Abstract
In this work, we aimed to develop a feasible method for in situ preparation of a magnetite ionic polymer nanocomposite at room temperature. For this purpose, acrylonitrile (AN) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) monomers were copolymerized and crosslinked using different monomer mol ratios in the presence of N,N-methylenebisacrylamide (MBA) as crosslinker to produce ionic crosslinked polymers P(AN-co-AMPS. The nitrile groups were converted to amine amidoxime by reacting with hydroxylamine to increase the adsorption characteristics of the ionic polymers. The produced polymers were swelled in iron cations produced from the reaction of ferric chloride and potassium iodide, followed by reaction with an ammonium hydroxide solution to produce magnetite nano-polymer composites. We performed FT-IR and XRD analysis to determine the chemical and crystalline structures, and assessed the morphologies and magnetite content using SEM, TEM and TGA analyses. We investigated the adsorption capacity and mechanism of the prepared magnetite nano-composites as adsorbents for methylene blue, Co2+ and Ni2+ cations from water.
Similar content being viewed by others
References
Ozay O, Ekici S, Baran Y, Aktas N, Sahiner N (2009) Water Res 43:4403–4411
Smith SC, Rodrigues DF (2015) Carbon 91:122–143
Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX (2012) Sci Total Environ 424:1–10
Hossain F, Perales-Perez OJ, Hwang S, Román F (2014) Sci Total Environ 466:1047–1059
Qu X, Alvarez PJ, Li Q (2013) Water Res 47:3931–3946
Chen C, Wang X, Nagatsu M (2009) Environ Sci Technol 43:2362–2367
Wang S, Sun H, Ang H-M, Tadé M (2013) Chem Eng J 226:336–347
Ma Y, Elankumaran S, Marr LC, Vejerano EP, Pruden A (2014) Toxic Rep Ser 1:871–876
Thatai S, Khurana P, Boken J, Prasad S, Kumar D (2014) Microchem J 116:62–76
O’Carroll D, Sleep B, Krol M, Boparai H, Kocur C (2013) Adv Water Resour 51:104–122
Pang Y, Zeng G, Tang L, Zhang Y, Liu Y, Lei X, Li Z, Zhang J, Xie G (2011) Desalination 281:278–284
Chen H, Deng C, Zhang X (2010) Angew Chem Int Ed 49:607–611
Akkaya R (2013) Desalination 321:3–8
Zhao F, Tang WZ, Zhao D, Meng Y, Yin D, Sillanpää M (2014) J Water Proc Eng 4:47–57
Shuang C, Li P, Li A, Zhou Q, Zhang M, Zhou Y (2012) Water Res 46:4417–4426
Ge F, Li M-M, Ye H, Zhao B-X (2012) J Hazard Mater 211:366–372
Zhang Q, Du Q, Hua M, Jiao T, Gao F, Pan B (2013) Environ Sci Technol 47:6536–6544
Li X-m, Zheng W, Wang D-b, Yang Q, Cao J-b, Yue X, Shen T-t, Zeng G-m (2010) Desalination 258:148–153
Şimşek S, Ulusoy U (2013) React Funct Polym 73:73–82
Shubha K, Raji C, Anirudhan T (2001) Water Res 35:300–310
Zhao G, Zhong H, Qiu X, Wang S, Gao Y, Dai Z, Huang J, Liu G (2013) Miner Eng 49:54–60
Isikver Y, Saraydin D, Sahiner N (2001) Polym Bull 47:71–79
Codd R (2008) Coord Chem Rev 252:1387–1408
Nyirő-Kósa I, Nagy DC, Pósfai M (2009) Eur J Mineral 21:293–302
Atta AM, Al-Lohedan HA, Al-Hussain SA (2014) Molecules 19:11263–11278
Atta AM, Al-Lohedan HA, Al-Hussain SA (2015) Int J Mol Sci 16:6911–6931
Atta AM, Ismail HS, Mohamed HM, Mohamed ZM (2011) J Appl Polym Sci 122:999–1011
Atta AM, El-Mahdy GA, Al-Lohedan HA, Al-Hussain SA (2014) Int J Mol Sci 15:6974–6989
Sun S, Zeng H, Robinson DB, Raoux S, Rice PM, Wang SX, Li G (2004) J Am Chem Soc 126:273–279
Atta AM, El-Mahdy GA, Al-Lohedan HA, El-Saeed AM (2015) Molecules 20:1244–1261
Baybaş D, Ulusoy U (2011) J Hazard Mater 187:241–249
Huang J, Pen H, Xu Z, Yi C (2008) React Funct Polym 68:332–339
Goya G, Berquo T, Fonseca F, Morales M (2003) J Appl Phys 94:3520–3528
Chomoucka J, Drbohlavova J, Huska D, Adam V, Kizek R, Hubalek J (2010) Pharmacol Res 62:144–149
Mincheva R, Stoilova O, Penchev H, Ruskov T, Spirov I, Manolova N, Rashkov I (2008) Eur Polym J 44:615–627
Atta AM, Arndt KF (2005) Polym Int 54:448–455
Atta AM (2002) Polym Adv Technol 13:567–576
Xu S, Fan L, Zeng M, Wang J, Liu Q (2010) Colloids Surf A Physicochem Eng Asp 371:59–63
Philippova O, Barabanova A, Molchanov V, Khokhlov A (2011) Eur Polym J 47:542–559
Luo S, Xu X, Zhou G, Liu C, Tang Y, Liu Y (2014) J Hazard Mater 274:145–155
Xu X, Ba B, Ding C, Wang H, Suo Y (2015) Ind Eng Chem Res 54(13):3268–3278
Singh A, Bajpai J, Bajpa AK (2014) J Nanoparticle Res 12:38–45
de Lima ROA, Bazo AP, Salvadori DMF, Rech CM, de Palma Oliveira D, de Aragão Umbuzeiro G (2007) Mutat Res Genet Toxicol Environ Mutagen 626:53–60
Rytwo G, Tropp D, Serban C (2002) Appl Clay Sci 20:273–282
Kołodyńska D (2010) Chem Eng J 165:835–845
Tansel B (2012) Sep Purif Technol 86:119–126
Hokkanen S, Repo E, Sillanpää M (2013) Chem Eng J 223:40–47
Saeed K, Haider S, Oh TJ (2008) J Membr Sci 322(2):400–405
Bilba N, Bilba D, Moroi G (2004) J Appl Polym Sci 92(6):3730–3735
Coskun R, Soykan C (2009) J Appl Polym Sci 112(3):1798–1807
Griffith DM, Szőcs B, Keogh T, Suponitsky KY, Farkas E, Buglyó P, Marmion CJ (2011) J Inorg Biochem 105:763–769
Kumar SA, Pandey SP, Thakur N, Parab H, Shinde RN, Pandey AK, Wagh DN, Kumar SD, Reddy A (2013) J Hazard Mater 262:265–273
Xiao L, Li J, Brougham DF, Fox EK, Feliu N, Bushmelev A, Schmidt A, Mertens N, Kiessling F, Valldo M, Fadeel B, Mathur S (2011) ACS Nano 5:6315–6324
Acknowledgments
This project was supported financially by King Saud University, Vice Deanship of Research Chairs.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Atta, A.M., Al-Lohedan, H.A., Ezzat, A.O. et al. Synthesis and application of magnetite polyacrylamide amino-amidoxime nano-composites as adsorbents for water pollutants. J Polym Res 23, 69 (2016). https://doi.org/10.1007/s10965-016-0963-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10965-016-0963-z