Abstract
Instrumental neutron activation analysis as carried out at the National Institute of Standards and Technology (NIST) is inadequate for determining Al, Ni, and V at the levels found in the newly prepared Standard Reference Material® (SRM) 1577c Bovine Liver. To overcome shortcomings in the value assignment, the authors initiated a cooperative approach using NAA with previously established chemical separation procedures and with significantly different neutron energy spectra to determine Al and V with pre-irradiation separation of the elements at NIST, and V and Ni with post-irradiation separation at the Nuclear Physics Institute Řež. The determinations were confirmed with the analyses of several SRMs. The work supported the certification of mass fraction values for V and Ni in SRM 1577c.
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Certain commercial equipment, instruments, or materials are identified in this paper in order to adequately specify the experimental procedure. Such identification does not imply recommendation or endorsement by the National Institute of Standards and Technology, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose.
References
Zeisler R, James WD, Mackey EA, Spatz RO, Greenberg RR (2008) J Radioanal Nucl Chem 278:783
Greenberg RR, Kingston HM (1983) Anal Chem 55:1180
Zeisler R, Greenberg RR, Mackey EA, Murphy KE, Spatz RO, Tomlin BE (2009) J Radioanal Nucl Chem. doi:10.1007/s10967-009-0089-4
Zeisler R (2000) J Radioanal Nucl Chem 244:507
Lindstrom RM, Zeisler R, Mackey EA, Liposky PJ, Popelka-Filcoff RS, Williams RE (2008) J Radioanal Nucl Chem 278:665
Byrne AR, Kučera J (1991) Fresenius J Anal Chem 340:48–52
Kučera J, Byrne AR (1993) J Radioanal Nucl Chem 168:201
Certificate of Analysis. http://ts.nist.gov/measurementservices/referencematerials/index.cfm
May WE, Gills TE, Parris R, Beck CM II, Fassett JD, Gettings RJ, Greenberg RR, Guenther FR, Kramer G, Macdonald BS, Wise SA (1999) NIST Special Publication 260-136. http://ts.nist.gov/MeasurementServices/ReferenceMaterials/upload/SP260-136.PDF
Levenson MS, Banks DL, Eberhardt KR, Gill LM, Guthrie WF, Liu KH, Vangel MG, Yen JH, Zhang NF (2000) J Res Natl Inst Stand Technol 105:571
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Zeisler, R., Tomlin, B.E., Murphy, K.E. et al. Neutron activation analysis with pre- and post-irradiation chemical separation for the value assignments of Al, V, and Ni in the new bovine liver SRM 1577C. J Radioanal Nucl Chem 282, 69–74 (2009). https://doi.org/10.1007/s10967-009-0141-4
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DOI: https://doi.org/10.1007/s10967-009-0141-4