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Recognition of perrhenate and pertechnetate by a neutral macrocyclic receptor

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Abstract

The synthesis and anion binding properties of a neutral macrocyclic receptor bearing H-bond donor coordination sites are described. The anion binding studies by use of UV-vis and 99Tc NMR methods revealed that the receptor can coordinate perrhenate and pertechnetate in dimethylsulfoxide and chloroform solutions with the relatively high binding constants, viz. log K a > 4. The coordination mode of the perrhenate to the receptor was determined by a single-crystal X-ray diffraction analysis.

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Acknowledgments

We thank the Russian Academy of Sciences program “Chemistry and Physico-Chemistry of Supramolecular Systems and Atomic Clusters” and Russian President Grant MК-2903.2008.3 for financial support. Prof. Yu. A. Ustynyuk and Prof. I.·S. Antipin are gratefully acknowledged for helpful discussions.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences, Vavilov st., 28, 119991, Moscow, Russian Federation

    E. A. Katayev, G. V. Kolesnikov, V. N. Khrustalev & M. Yu. Antipin

  2. Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie gory 1/3, 119992, Moscow, Russian Federation

    E. A. Katayev

  3. Baku State University, Z. Khalilov st. 23, 1148, Baku, Azerbaijan

    R. K. Askerov & A. M. Maharramov

  4. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences, Leninskiy pr. 31, 119991, Moscow, Russian Federation

    K. E. German, G. A. Kirakosyan & I. G. Tananaev

  5. Department of Natural Sciences, New Mexico Highlands University, Las Vegas, NM, 87701, USA

    V. N. Khrustalev, M. Yu. Antipin & T. V. Timofeeva

Authors
  1. E. A. Katayev
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  2. G. V. Kolesnikov
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  3. V. N. Khrustalev
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  4. M. Yu. Antipin
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  5. R. K. Askerov
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  6. A. M. Maharramov
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  7. K. E. German
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  8. G. A. Kirakosyan
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  9. I. G. Tananaev
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  10. T. V. Timofeeva
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Corresponding authors

Correspondence to E. A. Katayev or V. N. Khrustalev.

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Katayev, E.A., Kolesnikov, G.V., Khrustalev, V.N. et al. Recognition of perrhenate and pertechnetate by a neutral macrocyclic receptor. J Radioanal Nucl Chem 282, 385–389 (2009). https://doi.org/10.1007/s10967-009-0172-x

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  • DOI: https://doi.org/10.1007/s10967-009-0172-x

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