Skip to main content

Advertisement

SpringerLink
Log in

The improvement of mechanical properties of repair and construction compositions based on epoxy resin with mineral fillers

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

The mechanical properties of repair composites and P-concretes based on epoxy diane resin binder (ED-20, 100% wt) + (L-20, 90% wt) modified with nanostructuring silicon-containing additive (PDMS-5) + (HDK) filled by mineral fillers are studied experimentally. The molding, filling and repair compounds are developed. Quantitative dependences of the change in physical and mechanical characteristics on the ratio of the components of the filled compositions are obtained. Higher strength indicators are achieved when using sand fraction (150% wt) of 1.25–2.2 mm, compressive strength is 108 MPa. The maximum compressive strength of cement-filled (80% wt) repair compound is 123 MPa. P-concretes on mixed aggregate (cement/sand) have higher mechanical properties: compressive strength is 117 MPa; bending strength is 16 MPa; ultimate tensile strength is 30 MPa.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Hu Q, Chen ZR, Xi LJ, Wang XY, Wang HF (2018) The application of epoxy resin coating in grounding grid. IOP Conference Series: Materials Science and Engineering 292:012110. https://doi.org/10.1088/1757-899X/292/1/012110

    Article  Google Scholar 

  2. Zakaria MR, Kudus MHA, Akil HMd, Thirmizir MZM (2017) Comparative study of graphene nanoparticle and multiwall carbon nanotube filled epoxy nanocomposites based on mechanical, thermal and dielectric properties. Compos B Eng 119:57–66. https://doi.org/10.1016/j.compositesb.2017.03.023

    Article  CAS  Google Scholar 

  3. Meiirbekov MN, Ismailov MB, Manko TA (2020) The effect of the modification of an epoxy resin by liquid oligomers on the physical-mechanical properties of composites. Voprosy khimii i khimicheskoi tekhnologii, 3:122–127. https://doi.org/10.32434/0321-4095-2020-130-3-122-127

  4. Apuzzo A, Fabbrocino F, Russo E, Russo P (2018) 8 - Potential of Nanomaterials to Improve the Performances of Epoxy Resins for Civil Applications, Ed(s): Francesco Marotti de Sciarra, Pietro Russo, In Micro and Nano Technologies, Experimental Characterization, Predictive Mechanical and Thermal Modeling of Nanostructures and their Polymer Composites, Elsevier 273–291. https://doi.org/10.1016/B978-0-323-48061-1.00008-7

  5. Kablov EN, Erofeev VT, Rimshin VI, Zotkina MM, Dergunova AV, Moiseev VV (2020) Plasticized epoxy composites for manufacturing of composite reinforcement. J Phys: Conf Ser 1687:012031. https://doi.org/10.1088/1742-6596/1687/1/012031

    Article  CAS  Google Scholar 

  6. Kiryushina NYu, Semeykin AYu (2020) Properties of Epoxy-Diane Composites Modified by Techno-Genic Fillers. Solid State Phenom 299:84–88. https://doi.org/10.4028/www.scientific.net/ssp.299.84

    Article  Google Scholar 

  7. Szewczak A, Szelag M (2020) Physico-Mechanical and Rheological Properties of Epoxy Adhesives Modified by Microsilica and Sonication Process. Materials 13(23):5310. https://doi.org/10.3390/ma13235310

    Article  CAS  PubMed Central  Google Scholar 

  8. Smirnov SV, Veretennikova IA, Smirnova EO, Pestov AV (2017) Effect of Fillers in Epoxy Coatings Based on the ED-20 Resin on the Mechanical Properties Determined by Instrumented Microindentation. AIP Conf Proc 1915:020008. https://doi.org/10.1063/1.5017320

    Article  CAS  Google Scholar 

  9. Smirnov SV, Veretennikova IA, Smirnova EO, Pestov AV (2017) Estimating the effect of fillers on the mechanical properties of epoxy glue coatings by microindentation. Diagn Resour Mech Mater Struct 6:103–111. https://doi.org/10.17804/2410-9908.2017.6.103-111

