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Ion-exchange studies of 110mAg(I) using synthetic inorganic ion-exchanger

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Abstract

In the present investigation, the selective adsorption of silver on synthetic inorganic ion exchanger, zinc(II) ferrocyanide, has been established by batch method, under specific conditions, using 110mAg as a tracer. The efficiency of adsorption has been determined by γ-ray spectrometry and was found to be greater than 96%. The Ag(I) uptake by the exchanger has also been evaluated. The selectivity of the method was checked by studying the adsorption of Ag(I) in the presence of a number of foreign ions using their corresponding tracers. The interfering ions were removed by washing the ion-exchanger with appropriate reagents, so that it could be applied for the determination of trace amount of Ag(I) in complex matrices, containing trace amount of other metal ions.

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References

  1. C. B. Amphlett, Inorganic Ion-exchangers, Elsevier Publishing Co., New York, 1964.

    Google Scholar 

  2. Advances in Technology for the Treatment of Low and Intermediate Level Radioactive Wastes, IAEA Proceeding Series, IAEA, Vienna, 1994, p. 370.

  3. R. Kunin, Ion-exchange Resins, John Willey and Sons Inc., New York, 1958.

    Google Scholar 

  4. O. Samuelson, Ion-exchange Separation in Analytical Chemistry, John Wiley and Sons, Inc., New York, 1963.

    Google Scholar 

  5. R. Gans, Zentr. Mineral. Geol., 22 (1913) 699.

    Google Scholar 

  6. J. S. Gill, S. N. Tondon, Radiochem. Radioanal. Lett., 14 (1973) 379.

    CAS  Google Scholar 

  7. L. Szirtes, L. Zsinka, Radiochem. Radioanal. Lett., 21 (1974) 267.

    CAS  Google Scholar 

  8. Y. Ioune, M. Tsuzi, Bull. Chem. Soc. Japan, 51 (1978) 794.

    Article  Google Scholar 

  9. T. S. Murthy, K. Balasubramanium, Proc. Nucl. Chem. Radiochem. Sym., Waltair, 1980, p. 309.

  10. F. HELFFERICH, Ion Exchange, McGraw Hill Book Co. Inc., New York, 1967.

    Google Scholar 

  11. http://risk.lsd.ornl.gov/tox/profiles/silver.html

  12. http://www.atsdr.cdc.govt./facts.html

  13. http://minerals.usgs.gov/minerals/pubs/commodity/silver.html

  14. R. B. Nene, Z. R. Turel, Indian J. Chem., 33A (1994) 357.

    CAS  Google Scholar 

  15. N. B. Dubey, H. K. Bagla, Proc. Intern. Nuclear Chemistry Congress, Turkey, 14, 2005.

  16. N. B. Dubey, H. K. Bagla, Proc. Nuclear Chemistry and Radiochemistry Symp., Amritsar, 2005, p. 359.

  17. G. Grader, M. Mlanov, Y. Prodanov, G. Sterfanov, J. Radioanal. Chem., 45 (1978) 103.

    Article  Google Scholar 

  18. G. Alberti, M. Casciola, U. Constantino, M. L. Luciani, J. Chromatogr., 128 (1976) 289.

    Article  CAS  Google Scholar 

  19. A. K. Jain, R. P. Singh, Balachand, J. Radioanal. Chem., 75 (1982) 85.

    Article  CAS  Google Scholar 

  20. W. U. Malik, S. K. Srivastava, R. P. Singh, K. Satish, J. Radioanal. Chem., 36 (1977) 469.

    Article  CAS  Google Scholar 

  21. J. P. Rawat, D. K. Singh, K. P. S. Muktawat, Chem. Anal., 24 (1979) 801.

    CAS  Google Scholar 

  22. K. Akitimiti, J. Radioanal. Chem., 45 (1978) 91.

    Article  Google Scholar 

  23. K. G. Varshney, S. Naheed, A. A. Khan, S. N. Tondon, C. B. Gupta, Chromatographia, 12 (1979) 473.

    Article  CAS  Google Scholar 

  24. K. G. Varshney, A. Premdas, J. Liqu. Chromatogr., 4 (1981) 915.

    Article  CAS  Google Scholar 

  25. A. K. De, K. Chaudhary, Separ. Sci., 10 (1975) 639.

    Article  Google Scholar 

  26. J. Mathew, S. N. Tondon, J. Radioanal. Chem., 27 (1975) 315.

    Article  CAS  Google Scholar 

  27. A. I. Vogel, Textbook of Quantitative Inorganic Analysis, 3rd ed., Longman Green & Co., London, 1975.

    Google Scholar 

  28. W. W. Scott, Standard Methods of Chemical Analysis, 6th ed., D. Van Nostrand Reinhold Co., New York, I, 1962.

    Google Scholar 

  29. S. Kawamura, H. Kuraku, K. Kurotaki, Anal. Chim. Acta., 49 (1947) 317.

    Article  Google Scholar 

  30. N. E. Topp, J. W. Pepper, J. Chem. Soc., Vol. A (1949) 3299.

    Article  Google Scholar 

  31. E. Lederer, M. Lederer, Chromatography, Elsevier Publ. Co., New York, 1954.

    Google Scholar 

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Authors and Affiliations

  1. Nuclear and Radiochemistry Laboratory, K. C. College, Dinshaw Wachha Road, Churchgate, Mumbai, 400020, India

    N. B. Dubey & H. K. Bagla

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  1. N. B. Dubey
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  2. H. K. Bagla
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Correspondence to H. K. Bagla.

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Dubey, N.B., Bagla, H.K. Ion-exchange studies of 110mAg(I) using synthetic inorganic ion-exchanger. J Radioanal Nucl Chem 274, 271–276 (2007). https://doi.org/10.1007/s10967-007-1110-4

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  • DOI: https://doi.org/10.1007/s10967-007-1110-4

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