Skip to main content

Advertisement

Log in

Effect of infusion strategy on vacuum bagging process and properties of polyamide 6 composites

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

In this work, glass fiber reinforced polyamide 6 (GF/PA6) composites were fabricated by vacuum bagging (VB) process. An experimental platform for VB process of continuous fiber reinforced polyamide 6 composites was constructed in combination with the in-situ polymerization characteristics of caprolactam. The differences in properties such as crystallinity, reaction conversion rate and mechanical properties of the composites produced by the two infusion strategies were investigated. The results showed that the composites fabricated by isothermal infusion had high crystallinity and good internal homogeneity. Compared with isothermal infusion, the mechanical properties of composites fabricated by non-isothermal infusion were higher. At a curing temperature of 150 °C, the mechanical properties of the composite were enhanced at the outlet than the inlet. Flexural strength and ILSS had been improved by 13.2% and 16.3%, respectively. The flexural strength and flexural modulus were 273.7 MPa and 14.2 GPa, respectively. ILSS of the composites reached a maximum value of 47.3 MPa at 170 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

Data Availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

References

  1. Gong Y, Yang G (2010) All-polyamide composites prepared by resin transfer molding. Mater Sci 45(19):5237–5243

    Article  CAS  Google Scholar 

  2. Zaldua N, Maiz J, de la Calle A et al (2019) Nucleation and crystallization of PA6 composites prepared by T-RTM: Effects of carbon and glass fiber loading. Polymers 11(10):1680–1686

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. Abderrahim M, Khalid L, Mohamed D (2018) Chemorheological study and in-situ monitoring of PA6 anionic-ring polymerization for RTM processing control. Compos Part A 107(1):235–247

    Google Scholar 

  4. Dencheva N, Sampaio AS, Oliveira FM et al (2014) Preparation and properties of polyamide-6‐based thermoplastic laminate composites by a novel in‐mold polymerization technique. J Appl Polym Sci 131(8):1–11

    Article  Google Scholar 

  5. Tohidi SD, Rocha AM, Dencheva NV et al (2019) Comparative structural and mechanical studies on polyamide 6 knitted-reinforced single polymer composites prepared by different reactive processing techniques. Polym Compos 40(51):886–897

    Google Scholar 

  6. Ding X, He Q, Yang Q et al (2022) Numerical simulation of impregnation process of reactive injection pultrusion for glass fiber/PA6 composites. Polymers 14(4):666

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  7. Epple S, Bonten C (2014) Production of continuous fiber thermoplastic composites by in-situ pultrusion//AIP Conference Proceedings. Am Inst Phys 1593(1):454–457

    CAS  Google Scholar 

  8. Chen K, Jia M, Sun H et al (2019) Thermoplastic reaction injection pultrusion for continuous glass fiber-reinforced polyamide-6 composites. Materials 12(3):463–477

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. Chen K, Jia M, Sun H et al (2019) Optimization of initiator and activator for reactive thermoplastic pultrusion. J Polym Res 26(2):1–10

    Article  Google Scholar 

  10. Yan C, Li H, Zhang X et al (2013) Preparation and properties of continuous glass fiber reinforced anionic polyamide-6 thermoplastic composites. Mater Design 46(4):688–695

    Article  CAS  Google Scholar 

  11. van Rijswijk K, Bersee HEN, Jager WF et al (2006) Optimisation of anionic polyamide-6 for vacuum infusion of thermoplastic composites: choice of activator and initiator. Compos Part A Appl Sci Manufac 37(6):949–956

    Article  Google Scholar 

  12. Van Rijswijk K, Bersee HEN, Beukers A et al (2006) Optimisation of anionic polyamide-6 for vacuum infusion of thermoplastic composites: influence of polymerisation temperature on matrix properties. Polym Test 25(3):392–404

    Article  Google Scholar 

  13. Teuwen JJE, Ang HSA, Bersee HEN (2010) Post-processing of anionic polyamide-6 composites. In Proceedings of 55th International SAMPE Symposium, Seattle, WA.

