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Properties of waterborne polyurethane films: effects of blend formulation with hydroxyl telechelic natural rubber and modified rubber seed oils

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Abstract

A series of new waterborne polyurethanes (WPUs) was successfully prepared by the prepolymer process from the bio-renewable sources hydroxytelechelic natural rubber (HTNR with MW 3000 g mol−1) and hydroxylated rubber seed oil (HRSO), with DMPA fixed at 5.6 wt%. The effects of ratio of HTNR and HRSO (ranging from 1.00/0 to 0.10/0.90) and of hydroxyl value (OHV) of HRSO (200 or 270 mgKOH/g) on final properties were studied. It was found that the particle size of WPU increased significantly with both HRSO/HTNR ratio and OHV of HRSO. Chemical structure of the WPU films was confirmed by FT-IR. The water uptake, mechanical, dynamic mechanical properties and thermal stability of WPU film improved with both HRSO content and OHV of HRSO, while swelling in THF decreased. All these WPU films had similar Tg. This article reports novel green biobased WPU with promising applications as adhesive for shoe industries.

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References

  1. Kim BK (1996) Colloid Polym Sci 274(7):599–611

    Article  CAS  Google Scholar 

  2. Dieterich D (1981) Progress in Organic Coatings 9(3):281–340

    Article  CAS  Google Scholar 

  3. Yang J-E, Kong J-S, Park S-W, Lee D-J, Kim H-D (2002) J Appl Polym Sci 86(9):2375–2383

    Article  CAS  Google Scholar 

  4. Yoon Jang J, Kuk Jhon Y, Woo Cheong I, Hyun Kim J (2002) Colloids Surf A Physicochem Eng Asp 196(2–3):135–143

    Article  Google Scholar 

  5. Madbouly SA, Otaigbe JU, Nanda AK, Wicks DA (2005) Macromolecules 38(9):4014–4023

    Article  CAS  Google Scholar 

  6. Noble K-L (1997) Progress in Organic Coatings 32(1–4):131–136

    Article  CAS  Google Scholar 

  7. Eling B (2002) Coatings. In: Randall D, Lee S (eds) The polyurethane book. John Wiley & Sons, LTD, United Kingdom, p. 374

    Google Scholar 

  8. Kébir N, Campistron I, Laguerre A, Pilard J-F, Bunel C, Couvercelle J-P, Gondard C (2005) Polymer 46(18):6869–6877

    Article  Google Scholar 

  9. Kébir N, Campistron I, Laguerre A, Pilard J-F, Bunel C, Jouenne T (2007) Biomaterials 28(29):4200–4208

    Article  Google Scholar 

  10. Panwiriyarat W, Tanrattanakul V, Pilard J-F, Pasetto P, Khaokong C (2013) J Appl Polym Sci 130(1):453–462

    Article  CAS  Google Scholar 

  11. Saetung A, Kaenhin L, Klinpituksa P, Rungvichaniwat A, Tulyapitak T, Munleh S, Campistron I, Pilard J-F (2012) J Appl Polym Sci 124(4):2742–2752

    Article  CAS  Google Scholar 

  12. Saetung A, Rungvichaniwat A, Campistron I, Klinpituksa P, Laguerre A, Phinyocheep P, Doutres O, Pilard J-F (2010) J Appl Polym Sci 117(2):828–837

    Article  CAS  Google Scholar 

  13. Saetung A, Tsupphayakorn-ake P, Tulyapituk T, Saetung N, Phinyocheep P, Pilard J-F (2015) J Appl Polym Sci 132(36). doi:10.1002/app.42505

  14. Saetung N, Campistron I, Pascual S, Soutif J-C, Pilard J-F, Fontaine L (2011) Eur Polym J 47(5):1151–1159

    Article  CAS  Google Scholar 

  15. Bakare IO, Okieimen FE, Pavithran C, Abdul Khalil HPS, Brahmakumar M (2010) Mater Des 31(9):4274–4280

    Article  CAS  Google Scholar 

  16. Mutlu H, Meier MAR (2010) Eur J Lipid Sci Technol 112(1):10–30

    Article  CAS  Google Scholar 

  17. Lu Y, Larock RC (2010) Progress in Organic Coatings 69(1):31–37

    Article  CAS  Google Scholar 

  18. Saetung A, Rungvichaniwat A, Campistron I, Klinpituksa P, Laguerre A, Phinyocheep P, Pilard J-F (2010) J Appl Polym Sci 117(3):1279–1289

    CAS  Google Scholar 

  19. Kébir N, Morandi G, Campistron I, Laguerre A, Pilard J-F (2005) Polymer 46(18):6844–6854

    Article  Google Scholar 

  20. Lu Y, Larock RC (2008) Biomacromolecules 9(11):3332–3340

    Article  CAS  Google Scholar 

  21. Pawlik H, Prociak A (2012) J Polym Environ 20(2):438–445

    Article  CAS  Google Scholar 

  22. Tu Y-C, Suppes GJ, Hsieh F-H (2008) J Appl Polym Sci 109(1):537–544

    Article  CAS  Google Scholar 

  23. Tanaka R, Hirose S, Hatakeyama H (2008) Bioresour Technol 99(9):3810–3816

    Article  CAS  Google Scholar 

  24. Akram D, Sharmin E, Ahmad S (2014) Progress in Organic Coatings 77(5):957–964

    Article  CAS  Google Scholar 

  25. Akram D, Sharmin E, Ahmad S (2010) J Appl Polym Sci 116(1):499–508

    Article  CAS  Google Scholar 

  26. Hu YH, Gao Y, Wang DN, Hu CP, Zu S, Vanoverloop L, Randall D (2002) J Appl Polym Sci 84(3):591–597

    Article  CAS  Google Scholar 

  27. NR Export of Thailand by Types in 2002–2013. http://www.thainr.com/en/detail-stat.php?statID=241. Accessed 8 Mar 2014

