylonitrile binding matrix. I. Methods of modification of properties of inorganic ion-exchangers for application in column packed beds. J Radioanal Nucl Chem 220:77–88

    Article  Google Scholar 

  9. Braun T, Ghersini G (ed) (1975) Extraction chromatography. Akadémiai Kiadó, Budapest

    Google Scholar 

  10. Cortina JL, Warshawsky A (1997) Ion exchange and solvent extraction, vol 13. Marcel Dekker, Inc., New York

    Google Scholar 

  11. Kameník J (2008) A study on actinides separation by CMPO-based composite materials. Thesis, Czech Technical University, Prague (in Czech)

  12. Kameník J, Šebesta F (2006) Study of europium and selected actinides uptake on composite material CMPO-PAN. Czech J Phys 56:D493–D500

    Google Scholar 

  13. Ghersini G (1975) In: Braun T, Ghersini G (eds) Extraction chromatography. Akadémiai Kiadó, Budapest, pp 68–133

    Google Scholar 

  14. Marcus Y, Kertes AS (1969) Ion exchange and solvent extraction of metal complexes. Wiley Interscience, New York

    Google Scholar 

  15. Triskem international (September 2008) TrisKem Infos 1. http://www.triskem-international.com/en/TrisKem%20Infos.asp. Accessed 30 Nov 2009

Download references

Acknowledgements

This research has been supported by the Ministry of Education, Youth and Sports of the Czech Republic under contract No. MSM6840770040.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. Kameník.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Šebesta, F., Kameník, J. Extraction chromatographic material with HDEHP on polyacrylonitrile (PAN). J Radioanal Nucl Chem 283, 845–849 (2010). https://doi.org/10.1007/s10967-009-0441-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-009-0441-8

Keywords

Navigation