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Extremely adherent and protective polymeric coating based on polydiphenylamine electrodeposited on steel in an organic electrolytic medium

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Abstract

The present work fits into the efforts deployed to minimize the huge problems related to corrosion phenomena. As several industries are affected by the deterioration of metallic materials, new solutions need to be offered by the scientific community. In this context, we describe, in this paper, the electrochemical synthesis of polydiphenylamine coating (PDPA) on steel in an organic solution consisting of CH2Cl2 as solvent and N(Bu)4PF6 as supporting electrolyte. The electrolytic medium has been retained after a preliminary electrogravimetric study has shown that it can inhibit the working electrode dissolution without preventing the PDPA film formation. Spectroscopic and microscopic analyses were then achieved for the elaborated coatings. Analyses by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) have allowed a detailed characterization of the polymer (molecular structure, doping rate, chain length, …). In addition, morphological characterization by scanning electron microscope (SEM) confirmed that the value of the applied current density has a direct influence on the properties of the obtained polymer. The homogeneity and high adherence of the prepared PDPA film allow its use as a protective coating against steel dissolution. For this, corrosion tests were performed by studying the open-circuit potential (OCP), linear polarization curve (Tafel) as well as electrochemical impedance spectroscopy (EIS). The studies achieved in 3% NaCl solution have confirmed that the potential of the steel electrode shifts towards its passivation domain with the presence of PDPA coating. The latter is stable over time in contact with an aggressive solution and the inhibitory efficiency reached 97.2%.

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Funding

This work was supported by the MESRSFC and CNRST (Morocco) under grant No. PPR/30/2015.

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Authors and Affiliations

  1. Laboratory of Applied Chemistry and Environment, Faculty of Sciences, Mohammed First University, Oujda, 60000, Morocco

    Mimouna Bouabdallaoui, Abdelqader El Guerraf, Zaynab Aouzal & El Arbi Bazzaoui

  2. Materials and Environmental Laboratory, Faculty of Sciences, Ibn Zohr University, Agadir, 80000, Morocco

    Mohammed Bazzaoui

  3. Department of Mechanical Systems Engineering, Faculty of Engineering, Hiroshima Institute of Technology, 2-1-1 Miyake, Saeki-ku, Hiroshima, 731-5193, Japan

    Rongguang Wang

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  1. Mimouna Bouabdallaoui
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Bouabdallaoui, M., El Guerraf, A., Aouzal, Z. et al. Extremely adherent and protective polymeric coating based on polydiphenylamine electrodeposited on steel in an organic electrolytic medium. J Polym Res 29, 357 (2022). https://doi.org/10.1007/s10965-022-03215-y

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