Skip to main content
SpringerLink
Log in

Preparation and characterization of fluorocarbon latex modified by diallyl malate

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Usually, the traditional acrylate polymer latex, which is used as the binder of the coatings, is a linear polymer and properties of the latex film cannot meet with the demand of the high-grade coatings. Presently, there are few reports on the polyacrylate latex modified by diallyl malate, i.e. butanedioic acid,2-hydroxy-, 1,4-di-2-propen-1-yl ester (BAHD) and long fluorocarbon acrylate monomer such as dodecafluoroheptyl methacrylate (DFMA) in the open literatures. The purpose of this work is that the cross-linked acrylate latex is prepared which DFMA and BAHD are used as the functional monomer and as a cross-linking monomer, respectively. The cross-linked acrylate latex is prepared which methyl methacrylate (MMA) and butyl acrylate (BA) is used as the main monomers and the non-ionic emulsifier isomeric alcohol polyoxyethylene ether (X-407) and the anionic emulsifier sodium dodecyl sulfonate (SDS) are used as emulsifiers. DFMA and BAHD are used as the functional monomer and as a cross-linking monomer, respectively. Factors which have an influence on the properties of the resultant latex and the emulsion polymerization are investigated in detail. The optimal recipe of preparing the latex is obtained as follows: the amount of mixed emulsifiers is 6% and mass ratio of X-470 to SDS is 2:1. When the amount of BAHD is 4.47%, the water absorption rate is reduced greatly. The glass transition temperature is 10 °C. In compassion with the conventional latex, the thermal decomposition temperature is increased by 10 °C. The resultant latex has good stability and small particle size. The latex film exhibits hydrophobicity and the water contact angle is more than 90°.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Guan SL (2013) Paint chemistry and technology [M]. Chemical Industry, Beijing, p 67

    Google Scholar 

  2. Wang XR, Yang LL, Zhang WH, Wang XL (2017) Research on the application of cross-linking monomer modified acrylate emulsion. Coat Ind 47(9):29–34

    CAS  Google Scholar 

  3. Zhang ZX, Fu GW, Chen RQ, Wang CP (2019) Study on properties of acrylate postcrosslinked emulsion. China Adhes 28(3):1–4

    Google Scholar 

  4. Zhang J, Du M (2009) Properties of self-crosslinking reactive acrylate microgel emulsion and its coating film. Synth Rubber Ind 32(2):109–113

    Google Scholar 

  5. Fei GQ, Wang J, Yang J, Wang H, Yang X, Zhu K (2019) Influence of soft and hard monomers on polysiloxane/acrylate composite emulsion. China Adhes 28(1):6–12

    Google Scholar 

  6. Liu ZG, Ye H,　Chao Z, Zhang MY, Li WM, Zhang HX, Liu FQ, Liu WJ (2010) Seeded emulsion polymerization of butyl acrylate using a redox initiator　system:　kinetics and mechanism. Ind Eng Chem Res 49(16):7152–7158

    Article  CAS  Google Scholar 

  7. Gong Y　L, Shao TT, Chen LJ (2020) Preparation and characterization of fluorine-containing soap-free acrylic emulsion. Pigment Resin Technol 50(1):41–47

    Article  Google Scholar 

  8. Yang TT, Peng H, Cheng SY, Park IJ (2005) Surface immobilization of perfluorinated acrylate copolymers by self-crosslinking. J Fluorine Chem 126(11–12):1570–1577

    CAS  Google Scholar 

  9. Chen YJ, Zhang CC, Wang YF, Cheng S, Chen P (2003) Study of self-crosslinking acrylate latex. J Appl Polym Sci 90(13):3609–3616

    Article  CAS  Google Scholar 

  10. Zhang YL, An QF, Yu Y (2013) Synthesis of self-crosslinking fluorine-containing acrylic resin and its application in coatings. Coat Ind 43(09):31–35

    Google Scholar 

  11. Du PH, Xiao XY, Zhang HP, Wan CX (2007) Preparation of self-crosslinking fluorine-containing acrylate copolymer emulsion. Progress Chem Ind 10:1456–1461

