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Application of radiochemical technique in the investigation of chemical reaction at low temperature

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Abstract

Radiochemical technique was used to investigate cryogenic chemical reaction. By introducing reactants of H and T into liquid 3H through 3He(n,p)T reaction, behaviors of H+T→HT and T+T→T2 were investigated under pressurized condition. Within saturated vapor pressure upto 0.61 Mpa, the isotope ratio of HT/T2 changed. It was suggested that the change of HT/T2 was attributed to bubble formation and chemical potential in liquid helium.

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Authors and Affiliations

  1. Japan Atomic Energy Research Institute, Tokai-mura, Naka-gun, Ibaraki, 319-1112, Japan

    K. Iguchi & Y. Aratono

  2. Faculty of Science, Shizuoka University, Ohya, Shizuoka, 422-8529, Japan

    K. Okuno

Authors
  1. K. Iguchi
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  2. K. Okuno
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  3. Y. Aratono
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Iguchi, K., Okuno, K. & Aratono, Y. Application of radiochemical technique in the investigation of chemical reaction at low temperature. J Radioanal Nucl Chem 272, 293–297 (2007). https://doi.org/10.1007/s10967-007-0518-1

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  • DOI: https://doi.org/10.1007/s10967-007-0518-1

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