Abstract
Bioderived polycarbonate (ISB-PC) was synthesized via transesterification and polycondensation of isosorbide (ISB) and diphenyl carbonate (DPC) using lithium acetoacetone as a catalyst. The resulting ISB-PC exhibited high glass transition temperatures similar to bisphenol A polycarbonate (BPA-PC) and was thermally stable up to 350 ℃. The incorporation of isosorbitol into the polymer chain imparted an improved mechanical property of ISB-PC, such as a higher bending and tensile modulus and higher elongation at break. ISB-PC can be readily cast into transparent films with a tensile strength of 73.3 MPa and a tensile modulus of 534 MPa. ISB-PC displayed high UV transmittance and possessed blue fluorescence under UV irradiation. At the same time, ISB-PC also has strong anti-yellowing ability.
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The data that support the findings of this study are available from the corresponding author upon reasonable request.
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Acknowledgment
The authors wish to thank for the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province (2019CL04).
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The Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province, 2019 CL04, Fang Wu.
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Wu, F., Pu, Z., Hou, H. et al. Comparison of the properties of bioderived polycarbonate and traditional bisphenol-A polycarbonate. J Polym Res 30, 298 (2023). https://doi.org/10.1007/s10965-023-03687-6
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DOI: https://doi.org/10.1007/s10965-023-03687-6