Abstract
The work describes a procedure of preconcentration and separation of trace amounts of Pd(II) by solid phase extraction of the metal ion by dithiooxamide groups incorporated into a matrix of polystyrene-divinylbenzene whereas the determination of palladium has been carried out by radiotracer technique using 109Pd (T 1/2 = 13.43 hr, E γ = 311, 647 keV). The experiments were carried out using both batch method and column operation. Parameters such as the amount of resin, effect of pH, equilibration rate, sorption and desorption of metal ions have been studied. The maximum sorption capacity for palladium was found to be 0.10 mmol·g−1 at pH 6.0. The method is rapid, has a good accuracy and can be used routinely.
Similar content being viewed by others
References
R. Shah, S. Devi, Anal. Chim. Acta, 341 (1997) 217.
Y. Chen, C. Liang, Y. Chao, React. Funct. Polym., 36 (1998) 51.
K. D. Topp, M. Grote, React. Funct. Polym., 31 (1996) 117.
B. Konar, S. Basu, J. Das, Indian J. Chem., 31A (1992) 735.
S. Dutta, A. K. Das, Indian J. Chem. Technol., 12 (2005) 139.
B. C. Mondal, A. K. Das, Anal. Chim. Acta, 477 (2003) 73.
D. Banerjee, B. C. Mondal, D. Das, A. K. Das, Microchim. Acta, 141 (2003) 107.
M. Ahuja, A. K. Rai, P. N. Mathur, Talanta, 43 (1996) 1955.
D. Bilba, C. Paduraru, L. Tofan, Microchim. Acta, 144 (2004) 97.
D. Das, A. K. Das, C. Sinha, Talanta, 43 (1999) 1013.
M. A. Maheswari, M. S. Subramanian, Ann. Lett., 36 (2003) 2875.
M. Tuzen, I. Narin, M. Soylak, L. Elci, Ann. Lett., 37 (2004) 473.
M. Fujiwara, T. Matsushita, T. Kobayashi, Y. Yamashoji, M. Tanaka, Anal. Chim. Acta, 274 (1993) 293.
R. Gaita, S. J. A. Bari, Talanta, 42 (1995) 249.
B. W. Zhang, Y. Zhang, M. Grote, A. Kettrup, React. Polym., 22 (1994) 115.
S. Dutta, A. K. Das, J. Appl. Polym. Sci., in the press.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dutta, S., Mohapatra, P.K., Manchanda, V.K. et al. Preconcentration and separation of trace amounts of palladium using dithiooxamide functionalized chelating resin followed by its determination using radiotracer technique. J Radioanal Nucl Chem 274, 245–250 (2007). https://doi.org/10.1007/s10967-007-1106-0
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-007-1106-0