Skip to main content

Advertisement

Log in

Production and properties of epoxy matrix composite reinforced with hollow silica nanospheres (HSN): mechanical, thermal insulation, and sound insulation properties

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Hollow silica nanospheres (HSNs) have superior properties such as low density, low dielectric constant, low thermal conductivity, good sound absorption, dispersibility, fluidity, and stability. They have the potential to be utilised as a reinforcing material in the development of next generation composites due to their properties. Epoxy is one of the commonly utilised polymers in today’s technology. Production of epoxy matrix composite materials reinforced with particles having superior properties will open up new application areas for epoxy. In this study, mesoporous HSNs were produced. The mechanical, thermal and sound insulation properties of the composite were examined by reinforcing these mesoporous HSNs to the epoxy matrix. The epoxy matrix was reinforced with HSNs at 1 wt.%, 5 wt.%, and 10 wt.%. When the concentration of HSNs in the epoxy matrix was increased, its strength increased and its ductility decreased. While the non-reinforced epoxy had a tensile strength of 36.45 MPa, but the tensile strength of epoxy at the end of 10% HSN reinforcement reached 89.06 MPa. The strain % reduced in half. The sound insulation properties of epoxy improved as the concentration of HSNs increased. Thermal conductivity coefficient dropped up to a 5% reinforcement ratio, and then increased slightly at a 10% reinforcement ratio. The microstructure analyses indicated that when the reinforcement ratio increased, difficulties in the distribution of reinforcements to the matrix appeared. Furthermore, it was observed that when the matrix/reinforcement interface was improved, the properties of the composite improved.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. Zheng Y, Zheng Y, Ning R (2003) Effects of nanoparticles SiO2 on the performance of nanocomposites. Mater Lett 57:2940–2944

    Article  CAS  Google Scholar 

  2. Toldy A, Szolnoki B, Marosi G (2011) Flame retardancy of fibre-reinforced epoxy resin composites for aerospace applications. Polym Degrad Stab 96:371–376

    Article  CAS  Google Scholar 

  3. Gao G, Hu Y, Jia H, Liu P, Du P, Xu D (2019) Acoustic and dielectric properties of epoxy resin/hollow glass microsphere composite acoustic materials. J Phys Chem Solids 135:109105

    Article  Google Scholar 

  4. Aradhana R, Mohanty S, Nayak SK (2019) Novel electrically conductive epoxy/reduced graphite oxide/silica hollow microspheres adhesives with enhanced lap shear strength and thermal conductivity. Compos Sci Technol 169:86–94

    Article  CAS  Google Scholar 

  5. Bertling J, Blömer J, Kümmel R (2004) Hollow microsperes. Chem Eng Technol Ind Chem Plant Equipment-Process Eng Biotechnol 27:829–837

    CAS  Google Scholar 

  6. Zhu B, Wang J, Zheng H, Ma J, Wu J, Wu R (2015) Investigation of thermal conductivity and dielectric properties of LDPE-matrix composites filled with hybrid filler of hollow glass microspheres and nitride particles. Compos B Eng 69:496–506

    Article  CAS  Google Scholar 

  7. Yung KC, Zhu B, Yue TM, Xie C (2009) Preparation and properties of hollow glass microsphere-filled epoxy-matrix composites. Compos Sci Technol 69:260–264

    Article  CAS  Google Scholar 

  8. Vlassov S, Oras S, Timusk M, Zadin V, Tiirats T, Sosnin IM, Lõhmus R, Linarts A, Kyritsakis A, Dorogin LM (2022) Thermal, Mechanical, and Acoustic Properties of Polydimethylsiloxane Filled with Hollow Glass Microspheres. Materials 15:1652

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. Wang H, Hou F, Chang C (2020) Experimental and computational modeling of thermal conductivity of cementitious syntactic foams filled with hollow glass microspheres. Constr Build Mater 265:120739

