Abstract
Rigid polyurethane (PU) foams are widely used in modern life owing to excellent strength and weight carrying capacity. Most of the rigid PU foams in the market are based on polypropylene oxide (PPO) and methylene diphenyl diisocyanate. Amine catalysts, especially tertiary amines, are used to balance both the gelling and gas-foaming reactions, responsible for foam formation. The objective of present work is to prepare rigid PU foams from PPO based polyol and 4,4′- methylene diphenyl diisocyanate (MDI). The morphological and mechanical properties of polyurethane foam using tertiary amine and water blowing agent have been investigated. Moreover, acoustic and thermal insulation of polyurethane foam ordinary Portland cement mortar formulations were also examined. The results indicated that polyurethane ordinary Portland cement mortar formulations have good sound absorption and thermal insulation characteristics compared to blank formulations.
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References
Mahmoud AA, Nasr EAA, Maamoun AAH (2017) The influence of polyurethane foam on the insulation characteristics of mortar pastes. J Miner Mater Charact Eng 05:49–61
Sawpan MA (2018) Polyurethanes from vegetable oils and applications: a review. J Polym Res 25:184–198
Tan S, Abraham T, Ference D, Macosko CW (2011) Rigid polyurethane foams from a soybean oil-based polyol. Polymer (Guildf) 52:2840–2846
Yusuf AK, Mamza PAP, Ahmed AS, Agunwa U (2016) Physico-mechanical properties of rigid polyurethane foams synthesized from modified castor oil polyols. Int J Sci Res Publ 6:548–556
Akindoyo JO, Beg MDH, Ghazali S et al (2016) Polyurethane types, synthesis and applications – a review. RSC Adv 6:114453–114482
Saint-Michel F, Chazeau L, Cavaillé J-Y (2006) Mechanical properties of high density polyurethane foams: II effect of the filler size. Compos Sci Technol 66:2709–2718
Ribeiro da Silva V, Mosiewicki MA, Yoshida MI et al (2013) Polyurethane foams based on modified tung oil and reinforced with rice husk ash I: synthesis and physical chemical characterization. Polym Test 32:438–445
Zieleniewska M, Leszczyński MK, Szczepkowski L et al (2016) Development and applicational evaluation of the rigid polyurethane foam composites with egg shell waste. Polym Degrad Stab 132:78–86
Şerban D-A, Weissenborn O, Geller S et al (2016) Evaluation of the mechanical and morphological properties of long fibre reinforced polyurethane rigid foams. Polym Test 49:121–127
Verdolotti L, Lavorgna M, Di Maio E, Iannace S (2013) Hydration-induced reinforcement of rigid polyurethane–cement foams: the effect of the co-continuous morphology on the thermal-oxidative stability. Polym Degrad Stab 98:64–72
Dworakowska S, Bogdał D, Zaccheria F, Ravasio N (2014) The role of catalysis in the synthesis of polyurethane foams based on renewable raw materials. Catal Today 223:148–156
Choe KH, Lee DS, Seo WJ, Kim WN (2004) Properties of rigid polyurethane foams with blowing agents and catalysts. Polym J 36:368–373
Han MS, Choi SJ, Kim JM et al (2009) Effects of silicone surfactant on the cell size and thermal conductivity of rigid polyurethane foams by environmentally friendly blowing agents. Macromol Res 17:44–50
Silva AL, Bordado JC (2004) Recent developments in polyurethane catalysis: catalytic mechanisms review. Catal Rev 46:31–51
Defonseka C (2013) Properties and foaming technology of polyurethane foam. Practical guide to flexible polyurethane foams, In
Dounis DV, Wilkes GL (1997) Structure-property relationships of flexible polyurethane foams. Polymer (Guildf) 38:2819–2828
Kang SM, Lee SJ, Kim BK (2012) Shape memory polyurethane foams. Express Polym Lett 6:63–69
Van Maris R, Tamano Y, Yoshimura H, Gay KM (2005) Polyurethane catalysis by tertiary amines. J Cell Plast 41:305–322
Singh SN, Joong P, Chang Y, Han D (2000) Blowing agents for polyurethane foams. Item 1 Macromol
Verdolotti L, Di Maio E, Forte G et al (2010) Hydration-induced reinforcement of polyurethane–cement foams: solvent resistance and mechanical properties. J Mater Sci 45:3388–3391
Scrivener KL, Juilland P, Monteiro PJM (2015) Advances in understanding hydration of Portland cement. Cem Concr Res 78:38–56
Hökfors B, Boström D, Viggh E, Backman R (2015) On the phase chemistry of Portland cement clinker. Adv Cem Res 27:50–60
Lee S.T (2004) Introduction: Polymeric Foams, Mechanism, and Materials. In: Polymeric Foams: Mechanisms and Materials, CRC Press LLC, New York
Hui B, Ye L, Zhao X (2018) In situ preparation of polyurethane-imide/graphene oxide nano-composite foam: intercalation structure and thermal mechanical stability. J Polym Res 25:267–280
Rastegarfar N, Behrooz R, Barikani M (2018) Characterization of polyurethane foams prepared from liquefied sawdust by crude glycerol and polyethylene glycol. J Polym Res 25:154–161
Jiang T, Wang W, Yu D et al (2018) Synthesis and characterization of polyurethane rigid foams from polyether polyols with isosorbide as the bio-based starting agent. J Polym Res 25:140–150
Firdaus FE (2012) Role of silicone on molded flexible polyurethane from soy oil. Int J Chem 4:45–49
Stumpf González MA, Flach F, Reschke Pires J, Piva Kulakowski M (2013) Acoustic absorption of mortar composites with waste material. Arch Acoust 38:417–423
Corinaldesi V, Mazzoli A, Moriconi G (2011) Mechanical behaviour and thermal conductivity of mortars containing waste rubber particles. Mater Des 32:1646–1650
Acknowledgements
This research was supported by Royal Foam Co. through the supply of chemicals required for this work and Chemistry Lab. at the Faculty of Engineering Ain Shams University (ASU). Analysis help by Materials Lab. at American University in Cairo (AUC), National Institute for Standards (NIS) and Housing & Building National Research Center (HBRC) are highly appreciated. Dr. Sonia Zulfiqar is highly thankful to American University in Cairo for funding through STRC mini grant.
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Maamoun, A.A., Mahmoud, A.A., Nasr, E.A. et al. Fabrication of novel formulations from rigid polyurethane foams and mortar for potential applications in building industry. J Polym Res 26, 259 (2019). https://doi.org/10.1007/s10965-019-1934-y
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DOI: https://doi.org/10.1007/s10965-019-1934-y