  10. Tan EKW, Shrestha PK, Pansare AV, Chakrabarti S, Li S, Chu D, Lowe CR, Nagarkar AA (2019) Density Modulation of Embedded Nanoparticles via Spatial, Temporal, and Chemical Control Elements. Adv Mater 31:1901802. https://doi.org/10.1002/adma.201901802

    Article  CAS  Google Scholar 

  11. Kisiel M, Mossety-Leszczak B (2020) Development in liquid crystalline epoxy resins and composites – A review. Eur Polymer J 124:109507. https://doi.org/10.1016/j.eurpolymj.2020.109507

    Article  CAS  Google Scholar 

  12. Fan-Long J, Soo-Jin P, Jae-Rock L (2005) Synthesis and Characterization of a Novel Silicon-Containing Epoxy Resin. Macromol Res 13:8–13

    Article  Google Scholar 

  13. Xiao F, Sun Y, Xiu Y, Wong CP (2007) Preparation, Thermal and Mechanical Properties of POSS Epoxy Hybrid Composites. J Appl Polym Sci 181:2113–2121. https://doi.org/10.1002/app.25746

    Article  CAS  Google Scholar 

  14. Radoman TS, Džunuzović JV, Jeremić KB, Grgur BN, Miličević DS, Popović IG, Džunuzović ES (2014) Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters. Mater Des 62:158–167. https://doi.org/10.1016/j.matdes.2014.05.015

    Article  CAS  Google Scholar 

  15. Jin XC, Guo LY, Deng LL, Wu H (2017) Study on epoxy resin modified by polyether ionic liquid. IOP Conf Ser: Mater Sci Eng 213

  16. Yan Z, Zhen-yu J, Fa-rong H, Lei D (2011) Characterization of a modified siliconcontaining arylacetylene resin with POSS functionality. Chin J Polym Sci 29:726–731

    Article  Google Scholar 

  17. Purohit A, Satapathy A (2017) Mechanical and wear characteristics of epoxy composites filled with industrial wastes: A comparative study. IOP Conf Ser: Mater Sci Eng 178:012019. https://doi.org/10.1088/1757-899X/178/1/012019.

  18. Guzel G, Devec H (2018) Properties of polymer composites based on bisphenol A epoxy resins with original/modified steel slag. Polym Compos 39:513–521. https://doi.org/10.1002/pc.23962

    Article  CAS  Google Scholar 

  19. Kline DE (1960) Dynamic mechanical properties of polymerized epoxy resins. J Polym Sci 47:237–249. https://doi.org/10.1002/pol.1960.1204714921

  20. Álvarez-Muñoz D, Llorca M, Blasco J, Barceló D (2016) Chapter 1 - Contaminants in the Marine Environment, Marine Ecotoxicology, Academic Press, 1–34. https://doi.org/10.1016/B978-0-12-803371-5.00001-1

  21. Mata A, Fleischman AJ, Roy S (2005) Characterization of Polydimethylsiloxane (PDMS) Properties for Biomedical Micro/Nanosystems. Biomed Microdevices 7:281–293. https://doi.org/10.1007/s10544-005-6070-2

    Article  CAS  PubMed  Google Scholar 

  22. Morel B, Autissier L, Autissier D, Lemordant D, Yrieix B, Quenard D (2009) Pyrogenic silica ageing under humid atmosphere. Powder Technol 190(1–2):225–229. https://doi.org/10.1016/j.powtec.2008.04.049

    Article  CAS  Google Scholar 

  23. SR 11 AE Us Basic Characteristics of AEROSIL (2006–04) Degussa. Techical Bulletin Fine Particle. No 11. Available at: https://docuri.com/download/sr-11-ae-us-basic-characteristics-of-aerosil-2006-04_59bb854cf581719a317294b8_pdf#modals

  24. Linear Polydimethylsiloxanes CAS No. 63148–62–9 (Second Edition). JACC No. 5 (Brussels, 2011) 155. Available at: https://www.ecetoc.org/wp-content/uploads/2014/08/JACC-055-Linear-Polydimethylsiloxanes-CAS-No.-63148-62-9-Second-Edition.pdf

