Abstract
In this work, biodegradable composite were prepared using banana pseudostem fibre and polyvinyl alcohol (PVA) matrix along with plasticizers and cross linkers in form of blended films of different compositions by solution casting process. The effect of composition on the structure and properties of the resulting films were investigated. OH groups on banana fibre and PVA formed hydrogen bonding interactions, which could improve the compatibility of the two components. With the increase of banana fibre weight percent, the degree of crystallinity of PVA component decreased. The tensile strength and elongation at break decreased with increasing content of banana fibre. However, at 20% banana fibre content, the flexibility of the blend films was still high, with the elongation at break more than 100% and tensile strength of 30.8 MPa, which was near to the commonly used LDPE package films. Composite films were permeable to water, but at the same time able to maintain consistency and composition upon drying. Chemical crosslinking by citric acid and glutaraldehyde, between banana pseudostem fibre and PVA, all of which are hydroxyl functionalized, improved water resistance in films. Composite films with alkali treated banana pseudostem fibres had maximum tensile strength of 34.2 MPa and least water uptake of 60% only.
Similar content being viewed by others
References
Petersen K, Vae g NP et al (1999) Potential of biobased materials for food packaging. Trends Food Sci Technol 10:52–68. https://doi.org/10.1016/S0924-2244(99)00019-9
Weber CJ, Haugaard V, Festersen R, Bertelsen G (2002) Production and applications of biobased packaging materials for the food industry production and applications of biobased packaging materials for the food industry. Food Addit Contam 19:172–177. https://doi.org/10.1080/0265203011008748
Bertuzzi MA, Armada M, Gottifredi JC (2007) Physicochemical characterization of starch based films. J Food Eng 82:17–25. https://doi.org/10.1016/j.jfoodeng.2006.12.016
Lu DR, Xiao CM, Xu SJ (2009) Starch-based completely biodegradable polymer materials. Express Polym Lett 3:366–375. https://doi.org/10.3144/expresspolymlett.2009.46
Bin-dahman OA, Shehzad F, Al-harthi MA (2018) Influence of graphene on the non-isothermal crystallization kinetics of poly ( vinyl alcohol )/ starch composite. 25. https://doi.org/10.1007/s10965-017-1400-7
Guimarães M, Botaro VR, Novack KM, Teixeira FG, Tonoli GHD (2015) High moisture strength of cassava starch/polyvinyl alcohol-compatible blends for the packaging and agricultural sectors. J Polym Res 22. https://doi.org/10.1007/s10965-015-0834-z
Liu B, Xu H, Zhao H, Liu W, Zhao L, Li Y (2017) Preparation and characterization of intelligent starch/PVA films for simultaneous colorimetric indication and antimicrobial activity for food packaging applications. Carbohydr Polym 157:842–849. https://doi.org/10.1016/j.carbpol.2016.10.067
Singha AS, Priya B, Pathania D (2015) Cornstarch/poly(vinyl alcohol) biocomposite blend films: mechanical properties, thermal behavior, fire retardancy, and antibacterial activity. Int J Polym Anal Charact 20:357–366. https://doi.org/10.1080/1023666X.2015.1018491
Li W, Zhao X, Huang Z, Liu S (2013) Nanocellulose fibrils isolated from BHKP using ultrasonication and their reinforcing properties in transparent poly (vinyl alcohol) films. J Polym Res 20. https://doi.org/10.1007/s10965-013-0210-9
Lam NT, Saewong W, Sukyai P (2017) Effect of varying hydrolysis time on extraction of spherical bacterial cellulose nanocrystals as a reinforcing agent for poly(vinyl alcohol) composites. J Polym Res 24:1–10. https://doi.org/10.1007/s10965-017-1232-5