    Article  Google Scholar 

  10. Liu C, Kim JS, Kwon Y (2016) Comparative investigation on thermal insulation of polyurethane composites filled with silica aerogel and hollow silica microsphere. J Nanosci Nanotechnol 16:1703–1707

    Article  CAS  PubMed  Google Scholar 

  11. Cao X, Wen J, Song L, Liu X, He G (2021) Polyimide hollow glass microspheres composite films with low dielectric constant and excellent thermal performance. J Appl Polym Sci 138:50600

    Article  CAS  Google Scholar 

  12. Zhu B, Ma J, Wang J, Wu J, Peng D (2012) Thermal, dielectric and compressive properties of hollow glass microsphere filled epoxy-matrix composites. J Reinf Plast Compos 31:1311–1326

    Article  Google Scholar 

  13. Zhu B, Zheng H, Wang J, Ma J, Wu J, Wu R (2014) Tailoring of thermal and dielectric properties of LDPE-matrix composites by the volume fraction, density, and surface modification of hollow glass microsphere filler. Compos B Eng 58:91–102

    Article  CAS  Google Scholar 

  14. Pakdel E, Naebe M, Kashi S, Cai Z, Xie W, Yuen ACY, Montazer M, Sun L, Wang X (2020) Functional cotton fabric using hollow glass microspheres: Focus on thermal insulation, flame retardancy, UV-protection and acoustic performance. Prog Org Coat 141:105553

    Article  CAS  Google Scholar 

  15. Yang P, Ding J, Guo J, Shi W, Hu JJ, Wang C (2013) A strategy for fabrication of uniform double-shell hollow microspheres as effective acoustic echo imaging contrast agents through a new polymer-backbone-transition method. J Mater Chem B 1:544–551

    Article  CAS  PubMed  Google Scholar 

  16. Zhang Z, Jiang H, Li R, Gao S, Wang Q, Wang G, Ouyang X, Wei H (2021) High-damping polyurethane/hollow glass microspheres sound insulation materials: Preparation and characterization. J Appl Polym Sci 138:49970

    Article  CAS  Google Scholar 

  17. Shi X, Wu J, Wang X, Zhou X, Xie X, Xue Z (2017) Novel sound insulation materials based on epoxy/hollow silica nanotubes composites. Compos B Eng 131:125–133

    Article  CAS  Google Scholar 

  18. Yang H, Jiang Y, Liu H, Xie D, Wan C, Pan H, Jiang S (2018) Mechanical, thermal and fire performance of an inorganic-organic insulation material composed of hollow glass microspheres and phenolic resin. J Colloid Interface Sci 530:163–170

    Article  CAS  PubMed  Google Scholar 

  19. Wang Y, Meng X, Wang C, Han Z, Shi H (2021) Fire reaction properties of polystyrene-based composites using hollow silica as synergistic agent. J Therm Anal Calorim 146:1679–1686

    Article  CAS  Google Scholar 

  20. Jiao C, Wang H, Li S, Chen X (2017) Fire hazard reduction of hollow glass microspheres in thermoplastic polyurethane composites. J Hazard Mater 332:176–184

    Article  CAS  PubMed  Google Scholar 

  21. Chen K, Tan Y, Wang K, Niu J, Chen ZY (2022) High specific capacity of carbon coating lemon-like SiO2 hollow spheres for lithium-ion batteries. Electrochim Acta 401:139497

    Article  CAS  Google Scholar 

  22. Han Y, Guo Z, Teng S, Xia H, Wang D, Han M-Y, Yang W (2019) Rationalized fabrication of structure-tailored multishelled hollow silica spheres. Chem Mater 31:7470–7477

    Article  CAS  Google Scholar 

  23. Nuruzzaman M, Ren J, Liu Y, Rahman MM, Shon HK, Naidu R (2019) Hollow porous silica nanosphere with single large pore opening for pesticide loading and delivery. ACS Appl Nano Mater 3:105–113