  25. Savotchenko SE, Kovaleva EG (2021) The equation of glass transition of epoxy diane resin modified with the nanoparticle fillers. Polym Bull 78. https://doi.org/10.1007/s00289-021-03844-1

  26. Kovaleva EG, Savotchenko SE (2022) Kinetics of epoxy resin optical characteristics during ultrasonic processing. J Compos Mater 56(3):387–395. https://doi.org/10.1177/00219983211046373

    Article  CAS  Google Scholar 

  27. Kovaleva EG, Savotchenko SE (2022) Kinetic features of polymerization of epoxy resin modified by silicon-containing additives and mineral fillers. Polym Eng Sci 62(1):75–82. https://doi.org/10.1002/pen.25833

    Article  CAS  Google Scholar 

  28. Savotchenko SE, Kovaleva EG (2021) Mechanical properties of cured epoxy resin. Mod Phys Lett B 35:2150445. https://doi.org/10.1142/S0217984921504455

    Article  CAS  Google Scholar 

  29. Frigione M, Lettieri M, Lionetto F, Mascia L (2020) Experimental Cold-Cured Nanostructured Epoxy-Based Hybrid Formulations: Properties and Durability Performance. Polymers 12:476. https://doi.org/10.3390/polym12020476

    Article  CAS  PubMed Central  Google Scholar 

  30. Dyakonov T, Mann P, Chen Y, Stevenson TK (1996) Thermal analysis of some aromatic amine cured model epoxy resin systems-II: Residues of degradation. Polym Degrad Stab 53:67–83. https://doi.org/10.1016/0141-3910(96)00096-1

    Article  Google Scholar 

  31. Balcerzak ES, Janeczek H, Kaczmarczyk B (2004) Epoxy resin cured with diamine bearing azobenzene group. Polymer 45:2483–2493. https://doi.org/10.1016/j.polymer.2004.02.027

    Article  CAS  Google Scholar 

  32. Maity T, Samanta BC, Dalai S, Banthia AK (2007) Curing study of epoxy resin by new aromatic amine functional curing agents along with mechanical and thermal evaluation. Mater Sci Eng A 464:38–46. https://doi.org/10.1016/j.msea.2007.01.128

    Article  CAS  Google Scholar 

  33. Lionetto F, Timo A, Frigione M (2019) Cold-Cured Epoxy-Based Organic-Inorganic Hybrid Resins Containing Deep Eutectic Solvents. Polymers 11:14. https://doi.org/10.3390/polym11010014

    Article  CAS  Google Scholar 

  34. Kaya İ, Gül M, Şenol D (2019) Synthesis and characterization of epoxy resins containing imine group and their curing processes with aromatic diamine. Journal of Macromolecular Science, Part A 56:618–627. https://doi.org/10.1080/10601325.2019.1596747

    Article  CAS  Google Scholar 

  35. Padmaraja NH, Vijaya KM, Dayananda P (2021) Experimental investigation on fatigue behaviour of glass/epoxy quasi-isotropic laminate composites under different ageing conditions. Int J Fatigue 143:105992. https://doi.org/10.1016/j.ijfatigue.2020.105992

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Belgorod State Technological University Named After V. G. Shukhov, Kostukova St., 46, 308012, Belgorod, Russia

    Sergey Savotchenko & Ekaterina Kovaleva

  2. Belgorod I.D. Putilin Legal Institute, Gorkogo, 71, 308024, Belgorod, Russia

    Sergey Savotchenko & Ekaterina Kovaleva

  3. Financial University Under the Government of the Russian Federation, Leningradsky Pr., 49, 125167, Moscow, Russia

    Aleksei Cherniakov

Authors
  1. Sergey Savotchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ekaterina Kovaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Aleksei Cherniakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sergey Savotchenko.

Ethics declarations

Competing interest

The author declares that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Savotchenko, S., Kovaleva, E. & Cherniakov, A. The improvement of mechanical properties of repair and construction compositions based on epoxy resin with mineral fillers. J Polym Res 29, 280 (2022). https://doi.org/10.1007/s10965-022-03138-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-022-03138-8

Keywords

Search

Navigation