Davis G, Song JH (2006) Biodegradable packaging based on raw materials from crops and their impact on waste management. Ind Crop Prod 23:147–161. https://doi.org/10.1016/j.indcrop.2005.05.004
Rhim J-W, Ng PKW (2007) Natural biopolymer-based nanocomposite films for packaging applications. Crit Rev Food Sci Nutr 47:411–433. https://doi.org/10.1080/10408390600846366
Cinelli P, Chiellini E, Lawton JW, Imam SH (2006) Properties of injection molded composites containing corn fiber and poly(vinyl alcohol). J Polym Res 13:107–113. https://doi.org/10.1007/s10965-005-9012-z
Kalambettu A, Damodaran A, Dharmalingam S, Vallam MT (2015) Evaluation of biodegradation of pineapple leaf Fiber reinforced PVA composites. J Nat Fibers 12:39–51. https://doi.org/10.1080/15440478.2014.880104
Asgher M, Ahmad Z, Iqbal HMN (2017) Bacterial cellulose-assisted de-lignified wheat straw-PVA based bio-composites with novel characteristics. Carbohydr Polym 161:244–252. https://doi.org/10.1016/j.carbpol.2017.01.032
Imam SH, Cinelli P, Gordon SH, Chiellini E (2005) Characterization of biodegradable composite films prepared from blends of poly(vinyl alcohol), cornstarch, and lignocellulosic fiber. J Polym Environ 13:47–55. https://doi.org/10.1007/s10924-004-1215-6
Treinyte J, Bridziuviene D, Fataraite-Urboniene E, Rainosalo E, Rajan R, Cesoniene L, Grazuleviciene V (2018) Forestry wastes filled polymer composites for agricultural use. J Clean Prod 205:388–406. https://doi.org/10.1016/j.jclepro.2018.09.012
Sutka A, Gravitis J, Kukle S, Sutka A, Timusk M (2015) Electrospinning of poly(vinyl alcohol) nanofiber mats reinforced by lignocellulose nanowhiskers. Soft Mater 13:18–23. https://doi.org/10.1080/1539445X.2014.995309
Mittal A, Garg S, Kohli D, Maiti M, Jana AK, Bajpai S (2016) Effect of cross linking of PVA/starch and reinforcement of modified barley husk on the properties of composite films. Carbohydr Polym 151:926–938. https://doi.org/10.1016/j.carbpol.2016.06.037
Meng F, Zhang Y, Xiong Z, Wang G, Li F, Zhang L (2018) Mechanical, hydrophobic and thermal properties of an organic-inorganic hybrid carrageenan-polyvinyl alcohol composite film. Compos Part B Eng 143:1–8. https://doi.org/10.1016/j.compositesb.2017.12.009
Priya B, Gupta VK, Pathania D, Singha AS (2014) Synthesis, characterization and antibacterial activity of biodegradable starch/PVA composite films reinforced with cellulosic fibre. Carbohydr Polym 109:171–179. https://doi.org/10.1016/j.carbpol.2014.03.044
Guimarães M, Botaro VR, Novack KM et al (2015) Starch/PVA-based nanocomposites reinforced with bamboo nanofibrils. Ind Crop Prod 70:72–83. https://doi.org/10.1016/j.indcrop.2015.03.014
Shen Z, Ghasemlou M, Kamdem DP (2015) Development and compatibility assessment of new composite film based on sugar beet pulp and polyvinyl alcohol intended for packaging applications. J Appl Polym Sci 132:1–8. https://doi.org/10.1002/app.41354
Horseman T, Tajvidi M, Diop CIK, Gardner DJ (2017) Preparation and property assessment of neat lignocellulose nanofibrils (LCNF) and their composite films. Cellulose 24:2455–2468. https://doi.org/10.1007/s10570-017-1266-1
Food and Agricultural Organization of the United NAtions (2014) FAOSTAT 2014. http://www.fao.org/faostat/en/#data/QC. Accessed 2014
Padam BS, Tin HS, Chye FY, Abdullah MI (2014) Banana by-products: an under-utilized renewable food biomass with great potential. J Food Sci Technol 51:3527–3545. https://doi.org/10.1007/s13197-012-0861-2
Shah MP, Reddy GV, Banerjee R, Ravindra Babu P, Kothari IL (2005) Microbial degradation of banana waste under solid state bioprocessing using two lignocellulolytic fungi (Phylosticta spp. MPS-001 and Aspergillus spp. MPS-002). Process Biochem 40:445–451. https://doi.org/10.1016/J.PROCBIO.2004.01.020