  14. Teuwen JJE, Van Geenen AA, Bersee HEN (2012) Vacuum-infused anionic polyamide-6 composites: the effect of postprocessing. J Thermoplast Compos Mater 25(8):965–986

    Article  Google Scholar 

  15. Teuwen JJE, van Geenen AA, Bersee HEN (2013) Novel reaction kinetic model for anionic polyamide-6. Macromol Mater Eng 298(2):163–173

    Article  CAS  Google Scholar 

  16. Teuwen JJE (2011) Thermoplastic composite wind turbine blades: kinetics and processability. Technische Universiteit Delft, Delft, Nederland.

  17. Barbosa LCM, Duque GRV, Junior ACA (2020) Temperature-frequency-dependent properties analysis of a bio-composite based on a new liquid thermoplastic resin reinforced with jute fibers. J Thermoplast Compos Mater 3:1–21

    Google Scholar 

  18. Shi H, Xia L, Guo Z et al (2019) Manufacture and performance of textile-ramie fiber reinforced anionic polyamide 6 composites. Fibers Polym 20(8):1705–1715

    Article  CAS  Google Scholar 

  19. Struzziero G, Teuwen JJE (2019) Effect of convection coefficient and thickness on optimal cure cycles for the manufacturing of wind turbine components using VARTM. Compos Part A Appl Sci Manufac 123:25–36

    Article  CAS  Google Scholar 

  20. van Rijswijk K (2007) Thermoplastic composite wind turbine blades: vacuum infusion technology for anionic polyamide-6 composites. Technische Universiteit Delft, Delft, Nederland.

  21. Pepin J, Miri V, Lefebvre JM (2016) New insights into the Brill transition in polyamide 11 and polyamide 6. Macromolecules 49(2):564–573

    Article  CAS  Google Scholar 

  22. Teuwen JJE, van Rijswijk K, Harald ENB et al (2007) Effect of fibre textile reinforcement on anionic polyamide-6 composite properties .Kyoto Janpan: International conferenence on composite material, 1–7

  23. Teuwen J, Gillis J, Bersee H (2013) Optimisation of Infusion Temperature for Anionic Polyamide-6 Composites. 49th AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics, and Materials Conference, Schaumburg, Illinois, USA.

  24. Charron JF (2011) Vacuum infused anionic polyamide-6 composites a quest for uniformity. Technische Universiteit Delft, Delft, Nederland.

  25. Cartledge HCY, Baillie CA (1999) Studies of microstructural and mechanical properties of nylon/glass composite part I the effect of thermal processing on crystallinity, transcrystallinity and crystal phases. Mater Sci 34(20):5099–5111

    Article  CAS  Google Scholar 

  26. Rijswijk KV, Teuwen JJE, Bersee HEN et al (2009) Textile fiber-reinforced anionic polyamide-6 composites. Part I: The vacuum infusion process. Compos Part A Appl Manuf 40(1):1–10

    Article  Google Scholar 

  27. Ricco L, Russo S, Orefice G et al (1999) Anionic poly (ε-caprolactam): Relationships among conditions of synthesis, chain regularity, reticular order, and polymorphism. Macromolecules 32(23):7726–7731

    Article  CAS  Google Scholar 

  28. Rijswijk KV, Teuwen J, Bersee H et al (2007) The interface of reactive-and melt processed polyamide-6 composites. In Proceedings of 16th international conference on composite materials, Kyoto, Japan.

Download references

Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (Grant No. ZY2204).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Ke Chen or Mingyin Jia.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dong, X., Chen, K., Xue, P. et al. Effect of infusion strategy on vacuum bagging process and properties of polyamide 6 composites. J Polym Res 30, 137 (2023). https://doi.org/10.1007/s10965-023-03507-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-023-03507-x

Keywords

Navigation