    Google Scholar 

  12. Xu W, An QF, Hao LF, Sun Z, Zhao WJ (2014) Synthesis of self-crosslinking fluorinated polyacrylate soap-free latex and its waterproofing application on cotton fabrics. Fibers Polym 15(3):457–464

    Article  CAS  Google Scholar 

  13. Chen LJ, Wu FQ (2012) Preparation and characterization of novel self cross-linking fluorinated acrylic latex. J Appl Polym Sci 123(4):1997–2002

    Article  CAS  Google Scholar 

  14. Fang C, Zhu K, Zhu XB, Lin Z (2019) Preparation and characterization of self-crosslinking fluorinated polyacrylate latexes and their pressure sensitive adhesive applications. Int J Adhes Adhes 95:1–8

    Article  Google Scholar 

  15. Tuba ÇÇ, Esin H, Ersin S (2013) Synthesis and characterization of perfluorinated acrylate–methyl methacrylate copolymers. J Appl Polym Sci 128(3):1450–1461

    Article  Google Scholar 

  16. Chen LJ, Shao TT, Gong YL (2019) Synthesis and characterization of fluoro-silicone polyacrylate latex emulsified with novel green surfactants. Progress Rubber Plast Recycling Technol 35(2):102–114

    Article  Google Scholar 

  17. Fu GW, Zhang YH, Zhag ZX, Chen RQ, Wang CP (2020) Influence and application of crosslinking monomers on acrylate emulsion polymerization. Chem World 61(10):705–712

    CAS  Google Scholar 

  18. Vijayabaskar V, Bhattacharya S, Tikku VK, Bhowmick AK (2004) Electron Beam initiated modification of acrylic elastomer in presence of polyfunctional monomers. Radiat Phys Chem 71(5):1045–1058

    Article  CAS  Google Scholar 

  19. Shen YD, He Y, Wang HH, Yang J, Fei G, Yang X (2019) Influence of crosslinking agent on properties of polysiloxane/acrylate emulsion. New Chem Mater 47(1):187–191

    Google Scholar 

  20. Hu Y, Li FY, Zhao TB (2020) Improvement of mechanical properties of hydrophobic fluoroacrylates by cross-linking modification by emulsion polymerization. Electroplating Finish 39(4):188–194

    Google Scholar 

  21. Cao S, Liu B, Deng X, Li S (2005) Core/shell particles containing 3-(methacryloxypropyl)-trimethoxysilane in the shell: synthesis, characterization, and application. Macromol Biosci 5(7):669

    Article  CAS  PubMed  Google Scholar 

  22. Chen YJ, Hou FQ, Qing Q (2013) Research progress on modification of acrylate coatings. Mater Rev 27(Supplement 1):236–240

    Google Scholar 

  23. Lü T, Qi DM, Zhang D, Liu Q, Zhao HT (2016) Fabrication of self-cross-linking fluorinated polyacrylate latex particles with core–shell structure and film properties. Reactive Funct Polym 104:9–14

    Article  Google Scholar 

  24. Yu XL, Chen JF, Liu W (2016) Q.The relationship between the structure of polymethacrylate-based motor units and the glass transition temperature. Polym Mater Sci Eng 32(6):49–53

    CAS  Google Scholar 

  25. Li YW, Xu SF, Ma DX (2020) Research on polymer physics teaching in series with glass transition temperature (tg). Polym Bull 9:74–77

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemical Engineering, Zhejiang University of Technology, No. 18 Chaowang Road, Hangzhou, 310032, Zhejiang Province, P.R. China

    Lijun Chen & Shusen Cao

Authors
  1. Lijun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shusen Cao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Lijun Chen.

Ethics declarations

Conflict of interest

No conflict of interest exits in the submission of this manuscript and manuscript is approved by all authors for publication. I would like to declare on behalf of my co-authors that the work described was original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary Material 1

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, L., Cao, S. Preparation and characterization of fluorocarbon latex modified by diallyl malate. J Polym Res 31, 148 (2024). https://doi.org/10.1007/s10965-024-03997-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-024-03997-3

Keywords

Search

Navigation