Mueller S, Weder C, Foster EJ (2014) Isolation of cellulose nanocrystals from pseudostems of banana plants. RSC Adv 4:907–915. https://doi.org/10.1039/C3RA46390G
Bledzki AK, Mamun AA, Volk J (2010) Physical, chemical and surface properties of wheat husk, rye husk and soft wood and their polypropylene composites. Compos A Appl Sci Manuf 41:480–488. https://doi.org/10.1016/j.compositesa.2009.12.004
Jayaprabha JS, Brahmakumar M, Manilal VB (2011) Banana pseudostem characterization and its fiber property evaluation on physical and bioextraction. J Nat Fibers 8:149–160. https://doi.org/10.1080/15440478.2011.601614
Guimarães JL, Frollini E, da Silva CG, Wypych F, Satyanarayana KG (2009) Characterization of banana, sugarcane bagasse and sponge gourd fibers of Brazil. Ind Crop Prod 30:407–415. https://doi.org/10.1016/J.INDCROP.2009.07.013
Bilba K, Arsene MA, Ouensanga A (2007) Study of banana and coconut fibers. Botanical composition, thermal degradation and textural observations. Bioresour Technol 98:58–68. https://doi.org/10.1016/j.biortech.2005.11.030
Annie Paul S, Boudenne A, Ibos L, Candau Y, Joseph K, Thomas S (2008) Effect of fiber loading and chemical treatments on thermophysical properties of banana fiber/polypropylene commingled composite materials. Compos A Appl Sci Manuf 39:1582–1588. https://doi.org/10.1016/J.COMPOSITESA.2008.06.004
Barra GMO, Fredel MC, Al-Qureshi HA et al (2006) Properties of chemically treated natural amorphous silica fibers as polyurethane reinforcement. Polym Compos 27:582–590. https://doi.org/10.1002/pc.20229
John MJ, Thomas S (2008) Biofibres and biocomposites. Carbohydr Polym 71:343–364. https://doi.org/10.1016/j.carbpol.2007.05.040
Prasad SV, Pavithran C, Rohatgi PK (1983) Alkali treatment of coir fibres for coir-polyester composites. J Mater Sci 18:1443–1454. https://doi.org/10.1007/BF01111964
Rahman MM, Khan MA (2007) Surface treatment of coir (Cocos nucifera) fibers and its influence on the fibers’ physico-mechanical properties. Compos Sci Technol 67:2369–2376. https://doi.org/10.1016/J.COMPSCITECH.2007.01.009
Valadez-Gonzalez A, Cervantes-Uc JM, Olayo R, Herrera-Franco PJ (1999) Effect of fiber surface treatment on the fiber–matrix bond strength of natural fiber reinforced composites. Compos Part B Eng 30:309–320. https://doi.org/10.1016/S1359-8368(98)00054-7
MA Saïd Azizi Samir, Fannie Alloin, Michel Paillet and, Alain Dufresne (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. https://doi.org/10.1021/MA035939U
Dufresne A (2008) Polysaccharide nano crystal reinforced nanocomposites. Can J Chem 86:484–494. https://doi.org/10.1139/v07-152
de Souza Lima MM, Borsali R (2004) Rodlike cellulose microcrystals: structure, properties, and applications. Macromol Rapid Commun 25:771–787. https://doi.org/10.1002/marc.200300268
Merlini C, Soldi V, Barra GMO (2011) Influence of fiber surface treatment and length on physico-chemical properties of short random banana fiber-reinforced castor oil polyurethane composites. Polym Test 30:833–840. https://doi.org/10.1016/J.POLYMERTESTING.2011.08.008
Corrales F, Vilaseca F, Llop M, Gironès J, Méndez JA, Mutjè P (2007) Chemical modification of jute fibers for the production of green-composites. J Hazard Mater 144:730–735. https://doi.org/10.1016/j.jhazmat.2007.01.103
Yang H, Yan R, Chen H, Lee DH, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788. https://doi.org/10.1016/j.fuel.2006.12.013
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Srivastava, K.R., Singh, M.K., Mishra, P.K. et al. Pretreatment of banana pseudostem fibre for green composite packaging film preparation with polyvinyl alcohol. J Polym Res 26, 95 (2019). https://doi.org/10.1007/s10965-019-1751-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10965-019-1751-3