  28. Saetung N, Somjit S, Thongkapsri P, Tulyapitak T, Saetung A (2016) J Polym Res 23(3):1–10

    Article  Google Scholar 

  29. Charoen D (2011) Science and Rubber Technology 3:24–34

    Google Scholar 

  30. Morshed M, Ferdous K, Khan MR, Mazumder MSI, Islam MA, Uddin MT (2011) Fuel 90(10):2981–2986

    Article  CAS  Google Scholar 

  31. Gimbun J, Ali S, Kanwal CCSC, Shah LA, Ghazali NHM, Cheng CK, Nurdin S (2013) Procedia Engineering 53(0):13–19

    Article  CAS  Google Scholar 

  32. Sharma BB, Saha RK, Saha H (2014) Anim Feed Sci Technol 193:84–92

    Article  CAS  Google Scholar 

  33. Deng J, Mai K, Chen L, Mi H, Zhang L (2015) Fish & Shellfish Immunol 44(2):436–444

    Article  CAS  Google Scholar 

  34. Joseph R, Alex R, Vinod VS, Premalatha CK, Kuriakose B (2003) J Appl Polym Sci 89(3):668–673

    Article  CAS  Google Scholar 

  35. Joseph R, Alex R, Madhusoodanan KN, Premalatha CK, Kuriakose B (2004) J Appl Polym Sci 92(6):3531–3536

    Article  CAS  Google Scholar 

  36. Aigbodion AI, Pillai CKS (2000) Prog Org Coat 38(3–4):187–192

    Article  CAS  Google Scholar 

  37. Bakare IO, Pavithran C, Okieimen FE, Pillai CKS (2008) J Appl Polym Sci 109(5):3292–3301

    Article  CAS  Google Scholar 

  38. Okieimen FE, Pavithran C, Bakare IO (2005) Eur J Lipid Sci Technol 107(5):330–336

    Article  CAS  Google Scholar 

  39. Kim BS, Kim BK (2005) J Appl Polym Sci 97(5):1961–1969

    Article  CAS  Google Scholar 

  40. Harjunalanen T, Lahtinen M (2003) Eur Polym J 39(4):817–824

    Article  CAS  Google Scholar 

  41. Lu Y, Xia Y, Larock RC (2011) Prog Org Coat 71(4):336–342

    Article  CAS  Google Scholar 

  42. Chai SL, Tan HM (2008) J Appl Polym Sci 107(6):3499–3504

    Article  CAS  Google Scholar 

  43. Chai SL, Jin MM (2009) J Appl Polym Sci 114(4):2030–2035

    Article  CAS  Google Scholar 

  44. Paul CJ, Gopinathan Nair MR, Neelakantan NR, Koshy P, Idage BB, Bhelhekar AA (1998) Polymer 39(26):6861–6874

    Article  CAS  Google Scholar 

  45. Poussard L, Burel F, Couvercelle J-P, Loutelier-Bourhis C, Bunel C (2006) J Appl Polym Sci 100(4):3312–3322

    Article  CAS  Google Scholar 

  46. Jena KK, Chattopadhyay DK, Raju KVSN (2007) Eur Polym J 43(5):1825–1837

    Article  CAS  Google Scholar 

  47. Asif A, Shi W, Shen X, Nie K (2005) Polymer 46(24):11066–11078

    Article  CAS  Google Scholar 

  48. Petrović ZS, Zhang W, Javni I (2005) Biomacromolecules 6(2):713–719

    Article  Google Scholar 

  49. Petrović ZS, Guo A, Javni I, Cvetković I, Hong DP (2008) Polym Int 57(2):275–281

    Article  Google Scholar 

Download references

Acknowledgements

We acknowledge the Faculty of Science and Technology, Prince of Songkla University, for financial support under grant contract SAT 560318S. The authors also thank the Research and Development Office (RDO) and Assoc. Prof. Seppo Karrila for assistance in manuscript preparation.

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Authors and Affiliations

  1. Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, Pattani, 94000, Thailand

    Anuwat Saetung, Adisai Rungvichaniwat, Phathanyaphon Tsupphayakorn-ake, Pornsuda Bannob & Tulyapong Tulyapituk

  2. Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai Campus, Songkhla, 90112, Thailand

    Nitinart Saetung

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  1. Anuwat Saetung
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  2. Adisai Rungvichaniwat
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  5. Tulyapong Tulyapituk
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  6. Nitinart Saetung
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Correspondence to Anuwat Saetung.

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Saetung, A., Rungvichaniwat, A., Tsupphayakorn-ake, P. et al. Properties of waterborne polyurethane films: effects of blend formulation with hydroxyl telechelic natural rubber and modified rubber seed oils. J Polym Res 23, 264 (2016). https://doi.org/10.1007/s10965-016-1160-9

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  • DOI: https://doi.org/10.1007/s10965-016-1160-9

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