Abstract
In this paper, methodology and applicability of the in situ radiotracer “thin gap” method are presented and discussed via some studies of Cr(VI) electroreduction on Pt electrode by measuring the low energy (E = 4.90 keV) X-rays of 51Cr used for labeling. Two types of scintillators, 2 mm thick β-plastic and 300 μm thick CaF2(Eu), were tested for nuclear detection. The plastic scintillator cannot be utilized for selective measurement of the soft X-rays emitted by 51Cr, hence, it does not allow us the estimation of the surface excess of chromium containing species on Pt electrode. In contrast to this, CaF2(Eu) is suitable for selective detection of low-energy X-rays; therefore, the radioelectrochemical cell equipped with the latter detector provides very promising measuring conditions for the extension of the radiotracer “thin gap” method towards application of the low-energy X-ray emitters.
Similar content being viewed by others
References
K. Varga, A. Szabó, R. Buják, A kémia újabb eredményei, B. Csákvári (Ed.), Akadémiai Kiadó, Budapest (in Hungarian).
G. Horányi, in: Interfacial Electrochemistry, A. Wieckowski (Ed.), Marcel Dekker Inc., New York (1999) p. 477.
K. Varga, Kémiai Közlemények, 83 (1996) 77
K. Varga, in: Radiotracer Studies of Interfaces, G. Horányi (Ed.), Interface Science and Technology, Vol. 3. Elsevier B. V., Amsterdam, 2004, p. 313.
K. Varga, E. Maleczki, E. Házi, G. Horányi, Electrochim. Acta, 35 (1990) 817.
A. Kolics, G. Horányi, Appl. Radiation Isotopes, 47 (1996) 551.
K. Varga, I. Szalóki, A. Somogyi, P. Baradlai, A. Aramata, T. Ohnisi, Y. Noya, J. Electroanal. Chem., 485 (2000) 121.
I. Szalóki, K. Varga, R. Van Grieken, Spectrochim. Acta, B55 (2000) 1031.
L. Gáncs, A. S. Besing, R. Buják, A. Kolics, Z. Németh, A. Wieckowski, Electrochem. Solid-State Lett., 5 (2002) B16.
K. Varga, I. Szalóki, L. Gáncs, R. Marczona, J. Electroanal. Chem., 524–525 (2002) 168.
I. Szalóki, S. Szegedi, K. Varga, M. Braun, J. Osán, R. Van Grieken, X-Ray Spectrom., 30 (2001) 49.
R. Buják, K. Varga, Electrochim. Acta, 52 (2006) 332.
V. E. Kazarinov, V. N. Andreev, in: Comprehensive Treatise of Electrochemistry, Vol. 9, E. Yeager, J. O’M. Bockris, B. E. Conway, S. Sarangapani (Eds), Plenum Press, New York, 1984, p. 393.
E. K. Krauskopf, A. Wieckowski, in: Frontiers of Electrochemistry, J. Lipkowski, P. N. Ross (Eds), VCH, New York, 1992, p. 119.
G. Aniansson, J. Phys. Chem., 55 (1951) 1286.
G. Hirschberg, P. Baradlai, K. Varga, G. Myburg, J. Schunk, P. Tilky, P. Stoddart, J. Nuclear Mater., 265 (1999) 273.
G. Hirschberg, Z. Németh, K. Varga, J. Electroanal. Chem., 456 (1998) 171.
K. Varga, G. Hirschberg, P. Baradlai, M. Nagy, in: Surface and Colloid Science, E. Matijevic (Ed.), Kluwer Academic/Plenum Press, New York, 2001, p. 341.
A. Wieckowski, A. Kolics, J. Electroanal. Chem., 464 (1999) 118.
A. Kolics, in: Radiotracer Studies of Interfaces, G. Horányi (Ed.), Interface Science and Technology, Vol. 3. Elsevier B. V., Amsterdam, 2004, p. 279.
G. F. Knoll, Radiation Detection and Measurement, John Wiley and Sons, New York, 1989.
J. O’M. Bockris, M. Gamboa-Aldeco, M. Szklarczyk, J. Electroanal. Chem., 339 (1992) 355.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Buják, R., Varga, K. On the applicability of radionuclides emitting low energy X-rays for in situ radiotracer adsorption studies. J Radioanal Nucl Chem 275, 181–191 (2008). https://doi.org/10.1007/s10967-007-6957-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-007-6957-x