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High toughening and low friction of novel bismaleimide composites with organic functionalized serpentine@Fe3O4

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Abstract

A novel hybrid particles Srp@Fe3O4/OA, composed of phyllosilicate Serpentine (Srp), magnetic Fe3O4 and oleic acid (OA), has been explored via a two-step process. Then the as-prepared Srp@Fe3O4/OA particles were firstly mixed with bismaleimide resin (BMI) to constructe a series of Srp@Fe3O4/OA/BMI composites, the mechanical properties, tribological properties and thermal stability of the Srp@Fe3O4/OA/BMI composites are subsequently investigated. The characterization results indicate that the 0.3 wt% Srp@Fe3O4/OA/BMI composite shows the maximum impact strength (19.0 kJ·m−2) and minimum friction coefficient (0.21), higher 52.7% and lower 55% than those of the neat BMI resin, respectively. The significantly enhanced toughness and tribological performance of the Srp@Fe3O4/OA/BMI composites are mainly due to the increase of the free volume and the uniformly distribution of Srp@Fe3O4/OA, as well as the good interfacial adhesion between BMI matrix and Srp@Fe3O4/OA particles.

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Acknowledgements

This work is sponsored by a grant from the Specialized Research Fund for the Doctoral Program of Higher Education of China (20136102110049), and the Seed Foundation of Innovation and Creation for Graduate Students in Northwestern Polytechnical University (Z2016167).

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Authors and Affiliations

  1. Key Laboratory of Polymer Science and Technology, Shaanxi Province, School of Science, Northwestern Polytechnical University, Xi’an, 710129, China

    Xiaoli Zhi, Hongxia Yan, Song Li, Song Niu, Chao Liu & Peilun Xu

  2. Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, School of Science, Northwestern Polytechnical University, Xi’an, 710129, China

    Xiaoli Zhi, Hongxia Yan, Song Li, Song Niu, Chao Liu & Peilun Xu

Authors
  1. Xiaoli Zhi
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  2. Hongxia Yan
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  3. Song Li
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  4. Song Niu
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  5. Chao Liu
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  6. Peilun Xu
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Correspondence to Hongxia Yan.

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Zhi, X., Yan, H., Li, S. et al. High toughening and low friction of novel bismaleimide composites with organic functionalized serpentine@Fe3O4 . J Polym Res 24, 31 (2017). https://doi.org/10.1007/s10965-017-1192-9

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