    Article  Google Scholar 

  24. Dong Z, Jiang M-Y, Shi J, Zheng M-M, Huang F-H (2019) Preparation of immobilized lipase based on hollow mesoporous silica spheres and its application in ester synthesis. Molecules 24:395

    Article  PubMed Central  Google Scholar 

  25. Buttersack C (2019) Modeling of type IV and V sigmoidal adsorption isotherms. Phys Chem Chem Phys 21:5614–5626

    Article  CAS  PubMed  Google Scholar 

  26. Ambroz F, Macdonald TJ, Martis V, Parkin IP (2018) Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs. Small Methods 2:1800173

    Article  Google Scholar 

  27. Aradhya R, Renukappa NM (2018) In: Maalawi KY (ed) Optimum Composite Structures. IntechOpen, London

    Google Scholar 

  28. Sun Y, Zhang Z, Moon KS, Wong C (2004) Glass transition and relaxation behaviour of epoxy nanocomposites. J Polym Sci Part B Polym Phys 42:3849–3858

    Article  CAS  Google Scholar 

  29. Maity P, Kasisomayajula SV, Parameswaran V, Basu S, Gupta N (2008) Improvement in surface degradation properties of polymer composites due to pre-processed nanometric alumina fillers. IEEE Trans Dielectr Electr Insul 15:63–72

    Article  CAS  Google Scholar 

  30. Ghadimi-Herfeh F, Rahimi A, ErshadLangroudi A (2014) Investigation of SiO2- epoxy and SiO2-TiO2-epoxy nanocomposite coatings via Taber abrasion experiment. 11th International Seminar on Polymer Science and Technology

  31. Zhao R, Luo W (2008) Fracture surface analysis on nano-SiO2/epoxy composite. Mater Sci Eng A 483:313–315

    Article  Google Scholar 

  32. Lu S-r, Hongyu J, H-l Z, Wang X-y (2005) Wear and mechanical properties of epoxy/SiO2-TiO2 composites. J Mater Sci 40:2815–2821

    Article  CAS  Google Scholar 

  33. Lee J-W, Lee J-C, Pandey J, Ahn S-H, Kang YJ (2010) Mechanical properties and sound insulation effect of ABS/carbon-black composites. J Compos Mater 44:1701–1716

    Article  CAS  Google Scholar 

  34. Kaya GG, Yilmaz E, Deveci H (2018) Sustainable nanocomposites of epoxy and silica xerogel synthesized from corn stalk ash: Enhanced thermal and acoustic insulation performance. Compos B Eng 150:1–6

    Article  Google Scholar 

  35. Bao Y, Wang T, Kang Q, Shi C, Ma J (2017) Micelle-template synthesis of hollow silica spheres for improving water vapor permeability of waterborne polyurethane membrane. Sci Rep 7:1–14

    Article  Google Scholar 

  36. Li G, He Y, Zhu P, Zhao T, Sun R, Lu D, Wong C-p (2018) Tailored surface chemistry of SiO2 particles with improved rheological, thermal-mechanical and adhesive properties of epoxy based composites for underfill applications. Polymer 156:111–120

    Article  CAS  Google Scholar 

  37. Guchait A, Saxena A, Chattopadhyay S, Mondal T (2022) Influence of Nanofillers on Adhesion Properties of Polymeric Composites. ACS Omega 7:3844–3859

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  38. Jiang F, Li Z, Ji X, Gao C, Niu C (2020) Preparation and properties of hollow ceramic spheres-epoxy dielectric composites. IEEE Trans Dielectr Electr Insul 27:842–847

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ömer Güler.

Ethics declarations

Competing of interests

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Demir, E., Güler, Ö. Production and properties of epoxy matrix composite reinforced with hollow silica nanospheres (HSN): mechanical, thermal insulation, and sound insulation properties. J Polym Res 29, 477 (2022). https://doi.org/10.1007/s10965-022-03322-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-022-03322-w

Keywords

Navigation